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Effects and conditioning mechanisms of sludge dewaterability by activating persulfate with a combination of ultraviolet light and ferrous iron
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Mei LAN*, Pei-sen YANG, Hui-long ZHANG, Jia-lu KONG
China Environmental Science | 2026, 46(1) : 238 - 247
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China Environmental Science | 2026, 46(1): 238-247
• Solid Waste •
Effects and conditioning mechanisms of sludge dewaterability by activating persulfate with a combination of ultraviolet light and ferrous iron
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Mei LAN*, Pei-sen YANG, Hui-long ZHANG, Jia-lu KONG
Affiliations
  • Hebei Engineering Research Center of Sewage Treatment and Resource Utilization, Key Laboratory of Urban Water Utilization Technology of Handan City, Hebei Provincial Technology Innovation Center for Water Pollution Control and Water Ecological Restoration, Hebei University of Engineering, Handan 056038, China
Published: 2026-01-20
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A combined conditioning system using NaClO as the oxidizing agent was employed to condition sludge. The variations in sludge dewatering performance before and after conditioning were investigated to validate the enhancing effect of ultraviolet irradiation on the advanced oxidation process. Meanwhile, the reasons for the deterioration in dewatering performance were discussed when NaClO was added alone. The effects of dosage ratios (NaClO/FeSO4), Fe2+ dosage, and pH value on sludge dewatering performance were investigated using the capillary suction time (CST) and specific resistance to filtration (SRF) as key evaluation indicators. The results demonstrated that the ultraviolet irradiation activated a higher concentration of strong oxidative free radicals based on the activation of Fe2+ towards NaClO, thereby promoting the decomposition of EPS. With the addition of UV irradiation, the CST reduction rate increased from 61.5% to 65.4%, while the SRF reduction rate increased from 71.4% to 79.8%. During the experiment, the TB-EPS of the sludge were converted into the LB-EPS of the sludge. As a result of this conversion, the decomposition and oxidation of protein played a crucial role in enhancing sludge dewaterability. Analysis revealed that the deterioration in dewatering when NaClO was added alone was attributable to the insufficient oxidation capacity within the system and the excessive formation of bubbles during the conditioning process.

sludge dewatering  /  UV/Fe2+/NaClO  /  advanced oxidation process  /  extracellular polymeric substances (EPS)
蓝梅, 杨培森, 张慧龙, 孔嘉璐. 紫外光联合二价铁活化次氯酸钠对污泥脱水影响及调理机制. 中国环境科学, 2026 , 46 (1) : 238 -247 .
Mei LAN, Pei-sen YANG, Hui-long ZHANG, Jia-lu KONG. Effects and conditioning mechanisms of sludge dewaterability by activating persulfate with a combination of ultraviolet light and ferrous iron[J]. China Environmental Science, 2026 , 46 (1) : 238 -247 .
Year 2026 volume 46 Issue 1
74
18
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  • Receive Date:2024-07-07
  • Online Date:2026-10-08
  • Published:2026-01-20
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  • Received:2024-07-07
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    Hebei Engineering Research Center of Sewage Treatment and Resource Utilization, Key Laboratory of Urban Water Utilization Technology of Handan City, Hebei Provincial Technology Innovation Center for Water Pollution Control and Water Ecological Restoration, Hebei University of Engineering, Handan 056038, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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