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Influence of simulated fireside corrosion on creep rupture properties and microstructure evolution of Super 304H steel
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Xiaofeng YANG1, Yaxin XU1, Jintao LU2, Jinyang HUANG2, Wenya LI1
Thermal Power Generation | 2023, 52(10) : 31 - 38
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Thermal Power Generation | 2023, 52(10): 31-38
Special topic on material properties of generator set
Influence of simulated fireside corrosion on creep rupture properties and microstructure evolution of Super 304H steel
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Xiaofeng YANG1, Yaxin XU1, Jintao LU2, Jinyang HUANG2, Wenya LI1
Affiliations
  • 1.School of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, China
  • 2.Xi’an Thermal Power Research Institute Co., Ltd., Xi’an 710054, China
Published: 2023-10-25 doi: 10.19666/j.rlfd.202306361
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The synergy of fireside corrosion and stress is one of the challenges for austenitic steels used in modern fossil-fuel power plants during their service process. The creep rupture tests of Super 304H steel are carried out under static air and fireside corrosion environment at 650 ℃. The stress range is set at 200 to 300 MPa. The creep rupture life and microstructure evolution of different samples were studied. The results show that creep rupture life of Super 304H steel in corrosion condition decreases significantly, compared with that in static air. The rupture life decreases more seriously as the stress decreases, up to 83% at 200 MPa. The complete and continuous corrosion products scale is damaged by fireside corrosion, including the occurrence of cracks and spallation of these surface products. The formation of internal sulfide in the matrix caused by fireside corrosion leads to the deterioration of grain boundaries. Then it tends to crack along grain boundaries during creep rupture tests to accelerate the accumulation of creep damage. The surface of matrix undergoes recrystallization upon to the combination of high temperature and stress due to the loss of alloy elements caused by corrosion/oxidation. The formation of these fine recrystallized grains is unfavorable to creep properties of metals. The ferrite transformation also occurs in the same area during the cooling process after creep tests. Fireside corrosion increases the width of recrystallized grains area, thus expands its influence on the creep rupture life of the alloy. The fireside corrosion accelerates the creep rupture of Super 304H steel by promoting its corrosion process and the microstructure evolution.

Super 304H steel  /  simulated fireside corrosion  /  creep rupture properties  /  microstructure evolution
Xiaofeng YANG, Yaxin XU, Jintao LU, Jinyang HUANG, Wenya LI. Influence of simulated fireside corrosion on creep rupture properties and microstructure evolution of Super 304H steel[J]. Thermal Power Generation, 2023 , 52 (10) : 31 -38 . DOI: 10.19666/j.rlfd.202306361
  • National Natural Science Foundation of China(52071265; 52271070)
  • Science and Technology Project of China Huaneng Group Co., Ltd.(HNKJ20-H41; TA-20-TYK03)
  • Opening Testing Foundation for Basic Research of Analytical and Testing Center of Northwestern Polytechnical University(2021T013)
Year 2023 volume 52 Issue 10
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Article Info
doi: 10.19666/j.rlfd.202306361
  • Online Date:2026-01-26
  • Published:2023-10-25
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History
  • Revised:2023-06-22
Funding
National Natural Science Foundation of China(52071265; 52271070)
Science and Technology Project of China Huaneng Group Co., Ltd.(HNKJ20-H41; TA-20-TYK03)
Opening Testing Foundation for Basic Research of Analytical and Testing Center of Northwestern Polytechnical University(2021T013)
Affiliations
    1.School of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, China
    2.Xi’an Thermal Power Research Institute Co., Ltd., Xi’an 710054, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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