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Effect of bypass current on coulombic efficiency of vanadium redox flow battery
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Mou HOU, Tao ZHENG, Zefeng JIA, Junwei LI, Kun QIU
Thermal Power Generation | 2024, 53(12) : 57 - 67
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Thermal Power Generation | 2024, 53(12): 57-67
Special topic of low-carbon power technology
Effect of bypass current on coulombic efficiency of vanadium redox flow battery
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Mou HOU, Tao ZHENG, Zefeng JIA, Junwei LI, Kun QIU
Affiliations
  • School of Electrical and Automation Engineering, Hefei University of Technology, Hefei 230009, China
Published: 2024-12-25 doi: 10.19666/j.rlfd.202405116
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In order to improve the performance and efficiency of the battery in vanadium redox battery (VRB) system, a multi-stack equivalent loss circuit model is developed based on the composition and principles of VRBs, which includes electrochemical, hydrodynamic, temperature, bypass current, and vanadium batteries. Moreover, the effects of pumping loss and bypass current on vanadium batteries in the pipeline system of all-vanadium flow batteries are investigated. The relationship between pumping loss and pumping current, the bypass current model, and the equivalent circuit model of vanadium battery with multiple stacks connected in series are established, and the core mechanism of the vanadium battery taking into account the dynamic response is elaborated by transforming each model into a whole. The key factors involved in modelling of the VRB, including the pumping loss and bypass current, are discussed in detail. The influencing factors of battery performance and efficiency are also analyzed. The results show that, parameters such as the length and cross-sectional area of the pipeline affect the pipeline resistance, and the resistance of longer main and branch pipes will reduce the bypass current but increase the pumping loss current. Longer and thicker pipelines are conducive to the simultaneous reduction of both the bypass current and the pumping loss, which improves the energy efficiency of the battery. The research provides an idea for design of the manufacturer’s pipeline.

vanadium redox battery  /  bypass current  /  pumping loss  /  multi-stack modeling  /  energy efficiency
Mou HOU, Tao ZHENG, Zefeng JIA, Junwei LI, Kun QIU. Effect of bypass current on coulombic efficiency of vanadium redox flow battery[J]. Thermal Power Generation, 2024 , 53 (12) : 57 -67 . DOI: 10.19666/j.rlfd.202405116
  • National Natural Science Foundation of China(62202138)
Year 2024 volume 53 Issue 12
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Article Info
doi: 10.19666/j.rlfd.202405116
  • Receive Date:2024-05-31
  • Online Date:2026-03-06
  • Published:2024-12-25
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  • Received:2024-05-31
Funding
National Natural Science Foundation of China(62202138)
Affiliations
    School of Electrical and Automation Engineering, Hefei University of Technology, Hefei 230009, China
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表12种不同金属材料的力学参数

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Number of
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Number of
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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