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2024 Volume 57 Issue 11  Published: 2024-11-20
    Special Issue on Key Materials and Technology for New Energy Vehicles
  • Guangya ZHU , Muhong LIN , Guodong LIU , Peng WANG
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.001

    The motor is the key drive component of new energy vehicles, and the insulation system is an important guarantee for motor reliability. Once the motor insulation fails, it will pose a threat to the safe operation of the vehicle. The severe electric heating stress is the main factor causing insulation failure, so it is of great significance to test the motor insulation level under complex pulse parameters and environmental conditions. This paper had reviewed the latest research results at home and abroad from several aspects of performance evaluation methods and influencing factors, voltage distribution calculation, and weak spot location of new energy vehicle drive motor insulation system. Combined with the development trend of voltage level improvement, power density improvement, breaking frequency improvement, and switching speed increase, the problems and challenges faced by insulation evaluation of variable frequency motor were pointed out, which provided reference for the future research in this field.

  • Special Issue on Key Materials and Technology for New Energy Vehicles
  • Tiandong ZHANG , Haixin MA , Gang LIU , Cheng YAO , Hai SUN , Chao YIN , Changhai ZHANG , Qingguo CHI
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.002

    In recent years, with the rapid development of new energy vehicles and flexible direct current transmission projects, and other fields, there was an increasing demand for the metallized film capacitors with high volume ratio and high temperature resistance. Especially under extreme conditions such as high temperature and high electric field, higher requirements were put forward for the electrical performance of dielectric films in capacitors. In this paper, the current research status and development trend of dielectric film materials for metallized film capacitors in recent years were summarized. Firstly, the key factors affecting the energy storage performance of dielectric films were introduced and the failure reasons of metallized film capacitors under operating conditions were analyzed. Secondly, the modification methods of energy storage performance for dielectric films designed on the basis of four aspects, such as molecular chain structure, aggregation state structure, doping of functional fillers, and surface modification were summarized. Finally, the strategies to improve the energy storage performance of dielectric films of metallized film capacitors were summarized and prospected.

  • Special Issue on Key Materials and Technology for New Energy Vehicles
  • Lihua ZHAO , Fuli TENG , Jia WEI , Meng GAO , Chao BIAN , Ran ZHUO , Qiuwanyu QING , Junwen REN
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.003

    An ANF/mica composite insulating paper was prepared by vacuum assisted filtration and hot pressing technology taking aramide nanofiber (ANF) as matrix and natural mica (mica) as filler. The microscopic morphology, tensile strength, electrical insulation properties, and temperature resistance of the composite insulating paper were studied systematically. The results show that the mica and ANF are superimposed in order during vacuum filtration process, and the mica fragments fill the gaps in paper effectively, creating a dense "brick-and-mortar structure", which significantly enhances the electric strength and insulating properties of the composite insulating paper. Furthermore, the glass transition temperatures of pure ANF insulating paper and ANF/mica-10 composite insulating paper are higher than 300℃, exhibiting excellent thermal stability. Although the addition of mica slightly reduces the tensile properties of pure ANF insulating paper, its insulation strength and tensile performance remain superior to traditional mica paper.

  • Special Issue on Key Materials and Technology for New Energy Vehicles
  • Jiujun ZHU , Zhibiao ZHU , Tingyu FU , Yafei HOU
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.004

    Excessive free electrons in thin film capacitors will increase the leakage current density, reduce the electric strength, and promote the breakdown of capacitors, thus preventing them from obtaining excellent energy storage performance. To mitigate the impact of free electrons and secondary impact ionization electrons (SIE) on energy storage performance, this study introduced perylene diimide (PDI), 1,4,5,8-naphthalenetetracarboxylic dianhydride (NDI), and 4-cyano-4′-pentylbiphenyl (5CB) into polyvinylidene-hexafluoropropylene (PVH) to construct an all-organic composite films, respectively, and the structure, thermal properties, and energy storage performance of three kinds of films were studied. The results show that PDI/PVH composite film with PDI mass fraction of 0.5% has the better thermal properties, smaller grain size, and tighter lattice structure, which is helpful to achieve higher electric strength and discharge energy density. Through comparison, it is found that PDI possesses a more suitable band structure and conductivity, which makes PDI/PVH composite film have better energy storage performance. The discharge energy density of 0.5%PDI/PVH composite film achieves 16.6 J/cm3 at 499.7 MV/m, and maintains a high charge-discharge efficiency of 80.5%.

