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The pH values of boiler feed water, steam, boiler water and other measuring points in a chemical power plant were abnormally low, and the problem could not be effectively solved by adjusting the boiler water dosing process. In order to solve this problem and ensure the safe operation of the unit, this paper discusses and analyzes the influence of water sample temperature on pH electrode, Nernst temperature coefficient slope and solution temperature coefficient (ionic activity), and verifies through experiments that the abnormally low pH measurement value is caused by the large deviation of water sample temperature from 25 ℃, and the pH measurement method cannot provide correct temperature compensation. Strict control of water sample temperature, adoption of computational pH meter or selection of high-precision pH meter with precise non-linear temperature compensation function can effectively solve the problem of abnormally low pH measurement in the water and steam system.
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| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |
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