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Research progress of SCR denitrification catalysts for copper-based LDHs derivatives
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Wei ZHANG1, 2, *, Kai-kai ZHANG1, 2, Quan-bin SONG1, 2, Yan-shan YIN1, 2, Shan CHENG1, 2, Yan-ni XUAN1, 2, Min RUAN1, 2, Tao LIU1, 2, Zhao-yi ZHOU1, 2, Zhi-hao YAO1, 2, Dan-cong LI1, 2
China Environmental Science | 2025, 45(10) : 5435 - 5447
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China Environmental Science | 2025, 45(10): 5435-5447
• Air Pollution Control •
Research progress of SCR denitrification catalysts for copper-based LDHs derivatives
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Wei ZHANG1, 2, *, Kai-kai ZHANG1, 2, Quan-bin SONG1, 2, Yan-shan YIN1, 2, Shan CHENG1, 2, Yan-ni XUAN1, 2, Min RUAN1, 2, Tao LIU1, 2, Zhao-yi ZHOU1, 2, Zhi-hao YAO1, 2, Dan-cong LI1, 2
Affiliations
  • 1.School of Energy and Power Engineering, Changsha University of Science and Technology, Changsha 410114, China
  • 2.Renewable Energy Power Technology Key Laboratory of Hunan Province, Changsha 410114, China
Published: 2025-10-20
Outline
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Copper-based layered double hydroxides (Cu-LDHs) are layered compounds composed of positively charged lamels and interlayer negative anions. With their excellent ion exchange properties, adjustable interlayer structure, unique memory effect, excellent catalytic activity and good thermal stability, they show great application potential in the field of denitrification. In this paper, the application progress of Cu-LDHs derivative catalysts in denitrification technology was reviewed. The types of SCR catalysts for Cu-LDHs derivatives were systematically classified from the perspectives of metal doping, carrier loading and anion regulation. The reaction mechanism of NH3, CO and C3H6 as reducing agents in SCR system of Cu-LDHs derivatives was investigated. In addition, the strengthening strategy of the Cu-LDHs derivative catalyst in the aspects of sulfur resistance, hydrothermal aging resistance and alkali metal poisoning resistance was described in detail, aiming to enhance the stability and durability of the catalyst by comprehensive means. Finally, the future research direction of Cu-LDHs derivatives is prospectively prospected.

layered double hydroxides (LDHs)  /  selective catalytic reduction (SCR)  /  copper based  /  reaction mechanism  /  sulfur resistance
张巍, 张凯凯, 宋权斌, 尹艳山, 成珊, 宣艳妮, 阮敏, 刘涛, 周昭仪, 姚志豪, 李丹聪. 铜基LDHs衍生物SCR脱硝催化剂的研究进展. 中国环境科学, 2025 , 45 (10) : 5435 -5447 .
Wei ZHANG, Kai-kai ZHANG, Quan-bin SONG, Yan-shan YIN, Shan CHENG, Yan-ni XUAN, Min RUAN, Tao LIU, Zhao-yi ZHOU, Zhi-hao YAO, Dan-cong LI. Research progress of SCR denitrification catalysts for copper-based LDHs derivatives[J]. China Environmental Science, 2025 , 45 (10) : 5435 -5447 .
Year 2025 volume 45 Issue 10
67
21
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  • Receive Date:2025-03-04
  • Online Date:2026-10-08
  • Published:2025-10-20
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  • Received:2025-03-04
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Affiliations
    1.School of Energy and Power Engineering, Changsha University of Science and Technology, Changsha 410114, China
    2.Renewable Energy Power Technology Key Laboratory of Hunan Province, Changsha 410114, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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