In response to the escalating energy crisis and the mounting pressure associated with industrial solid waste disposal, the development of efficient and stable composite phase change heat storage materials is of paramount significance. This study uses solar salt as the phase change medium, with steel slag and fly ash employed as porous skeleton materials. A novel composite phase change heat storage material is synthesized via the cold pressing and hot sintering process. Through systematic optimization of material composition, the optimal mass ratio is determined as fly ash: steel slag: solar salt equal to 25:25:50. The characterization results demonstrate excellent chemical compatibility among the composite components, with no formation of new phases. The composite exhibits superior thermal energy storage performance, with a phase change latent heat of 57.96 J/g, a heat storage density of 291.968 J/g within the temperature range of 100~400 ℃ and a thermal conductivity of 0.952 W/(m·K). Mechanical property testing reveals a high compressive strength of 55.0 MPa. Crucially, the material maintains stable phase change behavior and structural integrity after 3 600 thermal cycles, with a mass loss rate below 0.05%. This research not only facilitates the high-value-added utilization of industrial solid wastes but also provides novel insights into the material design for medium and high-temperature thermal energy storage systems.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |