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  • Jinpeng HAO, Hong WU, Shitao LIU, Kai YANG, Ziyi FANG, Yu WANG, Qiang WU
    Insulating Materials. 2021, 54(10): 73-78.

    Bird damage is an important factor affecting the safe operation of transmission lines. In order to quantitatively analyze the spatial electric field distribution of bird droppings near insulators, we carried out simulation and calculation on the bird droppings flashover of 110 kV composite insulators, and studied the influence of different factors on the electric field. The results show that the longer the continuous channel of bird droppings, and the closer it is to the insulator, the more probable that flashover occurs. The existence of grading ring shortens the distance between the high and low voltage ends, which will increase the flashover probability; the dropping path of bird droppings has a great influence on the flashover probability, and the flashover probability is the lowest when the bird dropping is on the different surface of the transmission line. Finally, combined with the simulation results, new protection range of bird droppings is proposed to give some advice for protecting transmission line from bird damage.

  • Jigang ZHOU, Xiyuan LI, Zhongkai XU, Yuancheng ZHU, Xizhong LI, Hongfeng MA
    Insulating Materials. 2021, 54(10): 79-83.

    The electric field strength and potential distribution of insulator strings with different locations, numbers and deterioration degrees of insulators were studied by finite element method. The results show that the deteriorated insulators at high and low voltage terminals has the greatest effect on the axial electric field of the insulator string, which significantly increases the peak amplitude of electric field at the deterioration location. Compared with the insulator string with a heavily deteriorated insulator, the electric field peak near the second insulator is greatly affected by the presence of two (first and second) deteriorated insulators. When the number and location of insulator degradation are the same, the effect of slightly deteriorated insulator on the axial electric field strength of insulator string is the same as that of zero value insulator, but the influence degree increases with the increase of degradation degree.

  • Yi LUO, Xiaorong ZHANG, Lue SUN, Congpeng HUANG, Yong ZHU
    Insulating Materials. 2021, 54(10): 105-109.

    Due to artificial operation and poor sealing performance during the assembly of oil-related equipment in some substation, the shed on composite insulator used in the auxiliary equipment may deform due to the contact with insulating oil. In order to further study the influence of insulating oil on the composite insulator shed and analyze the cause of its deformation, we used insulating oil to treat silicone rubber for shed, and investigated its volume change, chemical structure, hydrophobicity, mechanical properties, and electrical properties. The results show that the insulation oil increases the volume of silicone rubber, while decreases its elongation at break, tensile strength, tear strength, and hardness, which relates to the swelling of silicone rubber. According to the study, using oil dropping device and insulator to simulate the deforming process of the shed, we propose a method of recovering the deformation of the shed by heat treatment.

  • Huibin LIU, Yanwei WANG, Bo LI, Yongkun ZHU, Shenghui WANG, Wenwen ZHANG, Fangcheng LÜ
    Insulating Materials. 2021, 54(10): 84-88.

    Covering insulating sheath on transmission lines is one of the commonly measures to prevent bird damage in engineering, and the breakdown voltage of the air gap between bird droppings and the surface of sheath directly affects the configuration scheme of sheath. In this paper, the variation characteristics of breakdown voltage with the thickness of sheath and the influence of sheath defect on the breakdown voltage under different air gap distance were investigated by experiment, in which the bird droppings were simulated by copper rod. The results show that compared with bare wires, the breakdown voltage of the gap in the wires covered sheath with the thickness of 2.0, 3.0, 3.5 mm increases by 17.7%, 33.1%, 41.6%, respectively. Compared with new sheath of the same thickness, the breakdown voltage of gap in the defective sheath with the thicknesses of 2.0, 3.0, 3.5 mm decreases by 70.6%, 62.8%, 44.2%, respectively. It is concluded that the smaller the thickness of the defective sheath, the larger the decreasing amplitude of breakdown voltage.

  • Yao WANG, Zongke HOU, Jianying LI, Liucheng HAO, Kai LI, Xinke ZHAO, Jiguang SONG, Xiaogang CHEN
    Insulating Materials. 2021, 54(10): 41-50.

    It is one of the important methods to obtain the ZnO varistor ceramics with high-performance by improving the distribution uniformity of grain. In this paper, ZnO varistor ceramics samples doping with different contents of Sb2O3 were studied from several aspects such as the average grain size, distribution uniformity of grain size, and shape of grain. In addition, the non-uniform coefficient of grain size and the shape parameter were applied for quantification. The results show that with the increase of the doping content of Sb2O3, the average grain sizes, the non-uniform coefficients of grain size, and the shape parameters of the samples decrease generally. It suggests that the distribution uniformity of grain size is improved, and the grain shapes develop from slender to regular, which can also explain the enhance of the electrical properties of the samples. According to the analysis, the spinel phase formed after doping Sb2O3 inhibits the anisotropic growth of the crystal grains, which decreases the grain size and improves the uniform distribution and the shape of the grains. In addition, the inhibiting effect of spinel phase on the growth of grains in the large-grain region is weaker than that in the little-grain region.

