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Research on Three Methods for Calculating Heat Release from Ortho-Para Catalytic Conversion in Cryogenic Hydrogen Storage Systems
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Tenglong Yue, Jingxuan Xu
Journal of Refrigeration | 2025, 46(5) : 47 - 57
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Journal of Refrigeration | 2025, 46(5): 47-57
Hydrogen Liquefaction & Cryogenic Storage and Transmission
Research on Three Methods for Calculating Heat Release from Ortho-Para Catalytic Conversion in Cryogenic Hydrogen Storage Systems
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Tenglong Yue, Jingxuan Xu
Affiliations
  • Institute of Energy Storage Science and Engineering, University of Shanghai for Science and Technology, Shanghai, 200093, China
Published: 2025-10-16 doi: 10.12465/j.issn.0253-4339.2025.05.047
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In cryogenic hydrogen storage systems, an accurate calculation method for the heat release from different ortho-para hydrogen catalytic conversions is important to determine the load of hydrogen storage systems. The objective of this study is to present a precise calculation method for the conversion heat of ortho-para hydrogen. By establishing a conversion model, the methods of using a smoothing spline curve to fit the experimental data and energy balance calculations are used to derive the released heat in adiabatic conversion multistage converters and the released heat during continuous conversion. The heat release properties of different conversion methods are analyzed in this study. Notably, the heat release amount of continuous conversion is the smallest, that of isothermal conversion is the largest, and the conversion heat of adiabatic conversion is in between, which is related to the number of conversion stages. In addition, a specific method and procedure are programmed to solve the implicit differential formula for continuous conversion. Finally, the calculation results of the different methods are consistent with a maximum deviation of only 0.22%, indicating that the calculations in this study are valid and accurate.

ortho-para conversion  /  conversion heat  /  hydrogen storage technology  /  data processing  /  error analysis
Tenglong Yue, Jingxuan Xu. Research on Three Methods for Calculating Heat Release from Ortho-Para Catalytic Conversion in Cryogenic Hydrogen Storage Systems[J]. Journal of Refrigeration, 2025 , 46 (5) : 47 -57 . DOI: 10.12465/j.issn.0253-4339.2025.05.047
Year 2025 volume 46 Issue 5
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Article Info
doi: 10.12465/j.issn.0253-4339.2025.05.047
  • Receive Date:2025-04-19
  • Online Date:2026-03-13
  • Published:2025-10-16
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History
  • Received:2025-04-19
  • Revised:2025-04-28
  • Accepted:2025-05-07
Affiliations
    Institute of Energy Storage Science and Engineering, University of Shanghai for Science and Technology, Shanghai, 200093, China

Corresponding:

Xu Jingxuan, female, associate professor, School of Energy and Power Engineering, University of Shanghai for Science and Technology, 86-18217105157, E-mail: . Research fields: cryogenic hydrogen energy storage and transportation, cryogenic energy storage technology.
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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