Lithium-sulfur (Li-S) batteries as power supply systems possessing a theoretical energy density of as high as 2600 Wh kg⁻¹ are considered promising alternatives toward the currently used lithium-ion batteries (LIBs). However, the insulation characteristic and huge volume change of sulfur, the generation of dissolvable lithium polysulfides (LiPSs) during charge/discharge, and the uncontrollable dendrite formation of Li metal anodes render Li-S batteries serious cycling issues with rapid capacity decay. To address these challenges, extensive efforts are devoted to designing cathode/anode hosts and/or modifying separators by incorporating functional materials with the features of improved conductivity, lithiophilic, physical/chemical capture ability toward LiPSs, and/or efficient catalytic conversion of LiPSs. Among all candidates, molybdenum-based (Mo-based) materials are highly preferred for their tunable crystal structure, adjustable composition, variable valence of Mo centers, and strong interactions with soluble LiPSs. Herein, the latest advances in design and application of Mo-based materials for Li-S batteries are comprehensively reviewed, covering molybdenum oxides, molybdenum dichalcogenides, molybdenum nitrides, molybdenum carbides, molybdenum phosphides, and molybdenum metal. In the end, the existing challenges in this research field are elaborately discussed.

Stimulus-responsive metal-organic frameworks (MOFs) can be used for designing smart materials. Herein, we report a family of rationally designed MOFs which exhibit photoresponsive chiroptical and magnetic properties at room temperature. In this design, two specific nonphotochromic ligands are selected to construct enantiomeric MOFs, {Cu₂(L-mal)₂(bpy)₂(H₂O)·3H₂O}_n (1) and {Cu₂(D-mal)₂(bpy)₂(H₂O)·3H₂O}_n (2) (\text{mal}=\text{malate}, \text{bpy}=4,4^{\text{’}}-\text{bipyridine}), which can alter their color, magnetism, and chiroptics concurrently in response to light. Upon UV or visible light irradiation, long-lived bpy⁻ radicals are generated via photoinduced electron transfer (PET) from oxygen atoms of carboxylates and hydroxyl of malates to bpy ligands, giving rise to a 23.7% increase of magnetic susceptibility at room temperature. The participation of the chromophores (-OH and -COO⁻) bound with the chiral carbon during the electron transfer process results in a small dipolar transition; thus, the Cotton effects of the enantiomers are weakened along with a photoinduced color change. This work demonstrates that the simultaneous responses of chirality, optics, and magnetism can be achieved in a single compound at room temperature and may open up a new pathway for designing chiral stimuli-responsive materials.

As a promising renewable energy source, it is a challenging task to obtain blue energy, which is irregular and has an ultralow frequency, due to the limitation of technology. Herein, a nonresonant hybridized electromagnetic-triboelectric nanogenerator was presented to efficiently obtain the ultralow frequency energy. The instrument adopted the flexible pendulum structure with a precise design and combined the working principle of electromagnetism and triboelectricity to realize the all-directional vibration energy acquisition successfully. The results confirmed that the triboelectric nanogenerator (TENG) had the potential to deliver the maximum power point of about 470  μW while the electromagnetic nanogenerator (EMG) can provide 523 mW at most. The conversion efficiency of energy of the system reached 48.48%, which exhibited a remarkable improvement by about 2.96 times, due to the elastic buffering effect of the TENG with the double helix structure. Furthermore, its ability to collect low frequency wave energy was successfully proven by a buoy in Jialing River. This woke provides an effective candidate to harvest irregular and ultralow frequency blue energy on a large scale.

The ability of carbon dots (CDs) to emit afterglow emission in addition to fluorescence in response to UV-to-visible excitation allows them to be a new class of luminescent materials. When compared with traditional organic or inorganic afterglow materials, CDs have a set of advantages, including small size, ease of synthesis, and absence of highly toxic metal ions. In addition, high dependence of their afterglow color output on temperature, excitation wavelength, and aggregation degrees adds remarkable flexibility in the creation of multimode luminescence of CDs without the need for changing their intrinsic attributes. These characteristics make CDs particularly attractive in the fields of sensing, anticounterfeiting, and data encryption. In this review, we first describe the general attributes of afterglow CDs and their fundamental afterglow mechanism. We then highlight recent strategic advances in the generation or activation of the afterglow luminescence of CDs. Considerable emphasis is placed on the summarization of their emergent afterglow properties in response to external stimulation. We further highlight the emerging applications of afterglow CDs on the basis of their unique optical features and present the key challenges needed to be addressed before the realization of their full practical utility.

Achieving full-polarization (\sigma) invisibility on an arbitrary three-dimensional (3D) platform is a long-held knotty issue yet extremely promising in real-world stealth applications. However, state-of-the-art invisibility cloaks typically work under a specific polarization because the anisotropy and orientation-selective resonant nature of artificial materials made the \sigma-immune operation elusive and terribly challenging. Here, we report a deterministic approach to engineer a metasurface skin cloak working under an arbitrary polarization state by theoretically synergizing two cloaking phase patterns required, respectively, at spin-up (\sigma +) and spin-down (\sigma -) states. Therein, the wavefront of any light impinging on the cloak can be well preserved since it is a superposition of \sigma + and \sigma - wave. To demonstrate the effectiveness and applicability, several proof-of-concept metasurface cloaks are designed to wrap over a 3D triangle platform at microwave frequency. Results show that our cloaks are essentially capable of restoring the amplitude and phase of reflected beams as if light was incident on a flat mirror or an arbitrarily predesigned shape under full polarization states with a desirable bandwidth of ~17.9%, conceiving or deceiving an arbitrary object placed inside. Our approach, deterministic and robust in terms of accurate theoretical design, reconciles the milestone dilemma in stealth discipline and opens up an avenue for the extreme capability of ultrathin 3D cloaking of an arbitrary shape, paving up the road for real-world applications.

