ArchiveBiaxially oriented polypropylene (BOPP) film is an important part of capacitor. The key parameters (ash content, isotacticity, molecular weight, melt flow rate, isotactic sequence length) of polypropylene resin used as raw materials for BOPP films and their influence rules were summarized in this paper. At the same time, the existing production technology of BOPP capacitor film was summarized, and the methods to improve the performance of BOPP film were further reviewed. Finally, it is proposed that the future development of BOPP films for capacitors will focus on the ultra-low ash resin raw materials and heat resistant films.
In this paper, the performance and characteristics of low smoke halogen-free flame retardant cable material was reviewed. The advantage and disadvantage of ethylene-vinyl acetate copolymer (EVA) as the base material was introduced.The types and flame retardant mechanism of halogen-free flame retardant were reviewed. Finally, the development direction of low smoke halogen-free flame retardant cable material was prospected.
An epoxy resin-based sheet molding plastic (E-SMC) was prepared by using multi-function epoxy resin as the resin matrix, dicyandiamide as main curing agent, and mica as fillers. Then the epoxy molding composite was prepared by molding process, and its mechanical properties, thermodynamic properties, and electrical properties were systematically tested and studied. The results show that the epoxy molding composites have high mechanical strength, and the tensile strength, bending strength, vertical compression strength and parallel compression strength of typical samples can reach 64, 178, 440, and 332 MPa, respectively. At the same time, the epoxy molding composites have low density (1.69-1.76 g/cm3), high glass transition temperature (Tg up to 201℃), and excellent electrical strength properties, and the breakdown voltage of typical samples is up to 100 kV, the electric strength can reach 17.1 kV/mm, the comparative tracking index (CTI) is 600 V.
In order to obtain carbon-ceramic linear resistor with stable performance, the preparation of high resistance layer glaze slurry used in the manufacturing of carbon-ceramic resistor was studied systematically in this paper. Firstly, the glazing technology of glaze slurry prepared by different binders was compared, then the mixing time and water material ratio of slurry were systematically studied to obtain the influence of mixing time and water material ratio on the viscosity of glaze slurry, and finally the optimal mixing process parameters were determined. The results show that the glaze slurry has good suspension and coating properties when the Zuoyun clay is used as binder. When the mass fraction of Zuoyun clay is 15%, the glaze slurry has good processability and adhesion. The optimum mixing process parameters of high resistance glaze and binder is as below: Zuoyun clay is used as binder, the mass fraction of clay is 15%, the ratio of water and material is 0.6∶1, and the mixing time of ball glaze is 1 h. The breakdown strength of carbon-ceramic resistors coated with high resistance layer is 78% higher than that of the uncoated resistors, and the dispersion is smaller.
Ethylene-vinyl acetate copolymer/ethylene-α-olefin copolymer (EVA/POE) was used as the base material, and phosphorus-nitrogen halogen-free flame retardant (HF-601AE) compounded with surface modified aluminum hydroxide (ATH) was used as the flame retardant system, a halogen-free flame retardant polyolefin material for heat shrinkable tube was prepared by melt mixing method. The variation of limiting oxygen index, electrical properties, and mechanical properties of the composites under different ratios were studied, and the flame retardant mechanism of composites was investigated by thermo-gravimetric analysis (TGA) and the morphology characterization of combustion residue carbon. The results show that and the 2# sample prepared with 50 phr polyolefin materials, 35 phr flame retardant HF-601AE, and 20 phr ATH has the best mechanical properties, and the tensile strength is 7.1 MPa, the elongation at break is 502.86%. The limiting oxygen index is 37.2%, which meets the requirements of EN45545-2 R22 HL3 flame retardant grade. The thermogravimetric rate at 371.5℃ reaches -18.11%/min, the carbon residue is low after combustion, and there are no holes and pores in the carbon layer, which indicate that the comprehensive properties are the best.
