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  • Meng XU, Zhao AN, Ye WANG, Haojie YIN, Gaoyuan CHENG, Xingtao ZHANG
    Insulating Materials. 2021, 54(5): 47-53.

    In this paper, the low-temperature plasma was generated by DBD test platform, and the polyimide (PI) nanocomposite film was modified by the low-temperature plasma. The surface morphology, chemical bond structure, surface conductivity, and corona resistance of the nanocomposite film before and after the low-temperature plasma modification were tested to study the change law of the film surface characteristics. The results show that after surface modification, the nanocomposite film surface becomes rough gradually, and there are micropores and discontinuous protrusions appeared. Polar oxygen-rich groups were introduced on the surface by plasma modification with appropriate modification time. With the increase of modification time, the contact angle decreases, the surface energy and surface conductivity increase, and the corona resistance life increases at first and then decreases. When the low-temperature plasma modification time is 10 s, the corona resistance life of the modified nanocomposites film is 15.7% higher than that of the unmodified nanocomposites film. After modified by the low-temperature plasma, the nanocomposite film has more uniform surface than the pure PI film, and the modified nanocomposite film has the characteristics of small surface energy and large surface conductivity. The large surface conductivity will accelerate the dissipation speed of surface charge of the nanocomposite film, avoid the surface discharge produced by the concentration of local field strength, thereby improving the corona resistance life of the film. To obtain the same modification effect, the nanocomposite film need longer low-temperature plasma modification time than pure PI film.

  • Yin JIANG
    Insulating Materials. 2021, 54(5): 34-39.

    Using bisphenol A epoxy resin, phosphorus flame retardant, aluminum hydroxide, and molecular sieve as the main agent, organic anhydride and accelerator as curing agent, we prepared a halogen-free flame retardant potting material for film capacitor. The effects of different flame retardants and filling content on the glass transition temperature and flame retardancy of the potting materials and the durability of the capacitor were studied, and the optimum formula of halogen-free flame retardant potting material for film capacitor was determined. The results show that the glass transition temperature of the potting materials prepared by the optimum formula is 104℃, and the flame retardant is V0 (3 mm), and the electrical insulation performance is good. The film capacitor potted with this potting material can meet the 600 h durability test under the condition of 1.2 times of voltage and 85%RH /85℃, and the capacitance change rate before and after test is 3.93%.

  • Siyi XU, Dan CAO, Cheng ZHOU, Jianxi LI, Liguo SHEN
    Insulating Materials. 2021, 54(5): 66-71.

    In this paper, thermal ageing tests were conducted on the prepared silicone rubber-based flame-retardant transmission insulator samples at 210℃ for different times by high temperature accelerated ageing method, and their performance were tested by scanning electron microscope (SEM), Fourier infrared spectroscopy (FTIR), and contact angle tester. The results show that with the extension of ageing time, the melamine cyanurate (MCA) flame retardant particles in the sample decompose continuously, a large number of pores are formed on the surface of sample, and the infrared intensity of amino and hydroxyl functional groups continues to decrease. The contact angles measured by different solutions show a downward trend, and the erosion of hydrophobicity by the salt solution and acid solution is more serious. The lifetime of samples under the water condition calculated by Hallberg-Peck model and the contact angle is 16.6 years, the lifetime of samples under acid rain conditions is 10.4 years, and the lifetime of samples under seawater condition is 10.2 years.

  • Yuncai LU, Lu FAN, Fengbo TAO, Yi YIN
    Insulating Materials. 2021, 54(5): 10-20.

    Partial discharge would accelerate the ageing of power equipment insulation, which is an important monitoring indicator for the condition assessment of power equipment. The research related to partial discharge mainly include denoising of discharge signals, pattern recognition of defect types, equipment status assessment, and fault location of discharge sources. The artificial intelligence can effectively solve the problems of non-linear fitting and optimal solution in partial discharge detection. This paper introduces the detection methods of partial discharge, summarizes the application of artificial intelligence in both denoising of discharge signals and fault location of discharge sources, and points out the shortcomings and solutions in the current research.

  • Liang ZENG, Fang QI, Xiaoping DAI
    Insulating Materials. 2021, 54(5): 1-9.

    This paper introduces the research and application of polymer insulating materials in power module packaging, including silicone gel, epoxy potting adhesive, epoxy molding compound, plastic frame and other materials, and their performance indicators and research status at home and abroad were elaborated. Finally, the application direction of polymer insulating materials in power module packaging was prospected, including optimizing the use process, improving the stability and insulation performance, developing materials with temperature shock resistance, low linear thermal expansion coefficient, and high dielectric strength and studying new applications technology.

  • Wenjin WANG, Chang TANG, Xiqiang XU, Hongsheng CHEN, Xichuan LIANG, Changzhi XUE
    Insulating Materials. 2021, 54(5): 104-108.