In the past few years, triboelectric nanogenerator-based (TENG-based) hybrid generators and systems have experienced a widespread and flourishing development, ranging among almost every aspect of our lives, e.g., from industry to consumer, outdoor to indoor, and wearable to implantable applications. Although TENG technology has been extensively investigated for mechanical energy harvesting, most developed TENGs still have limitations of small output current, unstable power generation, and low energy utilization rate of multisource energies. To harvest the ubiquitous/coexisted energy forms including mechanical, thermal, and solar energy simultaneously, a promising direction is to integrate TENG with other transducing mechanisms, e.g., electromagnetic generator, piezoelectric nanogenerator, pyroelectric nanogenerator, thermoelectric generator, and solar cell, forming the hybrid generator for synergetic single-source and multisource energy harvesting. The resultant TENG-based hybrid generators utilizing integrated transducing mechanisms are able to compensate for the shortcomings of each mechanism and overcome the above limitations, toward achieving a maximum, reliable, and stable output generation. Hence, in this review, we systematically introduce the key technologies of the TENG-based hybrid generators and hybridized systems, in the aspects of operation principles, structure designs, optimization strategies, power management, and system integration. The recent progress of TENG-based hybrid generators and hybridized systems for the outdoor, indoor, wearable, and implantable applications is also provided. Lastly, we discuss our perspectives on the future development trend of hybrid generators and hybridized systems in environmental monitoring, human activity sensation, human-machine interaction, smart home, healthcare, wearables, implants, robotics, Internet of things (IoT), and many other fields.

Electronic skins with distinctive features have attracted remarkable attention from researchers because of their promising applications in flexible electronics. Here, we present novel morphologically conductive hydrogel microfibers with MXene encapsulation by using a multi-injection coflow glass capillary microfluidic chip. The coaxial flows in microchannels together with fast gelation between alginate and calcium ions ensure the formation of hollow straight as well as helical microfibers and guarantee the in situ encapsulation of MXene. The resultant hollow straight and helical MXene hydrogel microfibers were with highly controllable morphologies and package features. Benefiting from the easy manipulation of the microfluidics, the structure compositions and the sizes of MXene hydrogel microfibers could be easily tailored by varying different flow rates. It was demonstrated that these morphologically conductive MXene hydrogel microfibers were with outstanding capabilities of sensitive responses to motion and photothermal stimulations, according to their corresponding resistance changes. Thus, we believe that our morphologically conductive MXene hydrogel microfibers with these excellent features will find important applications in smart flexible electronics especially electronic skins.

For the realization of retina-inspired neuromorphic visual systems which simulate basic functions of human visual systems, optoelectronic synapses capable of combining perceiving, processing, and memorizing in a single device have attracted immense interests. Here, optoelectronic synaptic transistors based on tris(2-phenylpyridine) iridium (Ir(ppy)₃) and poly(3,3-didodecylquarterthiophene) (PQT-12) heterojunction structure are presented. The organic heterojunction serves as a basis for distinctive synaptic characteristics under different wavelengths of light. Furthermore, synaptic transistor arrays are fabricated to demonstrate their optical perception efficiency and color recognition capability under multiple illuminating conditions. The wavelength-tunability of synaptic behaviors further enables the mimicry of mood-modulated visual learning and memorizing processes of humans. More significantly, the computational dynamics of neurons of synaptic outputs including associated learning and optical logic functions can be successfully demonstrated on the presented devices. This work may locate the stage for future studies on optoelectronic synaptic devices toward the implementation of artificial visual systems.

Introducing the conductive intermediate layer into a triboelectric nanogenerator (TENG) has been proved as an efficient way to enhance the surface charge density that is attributed to the enhancement of the dielectric permittivity. However, far too little attention has been paid to the companion percolation, another key element to affect the output. Here, the TENG with MXene-embedded polyvinylidene fluoride (PVDF) composite film is fabricated, and the dependence of the output capability on the MXene loading is investigated experimentally and theoretically. Specifically, the surface charge density mainly depends on the dielectric permittivity at lower MXene loadings, and in contrast, the percolation becomes the degrading factor with the further increase of the conductive loadings. At the balance between the dielectric and percolation properties, the surface charge density of the MXene-modified TENG obtained 350% enhancement compared to that with the pure PVDF. This work shed new light on understanding the dielectric and percolation effect in TENG, which renders a universal strategy for the high-performance triboelectronics.

Piezoelectric nanogenerators (PENGs) and triboelectric nanogenerators (TENGs) are representative technologies that can harvest mechanical energy. In general, piezoelectric/triboelectric hybrid generators can harvest considerable energy with a limited input; however, PENGs and TENGs entail different requirements for harvesting energy. Specifically, PENGs produce a large output when a large mechanical strain is applied, and TENGs require a large surface area to produce a high power. Therefore, it is necessary to develop an innovative strategy in terms of the structural design to satisfy the requirements of both PENGs and TENGs. In this study, we developed a triangulated cylinder origami-based piezoelectric/triboelectric hybrid generator (TCO-HG) with an origami structure to enable effective energy harvesting. The proposed structure consists of a vertical contact-separation TENG on the surface of the triangulated cylinder, PENG on the inner hinge, and rotational TENG on the top substrate to harvest mechanical energy from each motion. Each generator could produce a separate electrical output with a single input. The TCO-HG could charge a 22  μF commercial capacitor and power 60 LEDs when operated.