  • Special Issue on Key Materials and Technology for New Energy Vehicles
  • Junwen REN , Chao BIAN , Jia WEI , Ran ZHUO , Qiuwanyu QING , Meng GAO , Fuli TENG , Shenli JIA
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.005

    The one-dimensional ANF and two-dimensional edge-hydroxylated BNNS (BNNS-OH) were mixed to prepare ANF/BNNS-OH composite insulating papers with “brick -mud” structure by vacuum filtration technology. The mechanical properties, thermal conductivity, dielectric properties, and breakdown properties of the composite insulating paper were studied. The results show that the BNNS-OH arranges in ANF orderly, and the structure is dense. The ANF/BNNS-OH composite insulating paper has excellent mechanical properties, thermal conductivity, and breakdown properties. When the mass fraction of BNNS-OH is 10%, the tensile strength and electric strength of the composite insulating paper are 242.4 MPa and 312.9 kV/mm, respectively. When the mass fraction of BNNS-OH is 40%, the thermal conductivity of the composite insulating paper reaches 6.76 W/(m·K), which is 158.02% higher than that of pure ANF insulating paper. At same time, the composite insulating paper has excellent high temperature wideband dielectric stability.

  • Special Issue on Key Materials and Technology for New Energy Vehicles
  • Yin JIANG , Cheng GU , Yuxuan GU , Xuefeng ZHUANG
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.006

    Using bisphenol A and bisphenol F epoxy resin as main resin, aluminum hydroxide and spherical silicon micro powder as fillers, combined with anhydride curing agent and epoxy toughening agent, a film capacitor epoxy potting material for new energy vehicle was prepared, and the effects of each component on the properties of potting materials were analyzed. The results show that the film capacitor epoxy potting material for new energy vehicles prepared by optimized formula has high glass transition temperature, good mechanical properties, good adhesion performance, small linear expansion coefficient, and the performances of capacitors are excellent. The prepared potting material has comparable performance levels to similar potting materials abroad and is suitable for thin film capacitors used in new energy vehicles.

  • Special Issue on Key Materials and Technology for New Energy Vehicles
  • Junwen REN , Qiuwanyu QING , Jia WEI , Ran ZHUO , Fuli TENG , Meng GAO , Chao BIAN , Shenli JIA
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.007

    With the development of modern electrical equipment toward miniaturization, high-degree integration, and multi-functionalization, a large amount of heat accumulation will lead to insulation failure of electrical equipment. In order to develop a composite that can achieve high thermal conductivity even with low filler content (mass fraction<50%) and meet the strict requirement of current electrical equipment for heat dissipation, a composite insulating paper composed of aramid nanofibers and hydroxylated boron nitride nanotubes (BNNT-OH) was synthesized in this paper, and the effects of BNNT-OH content on the properties of composite insulating paper were studied. The results show that when the mass fraction of boron nitride nanotubes is 20%, the thermal conductivity of composite insulating paper is as high as 15.92 W/(m·K). The excellent thermal conductivity is due to the high intrinsic thermal conductivity of boron nitride nanotubes, and that the strong interaction between hydroxylated boron nitride nanotubes and aramid nanofibers reduces the interfacial thermal resistance.