In order to improve the upper limit temperature and high temperature stability of BaTiO3 for MLCC insulating dielectric material, a Ba1-xCaxTiO3 nano-powder was prepared by using BaCl2·H2O, CaCl2, and H2TiO3 as raw materials and KOH as mineralizer under the condition of 210℃/22 h hydrothermal reaction. The phase structure, microstructure, and dielectric properties of the samples were characterized and analyzed by XRD, SEM, LCR detection methods. The results show that the obtained powders are uniformly dispersed and the particle size is (110±20) nm. The doping of Ca2+ increases the Curie temperature of BaTiO3, and a Ba0.91Ca0.09TiO3 ceramics with 136.2℃of Curie temperature, 1 882 of dielectric constant, and 0.02 of dielectric loss factor are obtained at 1 250℃/2 h. The preparation of MLCC insulating dielectric materials with small particle size, narrow distribution, low agglomeration, and high performance is realized.
To deeply understand the self-recovery mechanism of electrical tree in silicone rubber (SiR), the self-recovery characteristics of SiR electrical tree were studied in this paper. The morphology variation during the self-recover process of electrical tree in SiR were observed, the elastic modulus and crosslinking density of SiR during the self-recovery process of electrical tree were tested, and the self-recover mechanism of SiR electrical tree was analyzed. The results show that the electrical trees in SiR exhibit self-recovery characteristics without external interventions including external electrical field and healing fillers, wherein some branches of electrical tree gradually degrade and eventually disappear, meanwhile the fractal dimension gradually decreases, and the rate of self-recovery exhibits the stage characteristics of fast at first and then slow. During the self-recovery process, the elastic modulus of SiR sample increases slightly from 0.964 MPa to 0.977 MPa, and the crosslinking density decreases slightly from 1.886×10-4 mol/g to 1.883×10-4 mol/g. After recovery, the physical crosslinking density of electrical tree deteriorated area increases slightly from 0.55×10-4 mol/g to 0.58×10-4 mol/g. Combined with the growing mechanism of SiR electrical trees, it is analyzed that the self-recovery process of SiR electrical tree is essentially the elastic contraction of tree channel, which is controlled by the gas flow in the channel and accompanied by the reconstruction of hydrogen bond.
The dissociation of impurities such as crosslinking by-products can easily lead to the accumulation of heteropolar space charges, resulting in local field strength distortion. At the same time, after the cross-linked polyethylene (XLPE) DC cables is degassing, the crosslinking by-product impurity in the insulating layer will form a concentration gradient distribution of "high inside and low outside", and the effect of impurity concentration gradient on the space charge is still unclear. Therefore, based on the bipolar charge transport model, the effect of cross-linked by-products impurity with uniform distribution and gradient distribution on the XLPE space charge and electric field distribution were simulated and calculated, and various factors affecting the gradient effect of impurity were analyzed. The results show that under the impurity gradient distribution, the space charge and electric field distribution of XLPE show obvious impurity gradient effect, that is, there are more opposite polarity charges accumulated on the low concentration side, which leads to the enhancement of the nearby electric field. While the impurity dissociation barrier and the impurity distribution concentration are the main reasons of affecting the impurity gradient effect. When the impurity concentration gradient is constant, the lower the activation energy, the higher the temperature, the lower the dissociation barrier, and the lower the carrier mobility, which results in the impurity gradient effect more obvious. The larger the insulation layer thickness, the higher the concentration of impurity distribution, and the more obvious the impurity gradient effect.
In this paper, class H insulation system of high voltage motor was studied. The basic properties of electromagnetic wire, dry mica tape, and insulating impregnated resin used in class H insulation structure were tested. The coil sample was manufactured, and the electrical properties, electric ageing, and electrothermal ageing tests were conducted on the coil sample. The results show that the insulating coil sample has excellent electrical performance in breakdown voltage and dielectric loss factor, which can meet the technical requirements of class H 10 kV high voltage motor.
