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  • Haoou RUAN, Fangcheng LÜ, Kaixuan SUN, Jingxuan SONG, Xiaobin CHANG, Sidi FAN
    Insulating Materials. 2024, 57(2): 19-28.

    In this paper, the effects of properties of chopped fiber on the breakdown strength, conductivity, trap characteristics, and mechanical properties of meta-aramid paper were studied. The results show that based on the reference sample of which the fiber diameter is 25 μm, fiber length is 6 mm, crystallization temperature is 300℃, and the ratio of precipitated fibrids and chopped fibers is 7:3, when the fiber diameter increases to 45 μm, the embedding degree of chopped fibers decreases, interface pores appear, and the breakdown and tensile strength of aramid paper can decrease by 16% and 24%, respectively. When the length of fiber increases to 18 mm, chopped fiber morphology shows coiling-type thus forming the "hard-form" interface, the breakdown strength of aramid paper decreases by 63%, while the tensile strength shows little change. When the crystallization temperature decreases to 230℃, the structural stability of chopped fibers reduces, which causes their melting under hot-pressing process, and the breakdown strength and tensile strength decreases by 36% and 50%, respectively. With the increase of proportion of chopped fiber, the breakdown strength of aramid paper increases at first and then decreases, which is along with the change of paper compactness, while the tensile strength of aramid paper increases monotonically with the increase of chopped fiber content, which reflects the necessity of chopped fibers for the stable molding of aramid paper and the weakening effect of excessive chopped fibers on electrical insulation. In addition, the aramid papers with low breakdown strength show a higher conductivity and a shallower trap depth, which can be regarded as reference indexes for the insulation performance of meta-aramid papers.

  • Xiao WU, Ping YAO, Wenbin ZHAO
    Insulating Materials. 2024, 57(2): 112-120.

    In order to quickly detect the overheating defects of wire insulation materials by using the key parameters of gas derivatives, the relationship curves between the concentration of gas derivatives and the temperature wire insulation materials were obtained through experiments. A thermoelectric coupling simulation model was established to simulate the effects of wire parameters, wire laying mode and ambient temperature on wire insulation temperature. A heat-flow coupling simulation model was established to simulate the effects of overheating defect location, threading tube horizontal length, and gas class on the sensor response time of escaped gas derivatives in the fluid field. The weight of influence degree was determined by orthogonal test. The results show that CH4, C2H2, and CO are the main gases escaping from overheating defects of PVC insulation material. The selection of wire parameters has the greatest influence on insulation material temperature. The type of detected gas has the greatest influence on the response time of sensors.

  • Xinxin WANG, Cheng HE, Jun CHEN, Puzhi ZHAO, Shang WEI, Xinxing FENG
    Insulating Materials. 2024, 57(2): 86-91.

    In this study, EPDM seal ring commonly used in gas insulated switchgear (GIS) equipment was treated at -55℃, and the effects of low temperature on its surface morphology, structure, glass transition temperature, and mechanical properties (tensile and compression permanent deformation) were investigated. The results show that the low temperature treatment cannot damage the macromolecular chain structure in the seal ring, but it is easy to cause frosting, and the glass transition temperature shows an increasing trend. The mechanical properties of the seal ring change greatly after low temperature treatment, the hardness and breaking strength decrease, while the elongation at break and compression permanent deformation increase. The degree of change in tensile property is related to the amplitude of alternating temperature difference in alpine environment, the greater the amplitude, the greater the breaking strength loss of the seal ring.

  • Mingnan SHANGGUAN, Chaoying WANG, Yunyun ZHAO, Xiuyun ZHANG, Guisheng ZHU, Huarui XU
    Insulating Materials. 2024, 57(2): 53-59.

    In the preparation of tetragonal nano-barium titanate powder by traditional solid-phase method, the dispersion and particle size of the BaCO3 precursors play a crucial role in the morphology, particle size, and dielectric properties of the obtained tetragonal BaTiO3 nanoparticles. In this paper, nano BaCO3 powders were prepared by controlling the concentration of the Ba(OH)2 using Ba(OH)2 and drikold as raw materials. Then, BaTiO3 powders and ceramic were prepared using the BaCO3 powders, and the dielectric properties of BaTiO3 ceramic was studied. The results show that the short rod-shaped nano BaCO3 powders with a particle size of 180 nm and the highly dispersed, highly uniform and pure tetragonal BaTiO3 powders with a particle size of 400 nm were prepared. The dielectric constant and dielectric loss factor of the BaTiO3 ceramic obtained by calcination at 1 250℃ is 4 885 and 0.018 9, respectively.

  • Weijun WANG, Min CHEN, Hui YIN, Yuan LI
    Insulating Materials. 2024, 57(2): 72-79.

    Polarization-depolarization current (PDC) method is widely used to evaluate the insulation status of cross-linked polyethylene (XLPE) cables. However, the existing studies tend to use a single dielectric characteristic parameter to reflect the ageing condition of insulation, which does not make full use of the rich dielectric response information in PDC results, and a single dielectric parameter is difficult to apply to different ageing types. To solve the above problems, an improved radar spectroscopy evaluation method was proposed to evaluate the insulation condition of XLPE cable by comprehensively utilizing multidimensional dielectric parameters. To verify the effectiveness of the proposed method, PDC test was conducted on short XLPE cable specimens after being artificially accelerated thermal and water tree ageing. Then the PDC results were analyzed by the proposed multidimensional dielectric parameter radar spectroscopy method. The results show that the area parameter of polygon in radar chart can effectively reflect the degree of ageing in both types of aged XLPE cables.

