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Research progress of the synthesis of green plasticizer tributyl citrate catalyzed by solid acid
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Science & Technology Review | 2019, 37(12) : 79 - 85
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Science & Technology Review | 2019, 37(12): 79-85
• Leading Science and Technology •
Research progress of the synthesis of green plasticizer tributyl citrate catalyzed by solid acid
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XU Yongqiang1, GAO Qiang1,2, WANG Haiyan3, SHANG Hongyan1, LIU Chenguang1
Affiliations
    1. State Key Laboratory of Heavy Oil Processing, CNPC Key Laboratory of Catalysis, China University of Petroleum(East China), Qingdao 266555, China;
    2. School of Chemical Engineering, Qinghai Normal University, Xining 810008, China;
    3. College of Computer & Communication Engineering, China University of Petroleum(East China), Qingdao 266555, China
Published: 2019-06-28 doi: 10.3981/j.issn.1000-7857.2019.12.014
Outline
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The tributyl citrate is a non-toxic, green and environmentally friendly plasticizer, one of the new generation plasticizers to replace the widely used toxic plasticizers, and has become a research hotspot. The main properties of the tributyl citrate are listed in detail, and the main synthesis methods of the tributyl citrate are reviewed. The solid acid catalysts for the synthesis of the tributyl citrate are classified and their applications in the esterification are summarized. It is concluded that the organic solid acid catalyst is a suitable catalyst for the preparation of the tributyl citrate.
tributyl citrate  /  plasticizer  /  catalyst
徐永强, 高强, 王海燕, 商红岩, 刘晨光. 新一代环保型增塑剂柠檬酸三丁酯绿色合成进展. 科技导报, 2019 , 37 (12) : 79 -85 . DOI: 10.3981/j.issn.1000-7857.2019.12.014
XU Yongqiang, GAO Qiang, WANG Haiyan, SHANG Hongyan, LIU Chenguang. Research progress of the synthesis of green plasticizer tributyl citrate catalyzed by solid acid[J]. Science & Technology Review, 2019 , 37 (12) : 79 -85 . DOI: 10.3981/j.issn.1000-7857.2019.12.014
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Year 2019 volume 37 Issue 12
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doi: 10.3981/j.issn.1000-7857.2019.12.014
  • Receive Date：2019-05-20
  • Online Date：2019-06-24
  • Published：2019-06-28
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  • Received：2019-05-20
  • Revised：2019-06-10
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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