In order to study the effect of winding preload on thermal ageing characteristics of insulating pads, four groups of insulating pads were conducted accelerated thermal ageing tests at 135℃ after appling 0, 200, 500, and 1 000 N of preload, respectively, and the mechanical properties of insulating pads were tested. At the same time, in order to simulate the mechanical ageing of insulating pad under the influence of winding vibration in the actual working condition, a sinusoidal cyclic mechanical load with 5 N of amplitude and 2 Hz was applied on the accelerated thermal ageing of insulating pad with 200 N of preloading force. The results show that that thermal ageing causes the stress-strain curve of insulating pad gradually shift to the right under 0 N preload, and its elastic modulus decreases gradually. The elastic modulus of insulating pad decreases to 79.935% of the new insulating pad after accelerated ageing for 336 h at 135℃. Applying preloading force can slow down the thermal ageing of insulating pad, and the greater the preloading force, the lower the ageing rate and ageing degree of insulating pad. But applying cyclic mechanical load will accelerate the ageing of insulating pad. The research results have certain reference and practical application value for the research of insulation pad ageing and transformer vibration.
To investigate influence of high-altitude environment on the electrical ageing performance of the main insulating material of new energy vehicle (NEV) drive motor, NHN insulating paper was selected as the main research object. According to the actual working conditions of NEV, the NHN insulating paper was applied bipolar repeated square waves, and its partial discharge inception voltage (PDIV) under different air pressures was measured. The PDIV value under standard atmospheric pressure was used as standard voltage, and 1.5 times of standard voltage was applied to the samples under different air pressures. The physical and electrical parameters of the samples under the condition of electrical ageing for 30 minutes and ageing to breakdown were measured, and the ozone content generated during the electrical ageing process was detected. The results show that the PDIV value of the main insulation sample decreases significantly under low pressure, and when the applied voltage is greater than the PDIV, the sample surface is corroded more severely compared with the plain area, leading to the sample break down easier. During the electrical ageing process with the same time and voltage, the electrical parameters of the samples under low pressure have bigger change, the ozone production rate of partial discharge is faster, the corrosion of the material is intensified, and the deterioration of insulating properties is more serious. Based on above studies, the influence of altitude factors on the corona resistance performance of insulating materials should be fully considered when designing the insulation system of motor for NEV.
Medium frequency transformers have high power density, small volume, complex winding structure, and strong local electrical stress, so the design of transformer must fully consider the electro-thermal stress margin to ensure reliability. In this paper, the method of adding electrostatic ring and angle ring were proposed to suppress the electric field strength at the end of primary winding, and the electric field strength distribution of multi-winding transformer was calculated by electrostatic field finite element analysis method. Combined with the sensitivity analysis method, the influence of the size parameters of electrostatic ring and angle ring on the electric field strength was studied to determine the decisive factors of the maximum electric field strength. The response surface function related to electric field strength was constructed by response surface method to optimize the insulation structure of transformer. The results show that the optimal sizes of electrostatic ring and angle ring are obtained by the above response surface function through taking a 50 kW, 10 kHz multi-winding medium-frequency transformer as an example, which can reduce the maximum electric field strength by 15.4% and 17.49% under short-term power frequency withstand voltage test and rated operating conditions, respectively. It is proved that the response surface method can be applied to the insulation structure design of multi-winding transformer.
Inter-turn short circuit is the main fault type of dry-type air-core reactors. At present, there is a lack of effective offline detection method to discover potential faults in time before dry-type reactors put into operation. Based on the theory of multiconductor transmission line, a distributed parameter model of dry-type air-core reactor winding was built to simulate the refraction and reflection processes after pulse signal injection, and the influence law of inter-turn short circuit on the response signal at the head and end of winding was discussed. On this basis, a characteristic waveform was constructed by the integral value of response signal absolute value, and a characteristic value was extracted to diagnose the inter-turn insulation state of winding. The results show that the test results of four-eigenvalue method proposed in this paper based on the wave process and multiconductor transmission line theory are consistent with the simulation results. Through the simulation calculation of different structural reactor models, it is found that the eigenvalue change trend of different structural reactor is also consistent when the inter-turn short circuit fault occurs. Therefore, the above method can be applied to diagnoze the inter-turn short circuit fault of reactors with different structures. The research results can provide guidance for the diagnosis of the severity and regional localization of inter-turn short circuit in dry-type air-core reactor.
