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Exploring the drivers of PM2.5-O3 spatial differentiation in 274 Chinese prefecture-level cities
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Bin ZOU1, Man-man XIE1, Sha LI1, 2, *, Ning LIU3, Shen-xin LI1, Ying XIONG4
China Environmental Science | 2025, 45(11) : 6032 - 6044
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China Environmental Science | 2025, 45(11): 6032-6044
• Air Pollution Control •
Exploring the drivers of PM2.5-O3 spatial differentiation in 274 Chinese prefecture-level cities
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Bin ZOU1, Man-man XIE1, Sha LI1, 2, *, Ning LIU3, Shen-xin LI1, Ying XIONG4
Affiliations
  • 1.School of Geosciences and Info-physics, Central South University, Changsha 410083, China
  • 2.School of Hydraulic and Ocean Engineering, Changsha University of Science & Technology, Changsha 410114, China
  • 3.College of Meteorology and Oceanography, National University of Defense Technology, Changsha 410073, China
  • 4.College of Architecture, Changsha University of Science & Technology, Changsha 410114, China
Published: 2025-11-20
Outline
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In this study, based on the urban statistical yearbook and multi-source remote sensing data—including pollutant concentrations, nighttime light intensity, and land cover—the spatiotemporal distribution characteristics of PM2.5-O3 compound pollution across 274 prefecture-level cities in China were examined from an integrated perspective of meteorological, socioeconomic, and urban form factors. The results showed that from 2005 to 2020, PM2.5 concentrations in Chinese cities followed a 'rise-then-fall' trend, while O3 exhibited a 'rise-fall- rise' trend. Both the spatial distribution and the synergistic relationship between PM2.5 and O3 displayed pronounced regional heterogeneity. High PM2.5 concentrations were mainly concentrated in the North China Plain, whereas high O3 concentrations occurred in both the North China Plain and the eastern coastal urban agglomerations. Positive correlations between PM2.5 and O3 concentrations were predominant in the humid regions of southern and northeastern China, while negative correlations were more common in the semi-humid and semi-arid regions of northern China. Geodetector analysis revealed that the spatial differentiation drivers of PM2.5 and O3 concentrations was primarily shaped by urban form factors, followed by meteorological and socioeconomic conditions. Specifically, PM2.5 concentrations were strongly influenced by the proportion of ecological space (q=0.627) and agricultural land (q=0.610), whereas O3 concentrations were significantly affected by the proportion of ecological space (q=0.512) and topography (q = 0.466). The synergistic relationship between PM2.5 and O3 was mainly controlled by the single factors such as precipitation (q=0.396) and temperature (q=0.374), with significant enhancement observed under dual-factor interactions, such as temperature-topography (q=0.718) and precipitation-Shannon's evenness index (q=0.708). These findings highlight the nonlinear synergistic effects arising from the coupling of 'urban form constraints' and 'meteorological disturbances' on PM2.5-O3 compound pollution, and provide a scientific basis for the precise and coordinated prevention and control of such pollution.

air pollution  /  remote sensing  /  contribution  /  geodetector
邹滨, 谢曼曼, 李莎, 刘宁, 李沈鑫, 熊鹰. 中国274个地级市PM2.5-O3浓度空间分异的驱动因素解析. 中国环境科学, 2025 , 45 (11) : 6032 -6044 .
Bin ZOU, Man-man XIE, Sha LI, Ning LIU, Shen-xin LI, Ying XIONG. Exploring the drivers of PM2.5-O3 spatial differentiation in 274 Chinese prefecture-level cities[J]. China Environmental Science, 2025 , 45 (11) : 6032 -6044 .
Year 2025 volume 45 Issue 11
90
13
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  • Receive Date:2025-04-11
  • Online Date:2026-10-08
  • Published:2025-11-20
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  • Received:2025-04-11
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Affiliations
    1.School of Geosciences and Info-physics, Central South University, Changsha 410083, China
    2.School of Hydraulic and Ocean Engineering, Changsha University of Science & Technology, Changsha 410114, China
    3.College of Meteorology and Oceanography, National University of Defense Technology, Changsha 410073, China
    4.College of Architecture, Changsha University of Science & Technology, Changsha 410114, China
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表12种不同金属材料的力学参数
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Family
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Number of
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Number of
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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