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Preparation and High-Frequency Dielectric Properties of Micron-Sized Spherical TiO2 and Epoxy Matrix Composites
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Zaizai YU1, Ling LI1, Jian LIU1, Yang WANG2, Luming QI3, Tao SONG1
Journal of the Chinese Ceramic Society | 2023, 51(10) : 2634 - 2643
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Journal of the Chinese Ceramic Society | 2023, 51(10): 2634-2643
• Research Articles •
Preparation and High-Frequency Dielectric Properties of Micron-Sized Spherical TiO2 and Epoxy Matrix Composites
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Zaizai YU1, Ling LI1, Jian LIU1, Yang WANG2, Luming QI3, Tao SONG1
Affiliations
  • 1.Shandong Industrial Ceramics Research and Design Institute, Zibo 255000, Shandong, China
  • 2.School of Materials Science and Engineering, University of Jinan, Jinan 250022, China
  • 3.Sinoma Advanced Materials Co., Ltd, Beijing 100102, China
  • YU Zaizai (1993-), male, Master candidate. E-mail:

About Author:

YU Zaizai (1993-), male, Master candidate. E-mail:

Published: 2023-09-20 doi: 10.14062/j.issn.0454-5648.20230275
Outline
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Printed circuit boards (PCBs) are usually required to be integrated and miniaturized by a variety of applications, such as 5G microstrip antenna and millimeter wave radar, which require the used dielectric substrate materials with a low dielectric loss (Df) and a high dielectric constant (Dk). The composite substrate prepared by filling dielectric ceramics into organic polymers has good machinability and superior dielectric properties, which is regarded as the most promising solution. However, the physical and chemical indexes, dielectric properties of the ceramic filler and its compatibility with organic resins are three key factors affecting the comprehensive properties of organic/inorganic composites. In this paper, a micron-spherical filler with a high sphericity and a high crystallinity was prepared by a special spheroidization technology with titanium dioxide material with superior dielectric properties (i.e., Dk ≈110, Df ≈ 0.001, dielectric constant temperature coefficient (α) ≈ -700×10-6 ℃-1). The compatibility between the filler and organic resin is improved after the surface modification of TiO2 filler. Also, the dielectric constant temperature coefficient of TiO2 filler is regulated by Al2O3 doping. The composite substrate filling with 20% (in mass) Al2O3 exhibits the superior properties (i.e., Dk=10.2, Df=0.001 9, and α= -405×10-6 ℃-1). This indicates that the as-prepared ceramic filler has the promising characteristics for potential applications of 5G high-frequency, high-dielectric PCBs.

dielectric properties  /  titanium dioxide fillers  /  composites  /  surface modification
禹在在, 李伶, 刘建, 汪洋, 亓鲁鸣, 宋涛. 微米级球形TiO2的制备及其树脂基复合材料的高频介电性能. 硅酸盐学报, 2023 , 51 (10) : 2634 -2643 . DOI: 10.14062/j.issn.0454-5648.20230275
Zaizai YU, Ling LI, Jian LIU, Yang WANG, Luming QI, Tao SONG. Preparation and High-Frequency Dielectric Properties of Micron-Sized Spherical TiO2 and Epoxy Matrix Composites[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (10) : 2634 -2643 . DOI: 10.14062/j.issn.0454-5648.20230275
Year 2023 volume 51 Issue 10
36
5
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Article Info
doi: 10.14062/j.issn.0454-5648.20230275
  • Receive Date:2023-04-26
  • Online Date:2026-10-19
  • Published:2023-09-20
Article Data
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History
  • Received:2023-04-26
  • Revised:2023-06-13
Funding
Affiliations
    1.Shandong Industrial Ceramics Research and Design Institute, Zibo 255000, Shandong, China
    2.School of Materials Science and Engineering, University of Jinan, Jinan 250022, China
    3.Sinoma Advanced Materials Co., Ltd, Beijing 100102, China

Corresponding:

SONG Tao (1981-), male, Professor. E-mail:
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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