    The traditional electromagnetic wire appearance defect detection uses manual detection, which is low efficiency and high cost. With the continuous improvement of requirements of motor on the appearance quality of electromagnetic wire, it is necessary to enhance the identification efficiency of electromagnetic wire appearance defects. A visual identity system of electromagnetic wires defects was developed, and the practical application effect of the system was verified. The results show that the defect visual identity system can improve the detection rate of the thin film sintering line appearance defects. By analyzing the statistical types and quantities of defects, the problems of raw materials or the production process problems of electromagnetic wire can be found in time, so as to formulate corrective measures in time and reduce the rejection rate of the thin film sintering line.

  • Yuandong WANG, Wenjiang SHI, Zhongyi YANG, Xingliang JIANG, Chao ZHANG, Zhijin ZHANG
    Insulating Materials. 2021, 54(5): 92-97.

    Polluted insulators are easy to discharge or even flashover when the surface is wet to a certain extent, which seriously threatens the safety and stability of power grid. In this paper, in view of three kinds of common insoluble contaminates SiO2, Al2O3, Fe2O3, we conducted water absorption tests and insulator flashover tests under different environmental humidity, and the influence of environment humidity on the water absorption and flashover properties of insulators polluted with typical insoluble contaminates were analyzed. The results show that the SiO2 has the best water absorption property, the Al2O3 is followed, and the Fe2O3 has extremely weak water absorption property or cannot absorb water absolutely. The moisture absorption rate and saturated moisture content of SiO2 and Al2O3 tend to increase with the increase of environment humidity. In the situation of saturated humidity, the surface contamination of insulators polluted by SiO2 and Al2O3 may be washed away with the dripping process of liquid droplets. The pollution flashover voltage gradient of insulators decreases with the increase of environmental humidity, and this phenomenon is more obvious in low humidity.

  • Lin YANG, Zhenglin YANG, Yanpeng HAO, Tingting WANG, Bing LUO, Wei XIAO
    Insulating Materials. 2021, 54(5): 98-103.

    In order to realize the detection of surface discharge by the temperature sensor inside the composite insulator sheath, we used silicone rubber plate as research object, and established a thermal model to realize the indirect calculation of surface temperature on the silicone rubber plate based on internal temperature. Firstly, according to the heat transfer theory, a thermal model of silicone rubber plate was established. Considering the influence of nonlinear factors in the process of atmospheric convection, the air convection index n was introduced to modify the model, and the solution method of convection heat transfer coefficient h was proposed. Then, temperature rise tests were carried out to simulate the heating condition of silicone rubber plate surface, and the temperature data of the upper and lower surfaces of silicone rubber plate were measured. The measured value of upper surface was compared with the calculated value of model. The results show that the relative error of the steady-state temperature of silicone rubber plate surface calculated by the model based on internal temperature is less than 10%, which meets the accuracy requirement.

  • Bo KONG, Yongpeng MENG, Yanhao MA, Siyu CHEN, Yushuan GAO, Ruocheng WANG, Yonghong CHENG
    Insulating Materials. 2021, 54(5): 27-33.

    Curing agent acts as a link of epoxy resin molecular chains, its molecular structure will affect the various properties of epoxy resin. In this paper, the influence of curing agent molecular structure on the thermal properties, polarization properties, charge transport properties, and energy storage properties of epoxy films were comprehensively discussed by adjusting the ratio of alicyclic amine to polyether amine in curing agent. The results show that with the increase of proportion of rigid alicyclic amine in curing agent, the thermal stability of epoxy resin is significantly enhanced, and the dielectric loss is greatly reduced. This is mainly because the increase of rigid groups can effectively restrict the turning of molecular segments and the transporting of charge. Meanwhile, with the increase of ratio of alicyclic amine, the electric strength and charge-discharge efficiency of the epoxy film increase at first and then decrease. The F51/AP1.6 has the most excellent electric strength, energy density, and charge-discharge efficiency under four different ratios of curing agent. This is related to its stable molecular structure, low dielectric loss, and extremely high deep traps density.

  • Lu BAI, Guanliang LI, Chengpeng YANG, Tao JIN, Laifu ZHANG, Xiaojing LI
    Insulating Materials. 2021, 54(5): 85-91.

    The degree of partial discharge in transformer is an important basis to reflect the ageing degree of transformer insulating oil and evaluate the service life of transformer oil. In this paper, six kinds of transformer insulating oil with different water content were conducted partial discharge tests by two different test methods and four electrode arrangements. The influence of different test methods and electrode arrangements on the partial discharge initial voltage was analyzed. The results show that the partial discharge initial voltage is not only related to the physical and chemical properties of liquid dielectric, but also affected by the electrode arrangement, water content, and test methods. The test methods affect the dispersion of test results. The water content would change the physical and chemical properties of liquid dielectric, thereby it affects the partial discharge initial voltage from the aspects of macro dielectric property and micro ionization process. With the increase of water content, the electrode arrangement and test methods have less influence on the partial discharge initial voltage. The main factors affecting the partial discharge initial voltage of insulating oil with different water contents change from electrode arrangement and test method to the physical and chemical properties of insulating oil.