  • Special Issue on Key Materials and Technology for New Energy Vehicles
  • Junsheng CHEN , Guodong LIU , Peng WANG , Chizhou CHENG , Dongtao WU , Yingwei ZHU
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.008

    Partial discharge inception voltage (PDIV) detection is an essential test method for evaluating the insulation performance of random wound inverter-fed motor stators. As an important parameter of pulse-width modulation voltage, the effects of pulse width on the PDIV of interturn insulation and interphase insulation in random wound inverter-fed motors are noteworthy. In this paper, the PDIV distribution laws of interturn insulation and interphase insulation in motor under different pulse widths were studied in the frequency of 50 Hz, rise time of 75 ns, and pulse widths within of 0.5-20 μs. The results show that when unipolar pulse square waves are input into random wound inverter-fed motors for PDIV testing, the overall trend of PDIV decreases as the input pulse width increases. Due to the combined effect of overvoltage from the rising and falling edges of short pulses, a turning point occurs in PDIV at a pulse width of 4 μs. It is necessary to consider the effects of pulse width and overvoltage and select appropriate pulse widths to obtain conservative values of stator insulation PDIV when conducting the PDIV test of interturn insulation and interphase insulation in random wound inverter-fed motor under unipolar pulse.

  • Special Issue on Key Materials and Technology for New Energy Vehicles
  • Jianting HONG , Tong AN , Zechao CHEN , Liqi LIU , Yuqing PENG , Aijun LI , Mengxin XU , Jinhe WANG
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.009

    A new type of ceramifiable intumescent fire protection coating was prepared by using epoxy resin as the matrix, ammonium polyphosphate as the flame retardant, zinc borate as the flux, and raw vermiculite powder and wollastonite as the refractory fillers. The effects of the compound of four fillers on the properties of ceramifiable intumescent fire protection coating were studied by scanning electron microscope (SEM) and fire resistance test. The results show that ammonium polyphosphate can significantly improve the expansion multiplication rate and thermal insulation performance, zinc borate can effectively enhance the strength and density of the charcoal layer, and raw vermiculite powder and wollastonite can enhance the burn-resistant performance of the charcoal layer and increase the fire resistance time limit at high temperature. When the mass ratio of ammonium polyphosphate, raw vermiculite, zinc borate, and wollastonite is 11∶5∶6∶10, the tensile shear strength is 7.8 MPa, the refractory performance is the best, the fire resistance time limit reaches 10 min, the maximum backsheet temperature is 393℃, and the charcoal layer after burning can withstand a voltage of 1.0 kV.

  • Material Research
  • Xiangyu TAN , Nianrong ZHOU , Guochao QIAN , Dada WANG , Xiaowei XU
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.010

    High temperature vulcanized (HTV) silicone rubber insulators and liquid silicone rubber (LSR) insulators are widely used in power system transmission lines. In order to compare the performance differences of HTV silicone rubber and LSR material for external insulation under typical formulas, the mechanical properties, electrical properties, and hydrophobicity of the two materials were tested. The results show that LSR has better mechanical and electrical properties than HTV silicone rubber. The initial hydrophobicity characteristics of HTV silicone rubber and LSR are similar. The crystallization temperature of LSR is lower than that of HTV silicone rubber, and the thermal stability is higher than that of HTV silicone rubber, which indicates that LSR is more suitable for operation in low temperature or high temperature outdoor environment.

  • Material Research
  • Chong ZHANG , Huize CUI , Ruilu GUO , Shuo CHEN , Wenpeng LI
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.011

    A glass fiber winding reinforced epoxy resin composite with high thermal conductivity was prepared by filling the bisphenol A type epoxy resin system with a mixture of alumina and silica powder fillers. The effects of filler content on the mechanical properties, electrical properties, and thermal conductivity of composite were studied. The results show that the addition of mixed fillers is beneficial for improving the thermal stability and thermal conductivity of the composite. When the mass fraction of the fillers is 62% (of which the mass fraction of silicon powder is 48% and the mass fraction of alumina is 14%), the tensile strength (0° and 90° directions), bending strength, and NOL ring tensile strength of the composite are 160.25, 24.50, 245.40, and 134.30 MPa, respectively. The dielectric constant is 1.889, the dielectric loss factor is 0.673×10-2, the volume resistivity is 3.36×1016 Ω·cm, and the thermal conductivity is 1.257 W/(m·K), which is 155% higher than the thermal conductivity before addition.

