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Phosphate ester fire-resistant fluids, serving as hydraulic working medium for the speed regulation system of steam turbines, play a crucial role in the normal operation of steam turbines. Currently, imported products dominate the phosphate ester fire-resistant fluids market for the speed regulation system of steam turbines in domestic power generation units. To break the power industry’s high dependence on imported fire-resistant fluids, it is imperative to develop domestic phosphate ester fire-resistant fluids through independent research and application. Through performance evaluation of various domestic tri-aryl phosphate esters, tri-(dimethylphenyl) phosphate was identified as the optimal choice for domestic fire-resistant fluid development. Via oxidation and adsorption refining processes, the stability of the domestic tri-(dimethylphenyl) phosphate was significantly enhanced, resulting in the successful development of high-performance phosphate ester fire-resistant base oil. After the research on various additives, an optimized additive formulation was established, ultimately producing high-performance phosphate ester fire-resistant fluid that meets the new fluid requirements specified in Guide for Operation and Maintenance of Phosphate Ester Fire-resistant Fluid Used in Power Plant (DL/T 571—2014). Static and dynamic simulated aging tests demonstrated that the domestic phosphate ester fire-resistant fluid exhibits superior anti-aging performance compared to the commercially available alternatives. Following one year of industrial demonstration in power generation units, the fluid maintained new-oil quality standards throughout the application period, with the turbine governing system operating normally.
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| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |
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