In order to explore the generation mechanism of perfluoroisobutyronitrile (C₄F₇N) gas decomposition products under the presence of micro-water, the decomposition process of C₄F₇N gas and the recombination process after decomposition were investigated when micro-water participated in the reaction. On the basis of density functional theory and transition state theory, the thermodynamic parameters of C₄F₇N gas under micro-water participation reaction conditions, as well as the generation paths and generation rates of some characteristic products, were calculated. The results show that when micro-water participates in the reaction, the activation energy required for the decomposition of C₄F₇N gas is lower than that required for the decomposition of dry C₄F₇N gas. The presence of micro-water makes the C₄F₇N decompose easier. The reaction rate constant of CHF₃ gas is relatively high in the decomposition products of C₄F₇N gas, and its chemical properties are stable and detectable, which can be used as a characteristic product of C₄F₇N gas decomposition under the presence of micro-water.

C₄F₇N/CO₂/O₂ gas mixture is one of the promising environmentally friendly gas insulation medium to replace SF₆ currently. At present, there is relatively little research on the influence mechanism of the additional buffer gas O₂ and its content variation on the decomposition characteristics of C₄F₇N/CO₂/O₂. In this paper, on the basis of reactive molecular dynamics (ReaxFF-MD) method, a reaction system model of C₄F₇N/CO₂/O₂ gas mixture was constructed to simulate the thermal decomposition process of C₄F₇N gas mixture at different O₂ content and temperature, and the main reaction pathways, product composition and generation rate were analyzed. The results show that the C₄F₇N/CO₂/O₂ gas mixture mainly generates CF₃, CF₂, CF, F, C₂F₅, and CN after thermal decomposition, among them, the generation amount of CF₂ and CF is the highest, followed by CF₃ and F. Although the addition of O₂ to C₄F₇N/CO₂ gas mixture will decrease the initial decomposition time of C₄F₇N, it can effectively reduce the decomposition amount of C₄F₇N and the generation amount of most particles. Especially when the volume fraction of O₂ is 6%, the decomposition amount of C₄F₇N is the least. When the volume fraction of O₂ is 0%-4%, the reaction rate of the main decomposition reaction in the reaction system decreases, while the reaction rate increases when the volume fraction of O₂ is greater than 8%. When the simulation temperature is higher than 2 600 K, the initial decomposition time of C₄F₇N is significantly shortened and the generation rate of decomposed particles is accelerated. The research conclusions provide a theoretical basis for the application ratio optimization of C₄F₇N/CO₂/O₂ and the operation maintenance and diagnosis of its equipment.

A clean air insulation defect decomposition experimental device was constructed based on gas component analysis method, then the main characteristic decomposition components of clean air under different discharge form (spark discharge and corona discharge) and different gas pressure were detected and analyzed by Fourier transform infrared spectroscopy (FTIR). The basic reaction principles and pathways of the main decomposition components were explored, and the effects of different pressures on the partial main characteristic decomposition components of clean air were analyzed quantitatively or qualitatively. The results show that the main characteristic decomposition products of clean air under spark discharge are NO₂, NO, and N₂O₄, and the main characteristic decomposition products under corona discharge are O₃, N₂O₅, and N₂O. The increase of gas pressure can affect the generation ratio of NO and NO₂ under the spark discharge, the proportion of NO is lower in high gas pressure range, and the NO selectivity increases with the decrease of gas pressure. The concentrations of O₃, N₂O₅, and N₂O generated under corona discharge show an overall trend of increase at first and then decrease with the increase of gas pressure under a same voltage level, and the generation of N₂O₅ has a strong correlation with the concentration of O₃.

The adsorption of CF₃SO₂F gas on the surface of Al(111) and its decomposition mechanism were studied based on density functional theory. The adsorption energy, charge transfer, differential charge density, electron localization function (ELF), and state density of CF₃SO₂F gas on the surface of Al(111) were calculated, and the compatibility between CF₃SO₂F gas and Al(111) surface was analyzed theoretically. Further, a theoretical calculation model of the decomposition path of CF₃SO₂F gas was established to calculate the free energy of CF₃SO₂F gas under different decomposition paths, and the main decomposition products of CF₃SO₂F gas were obtained through transition state analysis. The results show that CF₃SO₂F gas has good compatibility with Al(111) surface under normal operating conditions, and their interaction is physical adsorption. The typical decomposition gas products of CF₃SO₂F gas mainly include CF₄ and SO₂. The research results can provide theoretical reference for evaluating the gas-solid compatibility and stability of the new environmentally friendly insulating gas CF₃SO₂F.

C₄F₇N will produce harmful decomposition by-products during discharge or overheating faults, especially C₂F₆ and C₃F₈, which have relatively large amount of production and pose a threat to the safe operation and service life of gas insulated equipment. Therefore, it is necessary to control and handle them. In this paper, the adsorption energy, charge transfer, and adsorption distance of C₂F₆ and C₃F₈ on γ-Al₂O₃(110) surface were studied, and a state density analysis was conducted to evaluate the possibility of γ-Al₂O₃ as a by-product adsorbent. The results show that the γ-Al₂O₃ surface has strong adsorption capabilities for C₂F₆ and C₃F₈, and the adsorption energies reaches -0.5744 eV and -2.819 eV, respectively, showing strong adsorption effects. Particularly, the adsorption configurations at Al sites show higher stability and strong charge transfer phenomenon, indicating that the two gases have strong interaction with γ-Al₂O₃. The state density analysis further confirms that the adsorption of C₂F₆ and C₃F₈ not only alters the electronic states on the γ-Al₂O₃ surface, but also influences its electronic and chemical properties, which provides theoretical support for using γ-Al₂O₃ as a by-product adsorbent for C₄F₇N.

