Home Journals Articles Updates About
CN
image
收藏切换
One-Step Hydrothermal Synthesis of NiCuP/NF Catalyst and Its Hydrogen Evolution Performance
收藏切换
Shizhi DONG1, 2, Jiaqi HE1, Zhuang MA1, Xudong HU1, Jinpeng YIN1, Hongyu HU1, Zhiyu LIU1, Xing ZHANG1
Journal of the Chinese Ceramic Society | 2023, 51(1) : 152 - 162
Less
收藏切换
Journal of the Chinese Ceramic Society | 2023, 51(1): 152-162
• Research Articles •
One-Step Hydrothermal Synthesis of NiCuP/NF Catalyst and Its Hydrogen Evolution Performance
Full
Shizhi DONG1, 2, Jiaqi HE1, Zhuang MA1, Xudong HU1, Jinpeng YIN1, Hongyu HU1, Zhiyu LIU1, Xing ZHANG1
Affiliations
  • 1.College of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, Liaoning, China
  • 2.School of Chemistry and Environment, Beihang University, Beijing 100191, China

    • DONG Shizhi (1981-), female, Ph.D., Associate Professor. E-mail:

About Author:

DONG Shizhi (1981-), female, Ph.D., Associate Professor. E-mail:

Published: 2023-01-20 doi: 10.14062/j.issn.0454-5648.20220647
Outline
收藏切换

Electrolysis of water to produce hydrogen is a promising green method to achieve sustainable energy supply. A NiCuP foam nickel hydrogen precipitation electrocatalyst was prepared by one-step hydrothermal method. The results show that the electrocatalyst has a good hydrogen reaction activity at 12 h at the nickel-copper ratio of 8∶1 and the hydrothermal temperature of 140 ℃. The effect of modifier on the catalytic activity was also investigated. It is indicated that the addition of the modifier NaCl can provide a better ion interaction environment, thus significantly improving the catalytic performance. At a current density of 10 mA/cm2, the overpotential is 108 mV with a Tafel slope of 113 mV/dec (the overpotential change is 113 mV for every 10-fold change in current). The calculations show that the atomic d-p orbital interaction of Ni2P-Cu3P induces an enhancement of the electronic activity at the catalyst interface, thus reducing the activation barrier. Moreover, the addition of NaCl promotes the dissociation of H2O molecules into H ions, thus enhancing the catalytic activity of hydrogen evolution reaction. This work provides a research basis for the research and development of transition metal electrocatalysts.

transition metal phosphates  /  hydrogen precipitation reaction  /  density functional theory  /  electrocatalyst  /  synergy
董世知, 何佳奇, 马壮, 胡旭东, 尹金鹏, 胡宏宇, 刘志宇, 张星. 一步水热法合成镍铜复合磷化物及其电催化析氢性能. 硅酸盐学报, 2023 , 51 (1) : 152 -162 . DOI: 10.14062/j.issn.0454-5648.20220647
Shizhi DONG, Jiaqi HE, Zhuang MA, Xudong HU, Jinpeng YIN, Hongyu HU, Zhiyu LIU, Xing ZHANG. One-Step Hydrothermal Synthesis of NiCuP/NF Catalyst and Its Hydrogen Evolution Performance[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (1) : 152 -162 . DOI: 10.14062/j.issn.0454-5648.20220647
Appendix
Less
Year 2023 volume 51 Issue 1
26
3
Cite this Article
BibTeX
Article Info
doi: 10.14062/j.issn.0454-5648.20220647
  • Receive Date：2022-08-08
  • Online Date：2026-10-20
  • Published：2023-01-20
Article Data
Affiliations
History
  • Received：2022-08-08
  • Revised：2022-09-01
Funding
Affiliations
    1.College of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, Liaoning, China
    2.School of Chemistry and Environment, Beihang University, Beijing 100191, China
References
Share
https://castjournals.cast.org.cn/joweb/gsyxb/EN/10.14062/j.issn.0454-5648.20220647
Share to
QR

Scan QR to access full text

Cite this article
BibTeX
Citations
表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
关闭全屏
  • BibTeX
  • EndNote
  • RefWorks
  • TxT
Links
Articles
Latest Articles
Most Read
Collections
Updates
Events
News
Multimedia
About
About Us
Contact
No. 86 Xueyuan South Road, Haidian District, Beijing
100081
010-62662699(Operation and Technical Support)
qkjq@cast.org.cn

Copyright © 2025 China Association for Science and Technology. All rights reserved. For all open access content, the relevant licensing terms apply.
Sponsored by the Office of the Leading Group for Cybersecurity and Informatization of CAST, and supported by Science and Technology Review Publishing House