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Research progress on selective leaching of lithium from spent lithium iron phosphate batteries
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Ya-nan LI, Jia-jun AN, Lei WANG*, Xu-dong WANG
China Environmental Science | 2025, 45(10) : 5570 - 5584
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China Environmental Science | 2025, 45(10): 5570-5584
• Solid Waste •
Research progress on selective leaching of lithium from spent lithium iron phosphate batteries
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Ya-nan LI, Jia-jun AN, Lei WANG*, Xu-dong WANG
Affiliations
  • Shaanxi Key Laboratory of Environmental Engineering, Key Laboratory of Membrane Separation of Shaanxi Province, Research Institute of Membrane Separation Technology of Shaanxi Province, School of Environmental &Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
Published: 2025-10-20
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With the rapid development of the renewable energy industry, the usage of lithium iron phosphate batteries has soared. Therefore, the recycling of spent batteries has become a social focus. The selective leaching method can effectively extract lithium, reduce impurities, and improve recycling efficiency. This paper systematically reviews various selective lithium leaching techniques, including chemical oxidation, acid-assisted leaching, electrochemistry, high-temperature roasting, mechanochemistry, and so on, which further compares their respective advantages and disadvantages from the aspects of technical economy and environmental benefits. The results indicate that the chemical oxidation method has advantages in cost control and operational flexibility, while the electrochemical method is more and environmentally friendly and green. For the selective recycling of spent lithium iron phosphate batteries, more efficient, environmentally friendly, and economical recycling solutions should be developed in the future. This will provide new ideas for exploring selective recycling strategies for lithium iron phosphate batteries, which can promote comprehensive and coordinated development of the economy, environment, and technology, and thereby build a virtuous cycle system of new quality productivity.

spent lithium iron phosphate  /  selective leaching  /  chemical oxidation method  /  auxiliary acid leaching method  /  electrochemical method
李亚楠, 安家君, 王磊, 王旭东. 废旧磷酸铁锂电池中锂的选择性浸出研究进展. 中国环境科学, 2025 , 45 (10) : 5570 -5584 .
Ya-nan LI, Jia-jun AN, Lei WANG, Xu-dong WANG. Research progress on selective leaching of lithium from spent lithium iron phosphate batteries[J]. China Environmental Science, 2025 , 45 (10) : 5570 -5584 .
Year 2025 volume 45 Issue 10
82
19
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  • Receive Date:2025-02-27
  • Online Date:2026-10-08
  • Published:2025-10-20
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  • Received:2025-02-27
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    Shaanxi Key Laboratory of Environmental Engineering, Key Laboratory of Membrane Separation of Shaanxi Province, Research Institute of Membrane Separation Technology of Shaanxi Province, School of Environmental &Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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