The graphene is a single layer of carbon arranged in a honeycomb (hexagonal) lattice. The unique single layer structure endows this material with a series of extraordinary physicochemical properties, with promising applications in energy, environmental and biomedical sciences. The controllable production and assembly of the graphene is critical for practical applications. This review focuses on the assembly behavior of the graphene based on the colloid chemistry and the interface engineering. The graphene based multi-dimensional assemblies, from the 0D graphene based nanoparticles and the 1D fibers to the macro flexible 2D films and the 3D monoliths, are discussed in this review. The possibility of creating novel graphene assemblies is explored.

graphene  /  self-assembly  /  multi-dimensional  /  functionalization