The hydrophobic resin-based solid amine adsorbent was prepared by modifying porous materials with different-molecular-weight polyethyleneimine (PEI), by taking hydrophobic oily macroporous adsorbent resin as carrier. The specific surface area, pore structure, functional group structure and thermogravimetric properties of the resin-based solid amine adsorbent were characterized by N2 isothermal adsorption-desorption, infrared and thermal analysis. The effects of PEI loading, air humidity (30%~80%), adsorption time and multiple cycles on the adsorption performance of CO2 were investigated. The results show that, the hydrophobic resin-based solid amine adsorbent has good trapping performance for CO2 in dry air (air humidity is less than 50%). The SD300 resin-based solid amine adsorbent modified by 30%PEI can reach more than 90% of the total adsorption capacity after one hour adsorption in atmospheric environment. When the molecular weight of the PEI is 1 800, it shows high adsorption capacity and good cycle stability of adsorption and desorption, mainly due to the high pore size and its excellent high temperature resistance.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |