Home Archive
Archive
2024 Volume 50 Issue 5  Published: 2024-10-25
  • Wu Hu-lin

    In the paper, the technical progress of ironmaking system of Baotou Steel is summarized and analyzed. It is thought that the technological breakthrough and innovation of beneficiation, sintering and smelting problems for special iron ore of Bayan Obo are fundamental guarantee for achieving the ironmaking production with high efficiency and quality, low consumption, long service life and environmental protection as well as technical support of great-leap-forward development for ironmaking of Baotou Steel.

  • Yu Hao , Liang Zhi-gang , Hao Bai-chuan , He Jian-zhong , Han Jun-gang , Shao Hui-min

    In the process of developing high quality steel, rare earth elements are widely used and effects are significant. In this paper, the mechanisms of action and lack of research of rare earth elements in steel are summarized as well as application situations of rare earth elements in wear-resistant steel, H beam and corrosion-resistant steel are overviewed. The design thinking of determining additive amount of rare earth by scie.pngically applying the first principle of density functional theory and combining mismatch theory with thermodynamic calculations is proposed aiming at such problems as lack of researches for the theory of determining additive amount of rare earth as well as solid solution of rare earth and mechanisms of action of the rare earth at grain boundary in steel, which could provide the thinking and references for design and wide applications of rare earth steel alloy.

  • Wang Guo-cheng , Xiao Yuan-you , Zhang Da-xian , Tang Jian-ping , He Jian-zhong

    The development of high performance rare earth steel with special effects of rare earth elements is of great significances for the utilization of rare earth resources and technological progress of iron and steel in Baotou, while it is the key for developing rare earth steel to clear the quantitative behavior of rare earth in steel. In the paper, the behaviors and mechanisms of rare earth elements in steel are discussed from such aspects as their thermodynamics, nucleation of rare earth inclusions and mechanism of internal friction for rare earth. Moreover, the non destructive characterization methods of rare earth inclusions are introduced.

  • Hao Juan-juan , Qu Wen-sheng , Liu Peng-cheng , Lu Xiao-yu , Wu Yu-xuan , Feng Hai-tao , Li Yang

    As an important manufacturing process of oriented silicon steel, the normalizing process has a key effect on magnetic properties of high magnetic induction oriented silicon steel. In the paper, the effects of holding time and cooling rate for normalizing on microstructure and texture of high magnetic induction oriented silicon steel are studied with optical microscope and X-ray diffractometer. The microstructure and texture of normalizing plate are similar to those of hot rolled plate as well as microstructure is with nonuniformity in the direction of plate thickness. The main types of texture are Goss texture {110}<001>, copper type texture {112}<111> and brass type texture {110}<112>. With the extension of holding time, grains recrystallize completely and texture types are changed significantly; with the increase of cooling rate, there are not significant changes for microstructure and texture types as well as strength of Goss texture is increased.

  • Zhu Hong-yu , Wang Zhen-dong , Tang Hai-yan , Liu Zhen-qi , Li Hong-peng , Deng Yan-tong , Zhang Jia-quan

    The warping on surface of hot rolled plate and strip is always the common defect that troubles production of high quality strip. The causes for warping defect on surface of steel could be throughout the whole process of steel production such as smelting, continuous casting, hot rolling and cold rolling. The types of warping defect are various and influencing factors are complex. The causes of common warping defect are classified into 5 types based on their morphology and microstructure characteristics, which are subsurface inclusions, surface cracks, subsurface bubbles, rolled-in scale and edgefold of intermediate billet. The probability of occurrence of warping defect for products could be reduced significantly by enhancing management of production equipment and process interfaces, especially increasing the level of continuous casting process from the origin to improve surface quality of ingot blank.

  • Liu Yan , Qu Wen-sheng , Song Wen-zhong , Wang Ya-nan

    In this article, the effects of key hot rolling process parameters on the properties of hot dip galvanized extra deep drawing IF steel for home appliances are studied combining with production practices. The analysis on the texture, me-tallographic structure and mechanical properties of test steel at finishing rolling temperatures of 880 ℃ and 915 ℃ as well as coiling temperatures of 680 ℃ and 710 ℃ separately are carried out. The study results revealed the correlation between different hot rolling process parameters and texture, metallographic structure as well as mechanical properties of finished product of hot dip galvanized extra deep drawing IF steel for home appliances, which could be as the reference for improving the properties of hot dip galvanized extra deep drawing IF steel products through establishing reasonable hot rolling process.

