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Revolutionizing energy storage: Calcium-based batteries for high energy density and low cost
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Lei YE, Meng LIAO, Bingjie WANG*, Huisheng PENG*
Science & Technology Review | 2025, 43(12) : 110 - 120
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Science & Technology Review | 2025, 43(12): 110-120
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Revolutionizing energy storage: Calcium-based batteries for high energy density and low cost
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Lei YE, Meng LIAO, Bingjie WANG*, Huisheng PENG*
Affiliations
  • State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Institute of Fiber Materials and Devices, and Laboratory of Advanced Materials, Fudan University, Shanghai 200438, China
Published: 2025-06-28 doi: 10.3981/j.issn.1000-7857.2025.03.00130
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Calcium-based batteries have attracted increasing attention as promising candidates for next-generation energy storage, owing to the natural abundance of calcium (approximately 2500 times more abundant than lithium in the Earth's crust), its high volumetric capacity (2073 mA·h·cm-3), and favourable environmental profile. Despite these advantages, their development remains hindered by several fundamental challenges, including inefficient and irreversible calcium metal plating/stripping, narrow electrochemical stability windows of electrolytes, and the scarcity of high-performance cathode materials. Here we provide a comprehensive overview of recent progress in calcium-based battery research, with a focus on calcium metal anode design, rational electrolyte design, development of cathode chemistries, and advances in cell configurations. We critically examine the underlying mechanisms and representative strategies proposed to address current bottlenecks, and discuss emerging opportunities for calcium-based systems in grid-scale and extreme-environment applications. This Review aims to offer a clear perspective on the path toward practical calcium-based batteries and to inspire future research directions for unlocking their full potential.

calcium-based battery  /  cathode materials  /  electrolyte  /  anode materials  /  sustainability
Lei YE, Meng LIAO, Bingjie WANG, Huisheng PENG. Revolutionizing energy storage: Calcium-based batteries for high energy density and low cost[J]. Science & Technology Review, 2025 , 43 (12) : 110 -120 . DOI: 10.3981/j.issn.1000-7857.2025.03.00130
Year 2025 volume 43 Issue 12
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doi: 10.3981/j.issn.1000-7857.2025.03.00130
  • Receive Date:2025-03-26
  • Online Date:2025-12-16
  • Published:2025-06-28
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  • Received:2025-03-26
  • Revised:2025-06-07
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    State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Institute of Fiber Materials and Devices, and Laboratory of Advanced Materials, Fudan University, Shanghai 200438, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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