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  • Die HU, Fan MO, Jiada WEI, Kang LI, Liujie WAN
    Insulating Materials. 2023, 56(11): 80-86.

    The study on the gas production law of stator bar for hydrogenerator under high temperature and partial discharge can provide a basis for insulation ageing monitoring of hydrogenerator on the basis of decomposition gas method. Aiming at the stator bar used in hydropower station, a high temperature pyrolysis experimental platform was built to study the pyrolysis gas of stator bar at 100, 120, 150 and 250℃. A partial discharge experimental platform of stator bar was established to study the ozone generation law of stator bar under partial discharge. The results show that CO and CO2 are suitable used as the early characteristic gases of stator bar with high temperature fault. When there is partial discharge on the stator bar surface, the ozone concentration is related to discharge voltage and time. Under the same discharge condition, the ozone concentration rate generated by semi-conductive silica gel is higher and it has stronger corona resistance. Filling stator slot with semi-conductive silica gel is beneficial to the safe operation and on-line monitoring of stator bar.

  • Anqiang LÜ, Ting LI
    Insulating Materials. 2023, 56(11): 110-116.

    In the process of transportation and laying, the submarine cable will inevitably be twisted. If the twisting angle is too large, it will cause irreparable damage for the submarine cable. In this paper, a torsion model of submarine cable was established by finite element method, and the characteristic parameters that can effectively reflect the mechanical characteristics of submarine cable were determined by analyzing the temporal and spatial distribution characteristics of stress and strain. The threshold values of each characteristic parameter when torsion failure occured were established, and the mechanical parameter system that can represent the torsion behavior of submarine cable was established. The results show that the axial stress distribution of the submarine cable is more uniform at the initial stage of torsion. With the increase of torsion angle, the axial stress distribution of cable body will fluctuate. A parametric system including copper conductor stress, XLPE insulating layer stress, lead alloy stress, armor layer stress, and torsion angle can be established for parametric evaluation of submarine cable torsion behavior.

  • Guangwei LIU, Yu GUAN, Ming DONG, Xinsheng MA, Yunpeng TANG, Boyan LIU, Yi LU
    Insulating Materials. 2023, 56(11): 7-15.

    The characteristics and research methods of transformer interturn breakdown, detection and protection and characteristics of interturn fault were introduced in this paper, and the research direction of transformer interturn fault was prospected, which can provide reference for the academic research and operation and maintenance of transformer interturn fault.

  • Xuechao HU, Shouhong XUE, Liqiang SUN, Lixia WU, Jiang LIU, Zhiping ZHU
    Insulating Materials. 2023, 56(11): 47-52.

    In order to study the effect of antioxidant types in transformer oil on the thermal ageing performance of insulating paper, antioxidants T501, T531, and DBP were added to the insulation system composed of naphthenic mineral oil and insulating paper, and the antioxidant mass fraction was 0.4%. The heat ageing test was carried out at 130℃ for 600 h. The moisture and furfural content in the insulating oil, the moisture content and polymerization degree in the insulating paper were determined every 120 h. At the same time, the aged insulating paper was characterized by FTIR, XRD, SEM, and EDS. The results show that the addition of antioxidant T501 and T531 have little effect on the deterioration of insulating paper, and the deterioration of insulating paper in the oil with antioxidant DBP is aggravate in the late ageing stage. Since the antioxidant T531 has a combination of neutralization and hydrolysis, it inhibits the degradation process of cellulose, and the ageing degree of T351 insulating paper is the lightest.

  • Manqing ZHAO, Yang WANG, Jianfei LI, Qiankai ZHANG, Huaqiang LI, Qingdong ZHU
    Insulating Materials. 2023, 56(11): 57-64.

    The nanomolecular model of TiO2/vegetable oil interface structures before and after modification of two silane coupling agents (KH570 and KH792) were established by molecular dynamics simulation, and the effect of TiO2 interface before and after modification with silane coupling agents on the diffusion behavior of water molecules in oil were further investigated by dynamics simulation. The results show that compared with the untreated TiO2, the modified TiO2 interface has stronger adsorption of water molecules, which inhibits the migration behavior of water molecules in the oil, resulting in the significant reduction of their diffusion coefficient, thus reducing the formation of “small bridges” of water molecule impurities in the oil, and improving the insulating properties of vegetable insulating oil. Among them, the modification effect of KH792 is more significant. Further, by calculating the interaction energy between water molecules and TiO2 interface system, the number of hydrogen bonds form and the free volume fraction, the causes and physical mechanisms of above phenomena are explain, which provides theoretical support for the study of nanoparticle doping to improve the insulating properties of vegetable insulating oil.

  • Zhan ZHOU, Jian WANG, Guisheng GONG, Xue LI, Guixia SONG, Jiejun LIU, Yunong LÜ
    Insulating Materials. 2023, 56(11): 23-27.

    A halogen-free flame retardant unsaturated polyester insulating impregnating resin was prepared by introducing DOPO into unsaturated polyester. The effect of adding flame retardant on the properties of the resin were analyzed by infrared spectroscopy, thermogravimetric analysis and flame retardancy experiment. The results show that the addition conversion rate of DOPO can be improved by using methyl tetrahydrophthalic anhydride (MTHPA) as the carrier to react with DOPO first and then with maleic anhydride (MA). The prepared resin is uniform, transparent after curing, and has good flame retardance, which can reach UL94 V0 level. With the increase of phosphorus content, the thermal stability of resin decreases, and the optimal phosphorus content is about 2.7%. When the molar ratio of unsaturated acid to saturated acid is 1∶1 to 1.5∶1 and using the compound initiation polymerization system, the resin has good reactivity and storage stability.