  • Dong Rui-feng , Zhao Jun-hui , Zhao Qing-bo , Lu Yong-fa , Yang Feng

    With the rapid rise of production and sales volume for new energy automobile, the quantity demanded of ultra high strength automobile steel is increasing. The problems such as spring back, deformation and cracking in cold forming process of ultra high strength automobile steel become the main factors restricting its applications. Therefore, it is of practical application values and huge market potential to develop a kind of automobile steel with high strength and excellent formability. It is found in many studies that the comprehensive properties of automobile steel could be improved by adding rare earth elements. In this paper, two groups of composition schemes are designed and the same process parameters of annealing of reverse transformation (ART) are used. The influencing mechanisms of rare earth elements on the microstructure and properties of cold formed ultra high strength automobile steel are studied by means of tensile test, scanning electron microscopy and X-ray diffraction (XRD). The results showed that the microstructure of experimental steel was martensite, retained austenite and trace ferrite under the ART process, but content of retained austenite of experimental steel with rare earth in the two composition schemes was slightly higher than that of experimental steel without rare earth, which provided the microstructure basis for transformation-induced plasticity (TRIP) effect in subsequent forming process. Under the optimum heat treatment process parameters of quenching at 800 ℃ and holding for 5 min., then annealing at 645 ℃ and holding for 15 min., the content of retained austenite in experimental steel with rare earth in the first scheme is increased by 8.1% compared with that of experimental steel without rare earth, percentage elongation after fracture is increased by 21.8% as well as product of strength and elongation (PSE) is increased by 17.2% and reaches 28.47 GPa·%; in the second scheme, the content of retained austenite in experimental steel with rare earth is increased by 4% compared with that of experimental steel without rare earth, percentage elongation after fracture is increased by 2.8% as well as PSE is increased by 5.1% and reaches 34.8 GPa·%, which illustrate that the comprehensive properties of ultra high strength automobile steel could be improved to different extent by adding rare earth elements.

  • Mi Yong-feng , Yao Xiao-le , Jiang Tao , Sun Wen-xiu , Kang Hong , Liu Yu-rong , Wang Zeng-hai

    The effects of rare earth Ce on the microstructure and properties of V, Ti microalloyed steel are studied by tensile and impact tests as well as with such analysis means as transmission electron microscope, scanning electron microscope and energy spectrometer. The results showed that the interlamellar spacing of pearlite for test steel was decreased, inclusions containing titanium were changed from rectangle with sharp edge angle to smooth spherality as well as long and thin MnS inclusions became shorter and spherized with the increase of rare earth Ce content. Moreover, the yield strength and impact toughness of test steel are improved.

  • Wang Han-tong , Zheng Wen-yue , Wen Qi-yun , Su Cheng , Lu Bin

    In this article, it is firstly introduced the current situations of pipeline for hydrogen transport and hydrogen mixing pipeline for natural gas at home and abroad as well as representative domestic project program of pipeline for hydrogen transport such as the hydrogen transport engineering of “west to east hydrogen transmission” led by Sinopec. Secondly, the relevant international standards for construction as well as operation and maintenance management of pipeline for hydrogen transport are briefly introduced. Finally, the development opportunities of hydrogen resistant pipeline steel are introduced from four aspects, which mainly include optimizing alloy composition as well as smelting, rolling and heat treatment processes of steel for storage and transportation pipeline and container; regulating and controlling size, morphology, type and distribution of inclusions in steel as well as controlling banded structure and harmful oxide; evaluating and optimizing mechanical properties of welding materials, welds with welding process and heat affected zone in hydrogen environment, improving welding process of steel for storage and transportation pipeline, storage containers and pipeline as well as studying the effect laws of alloy compositions of base metal, compositions of welding materials and welding processes on hydrogen embrittlement of weld heat-affected zone; establishing requirement specifications for pipeline materials and products including hydrogen compatibility of base metal of pipeline and welded joints.

  • Song Guang-jie , Wang Yi , Zhang Da-xian , Zhang Feng-ming , Fu Jian-xun , He Jian-zhong

    Baotou Steel is one of the main production bases of heavy rail steel in China and large size nonmetallic inclusions are the bottleneck restricting improvement of quality of heavy rail steel. In this paper, the control technology for superfine dispersion of inclusions in heavy rail steel with magnesium is developed based on the physicochemical and metallurgical properties of magnesium. The comparative analysis between industrial tests of magnesium modification and traditional process showed that the inclusions in heavy rail steel such as MnS and CaO-Al2O3-SiO2 were transformed into small size composite inclusions of MgO·Al2O3 and MnS, density of inclusions on vertical and horizontal observation planes and intermediate vertical observation plane of the rail were increased from 17 mm-2, 21 mm-2 and 18 mm-2 to 22 mm-2, 29 mm-2 and 25 mm-2 respectively, while equivalent diameters were decreased from 2.7 μm, 2.6 μm and 2.4 μm to 2.3 μm, 2.4 μm and 2.3 μm respectively as well as proportion of area of inclusions were decreased from 0.017%, 0.016% and 0.014% to 0.013%, 0.014% and 0.012% respectively after magnesium modification. Moreover, the nonmetallic inclusions in steel are rated as Grade A (0.5, 0.5), Grade B (0.5, 0.5), Grade C (1.0, 0.5), Grade D (0.5, 0.5) and Grade Ds (0) according to Method A as well as rated as 2.78 according to Method K. The inclusions of heavy rail steel after magnesium modification could meet the standard requirements.

