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Ammonium bicarbonate is a potential denitrification reducing agent that can efficiently produce ammonia gas through direct solid pyrolysis. The pyrolysis reaction of ammonium bicarbonate solid is numerically simulated, a pyrolysis ammonia production system suitable for coal-fired power plants is designed, and the economic feasibility of the ammonium bicarbonate pyrolysis ammonia production process is analyzed. The simulation results show that, the pyrolysis process of ammonium bicarbonate favors the atmosphere pressure and the conversion rate of pyrolysis rapidly increases when the reaction temperature is above 110 ℃. The pyrolysis system of ammonium bicarbonate for a 660 MW unit has been designed and calculated. An external heating pyrolysis reactor is adopted to realize the utilization of waste heat and stable solid feeding. Steam or flue gas from the coal-fired power plant is used as the heat source for pyrolysis. At 110 ℃, a conversion rate of 95% can be reached within 10 minutes for ammonium bicarbonate feed. Compared with the urea hydrolysis process, the equipment cost, land occupation and operating cost of the ammonium bicarbonate solid pyrolysis process all significantly reduce, showing good prospects for promotion and application.
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| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |
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