  • Material Research
  • Xiaoqiong ZHI , Anbin TANG , Xiuyun LI , Jie HUANG , Ting PANG , Xi LIAO
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.012

    A high heat resistant o-allylphenol-dicyclopentadiene epoxy resin was synthesized using dicyclopentadiene, o-allylphenol, and epichlorohydrin as raw materials, and its structure was characterized by infrared spectrum and gel chromatography. Then the epoxy resin was cured with bisphenol-A phenolic resin, benzoxazine resin, and active ester respectively, and a PCB substrate was pressed. The curing behavior of the system was studied by differential scanning calorimetry and thermogravimetric analysis. The mechanical properties, dielectric properties, and water absorption properties of the PCB substrate were tested, and compared with the curing system of phenol-dicyclopentadiene epoxy resin. The results show that compared with phenol-dicyclopentadiene epoxy resin, the o-allylphenol-dicyclopentadiene epoxy resin has higher heat resistance (glass transition temperature Tg and 5% thermogravimetric temperature Td5% are higher), bending strength, impact strength, high temperature bending strength retention, and better dielectric properties, lower water absorption.

  • Material Research
  • Li XIE , Shuang QIU , Fu LI
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.013

    To address the issues of inadequate high-temperature insulation performance and thermal stability of wires, a high-temperature resistant ceramic coating was prepared using the nano alumina and a small quantity of nano silica as the primary raw materials by nanoparticle surface modification technology, then the ceramic coating was coated on quartz fiber braided layer to prepare a high-temperature composite insulating material. The structure, composition, and thermal stability of the coating were analyzed by X-ray diffraction (XRD), fourier-transform infrared spectroscopy (FTIR), and thermogravimetric-differential scanning calorimetry (TG-DSC). The morphology, volume resistivity, and electric strength of the high-temperature resistant ceramic coating-quartz fiber composite insulation layer before and after calcination were analyzed by scanning electron microscopy (SEM), high insulation resistance tester, and automatic voltage tester. The results show that the ceramic coating forms a ceramic protective layer on the quartz fiber braided layer after high temperature calcination, which can enhance the temperature resistance rating of the quartz fiber and improve its insulation performance. When the temperature exceeds 800℃, the insulation resistivity of the high-temperature resistant composite insulation layer still exceeds 2×106 Ω·m, and the average electric strength at room temperature is as high as 400 kV/m, which has certain application prospects in the wires on specialized equipments such as aerospace engines, excitation coils, transformers.

  • Material Research
  • Yanbo LI , Sicheng YAN , Yinping HU
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.014

    To improve the insulating properties of machinable ceramic brush holders in high humidity environment, different types of organosilane film layers were formed on the surface of machinable ceramic, and their microstructure, contact angle, surface bonding strength, and moisture absorption rate were tested. The effects of the film layers containing KH-560, KH-570, and fluorosilane on the adhesion strength and moisture absorption of epoxy adhesive were studied. The mechanism of the films enhance the moisture resistance of machinable ceramic brush holder was concluded. The results show that the film layer thickness of KH-560 organosiliane on the surface of the machinable ceramic brush holder is about 40 μm. At the same time, the water contact angle of the brush holder product treated by KH-560 coupling agent increases from 9.2° to 42.8°, the moisture absorption rate reduces by more than 58.3%, and the hydrophobicity increases significantly. Even in the environment with relative humidity of 90%, the insulation resistance can still reach more than 220 MΩ, showing excellent insulation performance, which makes its insulation reliability improve significantly in high humidity environment.

