To determine the concentrations of 24 per- and polyfluoroalkyl substances (PAFs) in marine and freshwater shrimp sold in Tianjin and to characterize their pollution profiles.
The concentrations of PFASs in the samples was determined by UPLC-MS/MS. Descriptive statistics were applied, and non-parametric tests were used to compare concentrations.
A total of 67 samples of marine shrimp and 105 samples of freshwater shrimp were tested. A total of 14 kinds of PFASs were detected in marine shrimp, and the ∑PFASs concentration ranged from 0.160 to 43.4 μg/kg. The overall detection rate of PFASs pollutants was 100%. 17 kinds of PFASs were detected in freshwater shrimp, and the ∑PFASs concentration ranged from 0.135 to 27.9 μg/kg. The overall detection rate of PFASs pollutants was 99%. The main detected components in the two types of shrimp aquatic products were all long-chain PFASs. The number of PFASs detected in a single sample of marine shrimp ranged from 1 to 11, while that in a single sample of freshwater shrimp ranged from 0 to 13. Among them, PFOS, PFOA and PFNA were the main pollutant components, while 6:2Cl-PFESA and 8:2Cl-PFESA were both detected to a certain extent. Through comparison, it was found that the pollution of river shrimp among freshwater shrimp was relatively serious.
There is a certain degree of PFASs pollution in the shrimp aquatic products sold in Tianjin. In-depth research, attention and strengthened management should be carried out.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |