In order to study the corrosion behaviors of candidate materials for superheater of supercritical boilers in high-temperature flue gas environment, three austenitic heat-resistant steels including S31042, S31035 and C-HRA-5 were exposed to laboratorial simulated coal-fired flue gas for hot corrosion tests. The tests were carried out at 650, 675, 700 and 725 ℃. On the sample surface, there were three conditions including no coating, coating with real coal ash, and coating with corrosive simulated coal ash. The test duration was 500 h. The corrosion kinetic curves of the three materials were obtained through experimental research, and corrosion behaviors of the material were analyzed by XRD, SEM and EDS. Moreover, corrosion resistance of the three materials was compared. The results indicated that, the three materials had excellent resistance to oxidation and corrosion under the conditions of no coating and coating with real coal ash. Under the condition of coating with corrosive simulated coal ash, the material corrosion intensifies and the corrosion products are layered. The temperature effect was different under different coating conditions. S31042 had the best corrosion resistance, and the corrosion resistance of S31035 and C-HRA-5 materials was comparable.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |