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Composition analysis and properties of phosphate ester fire-resistant fluid
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Zhanyang GAO1, Xiaowei WANG1, Fan ZHANG2, Juan WANG1, Rui CUI2, Guojun LONG1, Yu WANG1, Yongzhi XU2, Lun WANG1, Mingrui HAN2, Jie LIU2
Thermal Power Generation | 2026, 55(3) : 64 - 71
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Thermal Power Generation | 2026, 55(3): 64-71
Thermal Energy Science Research
Composition analysis and properties of phosphate ester fire-resistant fluid
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Zhanyang GAO1, Xiaowei WANG1, Fan ZHANG2, Juan WANG1, Rui CUI2, Guojun LONG1, Yu WANG1, Yongzhi XU2, Lun WANG1, Mingrui HAN2, Jie LIU2
Affiliations
  • 1.Xi’an Thermal Power Research Institute Co., Ltd., Xi’an 710054, China
  • 2.Xigu Branch, Huaneng Gansu Energy Development Co., Ltd., Lanzhou 730070, China
Published: 2026-03-25 doi: 10.19666/j.rlfd.202503067
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As the working medium of turbine speed-control systems in power plants, phosphate ester fire-resistant fluid (FRF) plays a vital role in the normal operation of steam turbines. During operation, the deterioration of FRF may result in an increase in acid value, a decrease in volume resistivity, and the formation of oil sludge, and the degree of decomposition and deterioration varies among different oils. The chemical composition of different kinds of FRF samples was analyzed, the deterioration process of different phosphate ester molecules was simulated, and their aging-resistance properties were tested. The results show that the performance of FRF with tris-(dimethylphenyl) phosphate as the main component is more stable than that of FRF with tert-butylphenyl phosphate as the main component. During the production of FRF, the content of dimethylphenyl in triaryl phosphate should be increased, and the content of phenyl and tert-butyl phenyl should be reduced.

phosphate ester fire-resistant fluid  /  chemical composition  /  aryl phenol  /  aging resistance performance
Zhanyang GAO, Xiaowei WANG, Fan ZHANG, Juan WANG, Rui CUI, Guojun LONG, Yu WANG, Yongzhi XU, Lun WANG, Mingrui HAN, Jie LIU. Composition analysis and properties of phosphate ester fire-resistant fluid[J]. Thermal Power Generation, 2026 , 55 (3) : 64 -71 . DOI: 10.19666/j.rlfd.202503067
  • Science and Technology Project of China Huaneng Group Co., Ltd.(HNKJ23-H22)
Year 2026 volume 55 Issue 3
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Article Info
doi: 10.19666/j.rlfd.202503067
  • Receive Date:2025-03-10
  • Online Date:2026-08-14
  • Published:2026-03-25
Article Data
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History
  • Received:2025-03-10
  • Revised:2025-05-22
  • Accepted:2025-05-28
Funding
Science and Technology Project of China Huaneng Group Co., Ltd.(HNKJ23-H22)
Affiliations
    1.Xi’an Thermal Power Research Institute Co., Ltd., Xi’an 710054, China
    2.Xigu Branch, Huaneng Gansu Energy Development Co., Ltd., Lanzhou 730070, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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