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Research progress on the corrosion behavior and mechanisms of high−entropy alloys
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Shujun DONG, Qiancheng ZHAO, Hongxu CHENG, Minglei SUN, Xiaochen LIU, Xuefei WANG, Hong LUO*
Science & Technology Review | 2025, 43(17) : 62 - 76
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Science & Technology Review | 2025, 43(17): 62-76
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Research progress on the corrosion behavior and mechanisms of high−entropy alloys
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Shujun DONG, Qiancheng ZHAO, Hongxu CHENG, Minglei SUN, Xiaochen LIU, Xuefei WANG, Hong LUO*
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  • Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
Published: 2025-09-13 doi: 10.3981/j.issn.1000-7857.2024.12.01749
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High−entropy alloys (HEAs) exhibit significant application potential in extreme service environments due to their outstanding overall properties, with corrosion resistance being a critical factor determining their service life and reliability. This review systematically summarizes recent advances in the corrosion behavior and mechanisms of HEAs, highlighting the influence of alloy composition and atomic ratio adjustments on corrosion performance, as well as the effects of thermomechanical processing, such as heat treatment and rolling, on microstructure and passive film characteristics. Studies indicate that compositional design and process optimization can substantially alter the corrosion response and passivation behavior of HEAs, thereby affecting their overall corrosion resistance. Future research should focus on further elucidating localized corrosion mechanisms and the evolution of passivation films, integrating machine learning and multiscale simulations for intelligent alloy design, and establishing comprehensive evaluation frameworks that balance mechanical properties, corrosion resistance, and cost−effectiveness. Collectively, this review provides a systematic overview and reference for the design and application of corrosion−resistant HEAs.

high−entropy alloys  /  corrosion resistance  /  alloying elements  /  microstructure
Shujun DONG, Qiancheng ZHAO, Hongxu CHENG, Minglei SUN, Xiaochen LIU, Xuefei WANG, Hong LUO. Research progress on the corrosion behavior and mechanisms of high−entropy alloys[J]. Science & Technology Review, 2025 , 43 (17) : 62 -76 . DOI: 10.3981/j.issn.1000-7857.2024.12.01749
Year 2025 volume 43 Issue 17
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doi: 10.3981/j.issn.1000-7857.2024.12.01749
  • Receive Date:2024-12-16
  • Online Date:2025-12-18
  • Published:2025-09-13
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  • Received:2024-12-16
  • Revised:2025-08-01
  • Accepted:2025-09-01
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    Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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