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Study on the adsorption performance and mechanism of Fe/MnOx loaded attapulgite-hydrochar composite material for Cd in water
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Jun-wei GE1, Hui-dong LIU1, 3, Meng-yu WANG2, Zhi-cheng SHEN1, Sheng-cheng YU1, Liang-fei DONG1, *
China Environmental Science | 2025, 45(9) : 4923 - 4934
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China Environmental Science | 2025, 45(9): 4923-4934
• Water Pollution Control •
Study on the adsorption performance and mechanism of Fe/MnOx loaded attapulgite-hydrochar composite material for Cd in water
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Jun-wei GE1, Hui-dong LIU1, 3, Meng-yu WANG2, Zhi-cheng SHEN1, Sheng-cheng YU1, Liang-fei DONG1, *
Affiliations
  • 1.School of Urban Construction, Changzhou University, Changzhou 213164, China
  • 2.School of Environmental Science and Engineering, Changzhou University, Changzhou 213164, China
  • 3.Jiangsu Yihuan Grp Co Ltd, Wuxi 214206, China
Published: 2025-09-20
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To efficiently remove Cd (II) from water, this study prepared a novel adsorbent by compositing hydrochloric acid-activated attapulgite with hydrochar and in-situ loading iron-manganese bimetallic oxides. The material was characterized by SEM-EDS, XPS, XRD, FTIR, and BET, revealing the synergistic chemisorption of Cd (II) by iron-manganese oxides and functional groups such as hydroxyl and carboxyl groups. The optimally proportioned adsorbent exhibited a maximum Cd (II) adsorption capacity of 66.8mg/g. The adsorption process followed pseudo-second-order kinetics and the Langmuir model, indicating predominantly monolayer chemisorption. After five adsorption-desorption cycles, the material retained approximately 75% of its initial adsorption capacity, demonstrating excellent regeneration performance. These experimental results provide a reliable technical basis for low-cost, highly efficient, and reusable remediation of heavy metals in water bodies.

attapulgite  /  hydrochar  /  Cd (II)  /  adsorption mechanism
葛俊伟, 刘会东, 汪梦宇, 沈志澄, 余升城, 董良飞. 铁锰氧化物负载凹土-水热炭复合材料对水中Cd的吸附性能及机制研究. 中国环境科学, 2025 , 45 (9) : 4923 -4934 .
Jun-wei GE, Hui-dong LIU, Meng-yu WANG, Zhi-cheng SHEN, Sheng-cheng YU, Liang-fei DONG. Study on the adsorption performance and mechanism of Fe/MnOx loaded attapulgite-hydrochar composite material for Cd in water[J]. China Environmental Science, 2025 , 45 (9) : 4923 -4934 .
Year 2025 volume 45 Issue 9
63
17
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  • Receive Date:2025-02-13
  • Online Date:2026-10-08
  • Published:2025-09-20
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  • Received:2025-02-13
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Affiliations
    1.School of Urban Construction, Changzhou University, Changzhou 213164, China
    2.School of Environmental Science and Engineering, Changzhou University, Changzhou 213164, China
    3.Jiangsu Yihuan Grp Co Ltd, Wuxi 214206, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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