  • Test and Analysis
  • Ruiyu WANG , Pengyu ZHANG , Wei WANG , Yiling ZHANG , Ailiang KANG
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.015

    The main insulation of large motor will produce many kinds of insulation defects during its operation process, and only used the phase resolved partial discharge (PRPD) pattern cannot reflect the characteristics of the defects fully. In this paper, four typical insulation defects such as internal air gap, coil wear in slot, overlapping part fault of end semiconductor coating and anti corona layer, and surface contamination were simulated in laboratory, their partial discharge (PD) information were collected in the electromagnetic shielding chamber, and the PRPD patterns and PSA patterns were drawn respectively. Combined with the characteristics of PRPD and PSA patterns under different voltage levels, the discharge characteristics of the typical insulation defects were analyzed. The results show that considering the symmetry, discharge amplitude, spectrum envelope shape of PRPD pattern and the discharge cluster number, discharge cluster distribution position, discharge cluster shape of PSA pattern, the four typical insulation defects can be identified accurately.

  • Test and Analysis
  • Wei LI , Zhichao LIU , Leying LI , Minting DAI , Weiwei YAO , Shusheng ZHENG , Yong SUN , Zhiguo TANG , Bo QI , Depeng HU
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.016

    In the partial discharge test and detection of power transformers, multi-source pulse overlap seriously affects the identification of partial discharge signals. In this paper, a clustering separation method of partial discharge signals based on multi-terminal pulse amplitude ratio was proposed. Firstly, the partial discharge test of 220 kV transformer was carried out, and the pulse overlapping phenomena in PRPD and T-F spectra under different test voltages were analyzed. Then, based on the propagation attenuation law of different types of pulses in transformer, a three-dimensional amplitude ratio pulse clustering separation method based on multi-terminal detection of transformer was proposed, and the method was realized by DBSCAN algorithm. Finaly, multi-terminal detection was carried out during the partial discharge test of 220 kV transformer, and the clustering separation and pulse source analysis of the pulse were carried out. The results show that utilizing the multi-terminal amplitude ratio clustering separation method can accurately divide the multi-source overlap pulses during partial discharge process in to interference pulse and two kinds of discharge pulse, and the initial location of the pulse source can be realized according to the amplitude ratio . The multi-terminal pulse amplitude ratio clustering separation method realizes the extraction of transformer partial discharge pulse, and its development and application will be conductive to improve the anti-interference capability and detection accuracy in transformer partial discharge testing.

  • Test and Analysis
  • Shifang YANG , Xinyi ZANG , Mingxi ZHU , Yunpeng LIU , Chaojun SHI , Zhidong JIA
    doi: 10.16790/j.cnki.1009-9239.im.2024.11.017

    Algae is a special kind of biofouling, its attachment on the insulator surface of electrical equipment will significantly reduce the fouling flash resistance of insulator , which poses a threat to the safe and stable operation of power grids. In this paper, a semantic segmentation algorithm of insulating algae integrated multi-scale convolution attention mechanism was proposed. Firstly, a model for insulating algae class semantic segmentation was constructed on the basic U-Net network model, and VGG16 was used as the backbone feature extraction network. The model adopts a U-shaped structure, and the left side is the feature extraction part of the VGG16 backbone, which can effectively extract the informations of five feature layers. The right side was the enhanced feature extraction part. CBAM module was selected for attention module, and the multi-scale convolution was introduced based on CBAM module. Then the CABM convolutional attention module was added to the encoder and the decoder of U-Net network before up-sampling and down-sampling. Finally, the model was compared with Deeplabv3+ and Transfuse network on the self-constructed algae-covered insulator image dataset. The results show that compared with the basic U-Net model, the mIoU value of this model improves by 0.28, mPA value improves by 0.27, Dice coefficient improves by 0.06, Hausdorff distance reduces by 11.77, and the RVE value reduces by 0.06. The visualization results of the segmentation process demonstrates that the model in this paper can pay more attention to the algal coverage region, and locate the boundary of the algal coverage region more accurately, which reduces the segmentation error effectively.