  • Li XIE, Xiaofen QU, Bo PENG
    Insulating Materials. 2024, 57(2): 47-52.

    By using organic-inorganic composite technology, the high temperature resistant insulation layer was prepared by coating quartz fiber wrap cladding with silicone nano alumina sol. The micro morphology and structure of the organic silicon-nano alumina sol coating were analyzed by SEM, FTIR, XRD and other characterization techniques. The thermal stability of the organic silicon-nano alumina sol composite insulating paint was analyzed by TG-DSC. The insulation performance and breakdown voltage performance of high-temperature wire were tested at room temperature and high temperature. The results show that the organic silicon-nano alumina sol composite insulating paint has good thermal stability, and it can significantly improve the temperature resistance level of the glass fiber wrap cladding. The high-temperature wire shows good high temperature insulation and high voltage resistance. At 800℃, the electrical resistance is greater than 1 MΩ·m, and the normal temperature breakdown voltage is greater than 2 000 V. It is suitable for special environments such as high temperature and high voltage in the aviation and aerospace fields.

  • Xinwei ZHANG, Liying ZHOU, Bo WANG, Yuwei DAI, Tianxiang DUANMU, Xinzhe GUO, Jiahao LIU, Yunqi XING
    Insulating Materials. 2024, 57(2): 100-105.

    In order to investigate the ageing mechanism of composite insulators in extreme cold regions, the influence of ageing time on the physicochemical, mechanical, and electrical properties of composite insulator skirts were studied by an improved multi-factor ageing method. The results show that with the increase of the ageing time, cracks, holes and particle accumulation appear on the surface of the silicone rubber material, that leads to the significant decrease of its hydrophobicity. At the same time, the overall hardness of the silicone rubber material increases, the elongation at break decreases rapidly, and the mechanical properties decrease significantly. In addition, with the increase of ageing time, the dielectric constant increases significantly, the dielectric loss keeps increasing, the density of deep trap energy level gets lower, the density of shallow trap energy level increases, the surface conductivity increases significantly, and the flashover voltage decreases sharply.

  • Zhibin HE, Xi REN, Xinxin ZHI, Yan ZHANG, Haifeng YU, Jingang LIU
    Insulating Materials. 2024, 57(2): 10-18.

    In this paper, the research status and future developing trends of polyimide (PI) film carrier materials for flexible solar cells was reviewed. The basic structure of flexible solar cells, the property requirements of substrate materials and the research and application status of PI flexible substrate were introduced. Emphatically, the research and application progress of high temperature resistant PI films for the substrate-types flexible solar cells and the colorless and transparent PI films for the superstrate-types flexible solar cells were reviewed. At last, the future developing trends of PI film substrate materials for advanced flexible solar cells were prospected.

  • Xiaolei WANG, Yousheng ZHANG, Shengwei DAI, Shujun HAN, Yuexin QI, Xi REN, Jingang LIU
    Insulating Materials. 2024, 57(2): 1-9.

    Epoxy molding compounds (EMC) play important roles in packaging of chips for electrically controlling systems of electric vehicles (EV). The increasing working temperature of EV controlling system puts forward higher and higher requirements for the thermal stability of traditional EMC materials. In this paper, the progress on the high temperature resistant molding compounds at home and abroad in recent years was reviewed, and the development status of high temperature resistant resins and the progress of high temperature resistant resins modified traditional epoxy resin based EMC materials were described. Especially, the development status of high temperature resistant EMC materials modified by bismaleimide (BMI), cyanate ester (CE), and polybenzoxazine (PBZ) and phthalonitrile (PN) based molding compounds were reviewed. Finally, the future development trend of high temperature resistant molding compounds for packaging of electronic control chip in EV was prospected.

  • Ran XU, Qingdong ZHU, Jianfei LI, Huaqiang LI, Yang WANG
    Insulating Materials. 2024, 57(2): 121-128.

    Furan molecule is one of the important characteristic products of insulating paper pyrolysis during local thermal failure of oil-immersed transformer, and the detection of furan molecules content in transformer oil is an important off-line testing method to assess the operating condition of transformer. In order to clarify the diffusion process of furan molecules from insulating paper to insulating oil and its correlation with temperature labels of local overheating fault, molecular dynamics methods were used to study the diffusion process of furan molecules from insulating paper to vegetable oil based on nanoscale oil-paper interface models under room temperature (300 K), low temperature overheating (500 K), medium temperature overheating (750 K), and high temperature overheating (1 000 K). The results show that with the increase of temperature, the diffusion coefficient of furan molecules in oil-paper insulation increases gradually, and the number of furan molecules diffusing from insulation paper to vegetable oil changes closely with temperature. There are few furan molecules diffuse into vegetable oil under 300 K and 500 K. Under the temperature of 750 K and 1 000 K, some of furan molecules diffuse into vegetable oil, and the molecule number increases with temperature. The above simulation results are consistent with the empirical basis that furan compounds can be detected in local overheating fault of medium and high temperature in oil-immersed transformers.