  • Jianping LIAO, Jinwei CHU, Fan GAO, Yufei CHEN, Chen ZHANG, Siming YU, Huaqiang LI, Lisheng ZHONG
    Insulating Materials. 2021, 54(10): 20-25.

    Alkylbenzene insulating oil, represented by dodecylbenzene, is a kind of liquid medium that widely used in oil-filled submarine cables. Due to the stagnation of the development of oil-filled cable technology in China, the application and research of this type of insulating oil is relatively scarce. This paper introduced the physical and chemical, electrical, ageing, and biological toxicity of dodecylbenzene insulating oil for submarine cables.

  • Minghao WEI, Dongxin HE, Bo GAO, Bingxia JIANG, Wei WANG
    Insulating Materials. 2021, 54(10): 61-65.

    In order to study the effect of stress cone on the accumulation of space charge, we designed a cable model with stress cone structure. A platform was built to perform the combined electric and thermal ageing on the model cable. The distribution of space charge before and after ageing was measured by pulse electro-acoustic method, and the accumulation of space charge at different axial and radial positions was compared. The results show that more space charge accumulates at the root of the stress cone, and the accumulated space charge mainly distributes on the outside of the insulation layer of the cable. To make a preliminary explanation of this phenomenon, it is believed that the electric field distortion caused by the stress cone makes the space charge easy to accumulate in this area.

  • Yuqiao WANG, Qiaolong YUAN, Farong HUANG
    Insulating Materials. 2021, 54(10): 33-40.

    A triethoxyacetylenic silane (TEOAS) was synthesized to treat the surface of hydroxylated multiwalled carbon nanotubes (MWCNTs), and then the MWCNTs-T was obtained and characterized. PSA/MWCNTs and PSA/MWCNTs-T composite resins were prepared using solution method by mixing silicon-containing polyarylacetylene (PSA) with MWCNTs and MWCNTs-T, respectively. The thermal conductivity, thermal stability, electric insulation, and bending properties of the PSA/MWCNTs and PSA/MWCNTs-T composites were investigated. The results show that TEOAS was grafted on the surface of MWCNTs successfully, and MWCNTs-T is compatible with PSA matrix. The thermal conductivity of the composites increases with the increase of the mass fraction of MWCNTs and MWCNTs-T. The effect of MWCNTs-T is more obvious, with the mass fraction of 2%, the thermal conductivity of PSA/MWCNTs-T reaches 0.62 W/(m·K), which is 3 times as higher as that of PSA. The introduction of MWCNTs and MWCNTs-T can decrease the thermal stability and bending properties of PSA, the effect of MWCNTs-T is smaller than that of MWCNTs. The glass transition temperature of the PSA/MWCNTs is higher than 500℃, the electrical resistivity of the composite resin decreases linearly with the increase of frequency, while is still higher than 108 Ω·cm at 106 Hz.

  • Guangcheng ZHENG, Cuimiao ZHU, Siyi XU, Cheng ZHOU, Jianxi LI
    Insulating Materials. 2021, 54(10): 56-60.

    Silicone rubber/carbon iron powder composite was physically modified by adding hexagonal boron nitride (h-BN) through melt blending, and the effects of h-BN on the mechanical properties, magnetic permeability, thermal conductivity, and thermal ageing properties of the composite were analyzed. The results show that h-BN well distributes in the composite, and it has good compatibility with silicone rubber matrix. The introduction of h-BN can effectively increase the tensile strength of the composite, while decrease the magnetic permeability. When the adding amount of h-BN is more than 20 phr, the thermal conductivity increases effectively. Under the continuous thermal ageing, the tensile strength of the composite increases at first and then decreases, while the elongation at break decreases continuously.

  • Chuncheng CAO, Jie ZHANG, Yongli LUO, Lian DUAN, Penghao WANG, Ziqiu LUO, Ping XU
    Insulating Materials. 2021, 54(10): 93-99.

    On the basis of the impregnation mechanism analysis of oil-paper insulation, a test model of mixed insulating oil-paper impregnation was designed, and the main factors affecting the impregnation process of oil-paper insulation were discussed. The relationship diagram of the insulation impregnation length of mixed insulation oil-paper insulation with time was obtained through experiments, and it was compared with that of mineral oil-paper insulation. The results show that the impregnation effect of mixed insulating oil-paper insulation is weaker than that of mineral insulating oil, but the difference is slight. When the impregnation temperature and vacuum degree increase at the same time, the impregnation effect of the two kinds of insulating oil-paper insulation improves significantly in the impregnation stage of 12-36 h. The oil injection process of the mixed oil transformer was implemented on actual transformer, and the effectiveness of the process is verified by the high voltage test.