收藏切换
Study on compatibility between CF3SO2F gas and Al(111) surface and its decomposition characteristics
收藏切换
PDF
Xingfa CHEN1, Yu ZHENG2, Shubo REN2, Yapeng XIAO2, Dongxin HAO2
Insulating Materials | 2025, 58(2) : 66 - 75
Less
收藏切换
Insulating Materials | 2025, 58(2): 66-75
Special Issue on Eco-friendly Insulating Gas
Study on compatibility between CF3SO2F gas and Al(111) surface and its decomposition characteristics
Full
Xingfa CHEN1, Yu ZHENG2, Shubo REN2, Yapeng XIAO2, Dongxin HAO2
Affiliations
  • 1Construction Branch of Inner Mongolia Power Co., Ltd., Hohhot 010020, China
  • 2School of Electrical Engineering and Automation, Wuhan University, Wuhan 430072, China
Published: 2025-02-20 doi: 10.16790/j.cnki.1009-9239.im.2025.02.010
Outline
收藏切换

The adsorption of CF3SO2F gas on the surface of Al(111) and its decomposition mechanism were studied based on density functional theory. The adsorption energy, charge transfer, differential charge density, electron localization function (ELF), and state density of CF3SO2F gas on the surface of Al(111) were calculated, and the compatibility between CF3SO2F gas and Al(111) surface was analyzed theoretically. Further, a theoretical calculation model of the decomposition path of CF3SO2F gas was established to calculate the free energy of CF3SO2F gas under different decomposition paths, and the main decomposition products of CF3SO2F gas were obtained through transition state analysis. The results show that CF3SO2F gas has good compatibility with Al(111) surface under normal operating conditions, and their interaction is physical adsorption. The typical decomposition gas products of CF3SO2F gas mainly include CF4 and SO2. The research results can provide theoretical reference for evaluating the gas-solid compatibility and stability of the new environmentally friendly insulating gas CF3SO2F.

CF3SO2F gas  /  Al(111) surface  /  density functional theory  /  gas-solid compatibility  /  decomposition characteristics
Xingfa CHEN, Yu ZHENG, Shubo REN, Yapeng XIAO, Dongxin HAO. Study on compatibility between CF3SO2F gas and Al(111) surface and its decomposition characteristics[J]. Insulating Materials, 2025 , 58 (2) : 66 -75 . DOI: 10.16790/j.cnki.1009-9239.im.2025.02.010
Year 2025 volume 58 Issue 2
PDF
161
78
Cite this Article
BibTeX
Article Info
doi: 10.16790/j.cnki.1009-9239.im.2025.02.010
  • Receive Date:2024-08-26
  • Online Date:2025-11-06
  • Published:2025-02-20
Article Data
Affiliations
History
  • Received:2024-08-26
  • Revised:2024-09-06
Funding
Affiliations
    1Construction Branch of Inner Mongolia Power Co., Ltd., Hohhot 010020, China
    2School of Electrical Engineering and Automation, Wuhan University, Wuhan 430072, China
References
Share
https://castjournals.cast.org.cn/joweb/jycl/EN/10.16790/j.cnki.1009-9239.im.2025.02.010
Share to
QR

Scan QR to access full text

Cite this article
BibTeX
Citations
表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
关闭全屏
  • BibTeX
  • EndNote
  • RefWorks
  • TxT