  • Liang Zheng-wei

    On the occasion of the 70th anniversary of establishment of Baotou Steel, the works done for transformation and upgrading of key technologies and equipment of rail of Baotou Steel, creating characteristic rail products with advantages of rare earth resources as well as developing new technologies and steel grades of rail to satisfy the demands of rail market at home and abroad are summarized in this paper. In the 70-year process of enterprise development, brand building of rail of Baotou Steel becomes mature continuously with the enterprise development. Relying on advantages of rare earth resources and technological inheritance, Baotou Steel strives to create characteristic brand of rail to support the brand development strategy of “rare earth rail” and puts forth effort to building rail products as well known brands at home and abroad. Moreover, the brand advantages are transformed into driving forces of enterprise development, various property indexes of rail products are continuously improved by closely combining with the demands of user side so that rail of Baotou Steel could always maintain advanced level in the industry.

  • Jiang Bo , Zhang Ning , He Jian-zhong , Liu Zhou-li , Liu Ya-zheng

    With the increasing demand of high quality carburizing steel for key spare parts as well as proposal of “carbon peaking and carbon neutrality goals”, the requirements for such comprehensive properties of carburizing gear steel as wear resistance and strength and toughness are higher. It is the development direction of carburizing gear steel to develop high efficiency, energy saving, low carbon and economic high temperature carburizing technology with rare earth microalloying. In the paper, it is discussed the key problems and regulation of microstructure and properties for applications of rare earth in high temperature carburizing gear steel as well as summarized the applications and development trend of high temperature carburizing for gear steel with rare earth microalloying through introducing the applications and development situations of high temperature carburizing gear steel at home and abroad, which are of great significances for developing high temperature carburizing gear steel with rare earth characteristics.

  • Lu Bin , Huang Fei , Li Jing

    In order to improve the corrosion resistance of HRB400E steel, test steel is rolled by adding lanthanum-cerium mischmetal into it in refining process and controlling rolling-start-temperature. The inclusions and microstructure are characterized with scanning electron microscope, energy dispersive spectrometer and optical metallographic microscope as well as the effects of rare earth and rolling-start-temperature on corrosion resistance of test steel are analyzed combining with neutral salt spray test. The results showed that the Mn-Si-O inclusions were completely transformed into (Ce, La)2O3 and (Ce, La)2O2S after treatment with lanthanum-cerium mischmetal as well as part of Mn and S were nucleated around them to form complex inclusions of rare earth, but a small amount of individual MnS inclusion was still precipitated. Under the experimental conditions, the corrosion resistance of 2# test steel is optimal when rolling-start-temperature is 900 ℃, content of mischmetal is 0.011 6% and corrosion rate is 1.577 g/(m2·h).

  • Hu Bo , Cao Xiao-ming , Wang Hong-tao , Xu Xiao-ming , Ban Hua , Miao Zhi-gang , Hou De-qiang , Wu Wei-dong

    As the important steel of basic building components, screw-thread steel is widely used in such engineering constructions as buildings, bridges and roads. Its proportion of carbon emission is higher in building materials due to its large consumption so that the management and evaluation research of carbon footprint in its manufacturing process are particularly important. In this article, the key direction for its carbon reduction is found out through analyzing operation and conversion of carbon flow in its production process. The data of carbon emission and carbon footprint of products is qua.pngied as well as all of potential influencing factors are calculated with the LCA method so as to ide.pngy and control key areas of carbon emission, which could provide guidance for Baotou Steel to establish measures and plans of carbon reduction as well as environmental product declarations(EPD) of screw-thread steel products are successfully released on the EPD platform.

  • Tian Ying , Wang Yu , Liu Jia-feng , Sun Lei , Hu Hai-yang

    In the paper, it is introduced current treatment processes and utilization ways of coking high salinity wastewater as well as analyzed the restraining factors and solutions for technologies of salt separation and crystallization in treatment of coking wastewater. The treatment scheme of deep oxidation, salt separation and crystallization for coking high salinity wastewater is adopted by a coke making enterprise based on the existing biochemical treatment, deep treatment and membrane concentration treatment to further remove such pollutants as organic matters, ammonia nitrogen and fluoride in coking high salinity wastewater so that wastewater recycling is realized. Moreover, the recycling and zero discharge of coking wastewater are realized through producing such two high quality by products of crystal salt as sodium chloride and sodium sulfate by evaporation crystallization.