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The high-temperature and high-pressure (300 ℃/10 MPa) corrosion electrochemical behavior and oxide film microscopic features of Incoloy 800H alloy aged at 675 ℃ for 0~10 000 h in alkaline environament were investigated systematically. By means of electrochemical test, long-term immersion test, scanning electron microscope/transmission electron microscope observation, Raman spectroscopy/fast Fourier transform analysis and other methods, the electrochemical activity, evolution of oxide film morphology and composition characteristics of the 800H alloy with extension of aging time were systematically studied. The results show that, the value of open circuit potential and self-corrosion potential Ecorr of the 800H alloy in high-temperature and high-pressure water can be slightly increased by aging treatment, but the effect of aging time extension on the electrochemical behavior was not significant. A passive to trans-passive process was depicted. The oxide film of the 800H alloy formed in high-temperature and high-pressure water had a multilayer structure: the most outer layer was the dispersed large particle oxides composed of Fe2O3 or NiFe2O4; the middle layer was relatively compact small size oxides, mostly NiFe2O4 or FeCr2O4; while the inner layer was dense and continuous oxides, amorphous or nanocrystalline oxide containing Cr and a small amount of Fe. The 800H alloy has good corrosion resistance and surface stability in alkaline high temperature and high pressure water of 300 ℃/10 MPa.
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| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |
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