  • Xiaoyu HUANG, Wenting WANG, Yuyang JIAO, Ran JI, Jian GAO
    Insulating Materials. 2023, 56(11): 41-46.

    A thermochromic microcapsule epoxy resin composite insulation material (TEP) was prepared, and its power frequency permittivity (εr), dielectric loss factor (tanδ), and DC conductivity (σ) were analyzed in this paper. The results show that the temperature characteristic of dielectric constant of composite insulation material has an infelction point at 70℃. When the temperature is lower than 70℃, εr increases rapidly with the increase of temperature. When the temperature is higher than 70℃, the change rate of εr with temperature decreases significantly. The tanδ decreases significantly when the temperature is 50-70℃. The addition of thermochromic microcapsules can effectively reduce the DC conductivity of composite insulation material. In the thermochromic temperature range of 50-70℃, the solid-liquid phase transition occurs inside thermochromic microcapsules, which is the main reason for the special temperature characteristics of εr and tanδ. In the solid-liquid phase transition process, the molecular activity of the core material in microcapsule increases gradually, and the resistance that it needs to overcome in the orientation polarization with the external electric field decreases, resulting in the rapidly increase of εr and the significant decrease of tanδ with the increase of temperature. When the core materials of microcapsule are fully transformed to liquid state, its molecular activity decreases with temperature, leading to the significant decrease of εr with temperature.

  • Guanfang LIU, Xiaoqiang ZHANG, Jiexin FAN, Xiaomei PEI
    Insulating Materials. 2023, 56(11): 53-56.

    In order to study the influence of humid environment on the insulating performance of traction motor stator, we took the newly manufactured and overhauled stator winding of traction motor with silicone insulation system as the research object. The damp heat tests were carried out on the stator winding and its end, the insulating performance of the insulation system before and after moisture absorption were tested, and the main ways of moisture penetration into the insulation system were analyzed. The results show that the insulation resistance of the stator winding insulation system decreases after the damp heat test. The weakest part in the wet environment is the connection welding part of the end winding insulation, which is the main way of moisture to penetrate into the insulation system. Once this moisture channel is formed, it is easy to dry, but in the humid environment, the moisture will enter the channel and cause the insulation resistance decrease. After long term operation, the insulation performance of stator winding will decrease due to humidity.

  • Xiajin RAO, Xiaoxing ZHANG, Dajian LI, Lei ZHANG, Boya PENG, Wei HUANG
    Insulating Materials. 2023, 56(11): 87-93.

    C6F12O is a potential substitute gas for SF6. To explore the decomposition characteristics of C6F12O/CO2 mixed gas under floating electrode defect and different partial discharge intensity, a partial discharge decomposition test platform was built, and 96 h partial discharge decomposition experiments were conducted on C6F12O/CO2 mixed gas under different applied voltages. The decomposition components were quantitatively analyzed by gas chromatography. The relationship between the decomposition components content, gas production rate, characteristic gas ratio and partial discharge intensity was studied respectively. The results show that the change rule of concentration, gas production rate of four typical products (CF4, C2F6, C3F8, C3F7H) are different, which can be used as the characteristic component to judge the partial discharge intensity. The concentration relationship of characteristic components is c(CF4)>c(C2F6)≈c(C3F8)>c(C3F7H), and the gas production rate relationship is similar. The concentration of characteristic components shows a “linear-saturated” growth with the increase of discharge intensity. It is preliminarily suggested that using c(CF4)/c(C3F7H) as the auxiliary basis, and c(CF4+C2F6+C3F8)2/c(C3F7H)2 as the main basis, the PD intensity and defect severity can be judged combined with component content and gas production rate, which provide reference for finding out the operation and maintenance monitoring methods applicable to C6F12O/CO2 mixed gas insulation equipment.

  • Yulai ZHAO, Xuyang WU, Jiancong ZHANG, Jingchao DU, Wang ZHOU, Gaohui HE
    Insulating Materials. 2023, 56(11): 65-72.

    In this paper, the effect of electrical parameters of the semi-conductive layer on the surface electric field distribution of post insulator used in substation was calculated and analyzed by COMSOL. The results show that the semi-conductive layer can weaken the maximum electric field caused by water droplets, wet pollution, and dry pollution to different degrees, and the wet pollution is the most significant, with the electric field decreasing amplitude of 41.58%. Coating semi-conductive layer at the high voltage terminal has a significant improvement effect on the electric field, and the maximum decreasing amplitude of surface maximum electric field is 14.5% compared with not coating semi-conductive layer. When the high and low voltage terminals are coated by semi-conductive layer with the best relative dielectric constant, the comprehensive balance of electric field improvement is better. In the normal range of porcelain electrical parameters, the optimal electrical parameters of semi-conductive layer are universal, the relative dielectric constant of the optimal semi-conductive layer at high voltage terminal is 22, and the relative dielectric constant of that at low voltage terminal is 12. In addition, the resistivity of the semi-conductive layer at high and low voltage terminals should be at least greater than 1×107 Ω·m and 6×107 Ω·m, respectively, and the maximum electric field will be less than the case without semi-conductive layer.