Heptafluoroisobutyronitrile (C₄F₇N) has excellent insulation properties and low greenhouse effect, and is currently the mainstream environment-friendly gas used for electrical equipment insulation. Because of the large differences in physical and chemical properties between C₄F₇N and SF₆, the current SF₆ detection technology and equipment can not meet the application requirements of C₄F₇N gas mixture. In this paper, the detection method of C₄F₇N/CO₂ gas mixture was studied by referring to the live detection technology of SF₆ gas in operating equipment. The field detection schemes were proposed, which included using gas chromatography to detect purity and composition of gas based on high-precision helium ionization detector, using thermal conductivity principle to detect C₄F₇N ratio, using resistance capacitance sensor method to monitor micro-water content, and using non-spectral infrared technology combined with Lambert-Bill rule to quantitatively monitor gas leakage fault, and the corresponding detection devices were developed to carry out the detection and verification test for gas state. The results show that all detection schemes have high detection accuracy and can support the operation and maintenance testing and field application of C₄F₇N environment-friendly electrical equipment.

The influence mechanism of thermal-cooling cycling times and temperature change rate on the electrical properties of epoxy resin were studied using a linear rising and cooling method. The results show that as the cycle times increases, the DC electric strength and volume resistivity of epoxy resin increase at first and then decrease, and this trend slightly increases in early cycles with the increase of temperature change rate, but decreases significantly in later cycles. The analysis indicates that thermal and cold alternating environment will promote the dynamic adjustment of chain segments in epoxy resin, making its structure more compact and regular. Although thermal expansion and cold contraction may cause micro-cracks appear on the surface of epoxy resin during early cycles, dynamic adjustment plays a dominant role, which leads to the improvment of electrical properties of epoxy resin. However, with the increase of cycle times, long-term thermal expansion and cold contraction intensifies the fracture of molecular chain segments and the expansion of micro-crack, resulting in the decrease of electrical properties of epoxy resin. With the increase of temperature change rates, the internal chain segment in epoxy resin cannot be fully adjusted, and the impact of temperature stress increases, which lead the epoxy resin more prone to deterioration.

Regarding the internal carbonization creepage defect of composite insulator, a finite element model of electromagnetic and thermal coupling calculation for FXBW-500 large-small-small shed type composite insulator was established, and the influencing laws of defect location and surface pollution on the temperature rise caused by internal carbonization creepage defect in core rod were analyzed. The results show that when there is a local carbonization creepage defect at different positions of composite insulators, the local temperature rise from high to low is high voltage end, low voltage end, and middle end. When there is pollution, the temperature distribution of the carbonization creepage defective insulator does not change significantly, but the maximum temperature rise values of each part all increase significantly, among which the maximum temperature rise of high voltage end increases from 9.3℃ to 18.2℃, and the temperature rise along the surface increases from 2.52℃ to 4.94℃. Although the existence of pollution makes the overall temperature of the insulator rise, it still does not conceal the temperature jump at the defect location. Therefore, when the location of carbonization creepage defects are identified through temperature, the temperature jump can be taken as a reference.

Firstly, the physico-chemical characteristics of the decay-like core rod were analyzed, and the effect of decay-like on the mechanical properties of the core rod was studied. And then, the vibration modes of composite insulator core rods were analyzed by simulation, and the relationship between characteristic frequency and the decay-like degree was studied. Finally, a vibration excitation detection method was proposed for decay-like composite insulator, and the characteristic frequencies of the 110 kV composite insulators with different degrees of decay-like defects were measured and analyzed. The results show that the complete degradation of epoxy resin and the hydrolysis and pulverization of glass fibers in the core rod make the decay-like region loss mechanical properties, leading to the decrease in the overall stiffness, tensile resistance, and deformation resistance of the core rod. Compared with the intact core rod, the characteristic frequencies of 3-5 order vibration mode of decay-like core rod decrease by 2.8%-14.3%, the decreasing range of characteristic frequencies of higher order vibration modes decrease more obvious, and the decreasing range increases with the increase of decay-like degree. The decay-like detection method based on vibration mode can diagnose the decay-like degree of composite insulator, and also can reflect the changes of its mechanical properties, which is suitable for non-destructive detection of decay-like in composite insulators.

To resolve the issue that the traditional frequency domain reflection (FDR) method is easy to misjudge when diagnosing the moisture defects of cable joints, the influence law of thermal excitation on the characteristic impedance of moistened cable joints was firstly analyzed in this paper, and a diagnostic method for moisture in cable joints was proposed based on the frequency domain reflection characteristics under thermal excitation. Then a moistened joint was set up on a 10 kV XLPE cable with a length of 58 m, the temperature of the moistened joint was changed using a heating belt, and the moisture defects were located and diagnosed. The results show that when applying the thermal excitation, the unit capacitance and characteristic impedance of the cable body and normal joint hardly change with the temperature, the unit capacitance of the moistened cable joint decreases with the increase of temperature, and the characteristic impedance increases with the increase of temperature. The simulation results show that the amplitude of the frequency domain reflection spectrum at the moistened joint increases with the increase of temperature, while the amplitude of the frequency domain reflection spectrum at the normal joint is basically unchanged. Based on the above research results, the amplitude changes of the true cable reflection coefficient spectrum at the joint under different temperatures were obtained through thermal excitation, achieving the localization diagnosis of moisture defects.