Partial discharge (PD) phenomenon in power transformer is not only the main cause of insulation deterioration, but also the characteristic parameter to characterize the insulation condition. It is of great significance to accurately recognize the type of PD for the diagnosis of transformer insulation condition. A new method for identifying the type of multi-source PD spectrum based on Faster-RCNN algorithm was proposed in this paper, which can detect different types of PD clusters from multi-source spectrum. The results show that the average recognition accuracy of multi-source PD reaches 72.1% when the proposed algorithm was applied to the PD spectrum obtained from 35 kV transformer. Because the air gap defect has dense PD points and obvious characteristics, its missed and false detection rates are lower than other defects, leading to there be good discrimination for the air gap defect. Because the tip defect has the characteristics of intermittent discharge and high initial discharge voltage, its missed detection rate is high.
Partial discharge type is closely related to the early insulation deterioration degree of power capacitor film. The accurate identification of partial discharge type will effectively improve the operation state of capacitor and guarantee the safety of power grid. In this paper, the models of inter-film tip defects, air gap defects, and surface defects generated easily in metallic film capacitor were designed. The time series and phase distribution spectra characteristics of partial discharge in capacitor film and the development of average discharge quantity Q and discharge repetition rate F were analyzed. The curves of Q and F were fitted with points, and the correlation between them and partial discharge signal was analyzed. The correlation coefficient was taken as the characteristic parameter of time domain. The skew, steepness, and asymmetry of partial discharge phase distribution spectra were extracted as phase characteristic parameters. A partial discharge pattern recognition method of power capacitor film based on time-phase synthetic radar spectrum was proposed. The barycentric coordinates of the enclosed rectangle of characteristic parameters closed graph in the synthesis spectrogram were conducted cluster analysis, and the distribution quadrants of barycentric coordinates were used to recognize the partial discharge pattern of film. The results show that the method has more pattern recognition accuracy than the traditional single spectrum, which provides a theoretical basis for online monitoring and fault diagnosis of capacitor equipment.
High voltage cable fusion joint with defects operating for a long time is easy to cause operation failure. In order to timely troubleshoot the joint defects, we taked high-voltage cable fusion joints as research object. The main insulation and conductor recovery process of high-voltage cable fusion joint was detected by digital radiography (DR) technology, and the bending limit of conductors was analyzed by finite element method. The results show that the DR detection technology can effectively detect bubbles, conductor bending, eccentricity and other defects in the XLPE main insulation of fusion joint. The accuracy of detection results is demonstrated by field dissection, which provides an effective means for the defect detection of high voltage cable fusion joint. The bubble defect of XLPE main insulation is caused by the decrease of temperature and nitrogen pressure in the crosslinked pipeline. Considering the safety margin of the joint, it is recommended that the bending gap should not exceed 11 mm and the insulation thickness at the bending position should not be less than 30 mm.
In order to effectively adsorb the corrosive sulfur in transformer oil, XDK was used as adsorption material, and dibenzyl disulfide (DBDS) was used as the experimental object. The test oil was prepared by adding DBDS to new transformer oil. The removal effect of XDK on DBDS in test oil was studied under different adsorption conditions and regeneration conditions. The structure of XDK was characterized by scanning electron microscopy (SEM), thermogravimetry (TG), and specific surface area analyzers (BET). The results show that the optimal regeneration temperature of XDK is 600℃, and the regeneration XDK still has good adsorption effect after four times. When the XDK mass fraction is 10%, the adsorption times are two times, the adsorption temperature is 10℃, and the adsorption times is 2 h, the DBDS removal rate reaches 96.9%, the dielectric constant, breakdown voltage, and volume resistivity of the insulating oil after treated increases by 0.31%, 5.3 kV, and 0.23 Ω·m, respectively, and the dielectric loss factor decreases by 0.21%.