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Effect of crystal transformation of hydrolysis products on coagulation performance of iron salt for algae removal
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Xin FANG1, Jun-li WAN1, 2, *, Xiao-bao NIE1, 2, Luan-lin TU1, Shi-quan SUN1, 2, Yu-xin ZHAO3
China Environmental Science | 2026, 46(1) : 152 - 160
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China Environmental Science | 2026, 46(1): 152-160
• Water Pollution Control •
Effect of crystal transformation of hydrolysis products on coagulation performance of iron salt for algae removal
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Xin FANG1, Jun-li WAN1, 2, *, Xiao-bao NIE1, 2, Luan-lin TU1, Shi-quan SUN1, 2, Yu-xin ZHAO3
Affiliations
  • 1.School of Hydraulic and Ocean Engineering, Changsha University of Science and Technology, Changsha 410114, China
  • 2.Key Laboratory of Dongting Lake Aquatic Eco-Environmental Control and Restoration of Hunan Province, Changsha 410114, China
  • 3.Dongneng Zhuohuan Survey and Design Co., Ltd., Changsha 410116, China
Published: 2026-01-20
Outline
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Outbreak of blue-green algae posesa threat todrinking water safety. Coagulation is a key technology for algae removal in waterworks, andiron salt is one of the most commonly used coagulants. To further explore the mechanism of iron salt for removing algae, Microcystis aeruginosa and algal organic matters were selected as the target pollutants. The effect of crystal transformation of the main hydrolysis products on removal efficiency and coagulation process was investigated. The results indicated thatthe transformationof crystalline state, crystalline phase, and crystal form of hydrolysis products were mainly affected by the coagulant dosage and pH value. With the increase of dosage and pH, the main hydrolysis product FeO(OH) was replaced by amorphous Fe(OH)3(PDF#22-0346), and then converted to Fe3O4. Amorphous Fe(OH)3 finally transformed into quasicrystalFe (OH)3(PDF#38-0032). The surface characteristics of algal flocs were affected by the crystalline state and crystal form change of hydrolysis products. The maximum SBET and Vt values of algal flocs were observed at a dosage of 0.7mmolFe/L, which werebeneficial to adsorb algal organic matters andresulted in the optimal treatment efficiency. Within the range of 0.1~0.5mmolFe/L, the crystal transformation of the main hydrolysis products had a more significant effect on algae removal efficiency, particle size and growth rate of algal flocs.

iron salts  /  coagulation  /  hydrolysis products  /  crystal transformation  /  algae removal
方鑫, 万俊力, 聂小保, 涂栾林, 孙士权, 赵宇新. 水解产物晶型转变对铁盐混凝除藻的影响. 中国环境科学, 2026 , 46 (1) : 152 -160 .
Xin FANG, Jun-li WAN, Xiao-bao NIE, Luan-lin TU, Shi-quan SUN, Yu-xin ZHAO. Effect of crystal transformation of hydrolysis products on coagulation performance of iron salt for algae removal[J]. China Environmental Science, 2026 , 46 (1) : 152 -160 .
Year 2026 volume 46 Issue 1
68
16
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Article Info
  • Receive Date:2025-05-22
  • Online Date:2026-10-08
  • Published:2026-01-20
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  • Received:2025-05-22
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Affiliations
    1.School of Hydraulic and Ocean Engineering, Changsha University of Science and Technology, Changsha 410114, China
    2.Key Laboratory of Dongting Lake Aquatic Eco-Environmental Control and Restoration of Hunan Province, Changsha 410114, China
    3.Dongneng Zhuohuan Survey and Design Co., Ltd., Changsha 410116, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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