As a common pollutant in water, nitrate has nonnegligible harmful effects on human health and the ecological environment. Faced with an increasingly severe energy crisis, the development of green, clean and sustainable nitrate removal technologies to replace the conventional resource-intensive denitrification process is urgently needed. Photoelectrochemical nitrate reduction powered by sunlight has become a research hotspot at home and abroad. Based on the way photogenerated electrons being transferred from semiconductor to nitrate, this technology can be categorized into photocatalytic reduction, photoelectrocatalytic reduction, and microbial photoelectrotrophic reduction. In this review, the mechanisms of three photoelectrochemical nitrate reduction technologies were discussed. With a focus on improving system performance, the selection and design strategies of photocatalysts, photoelectrodes and microbial photosensitizers were also summarized. Moreover, the technical difficulties of photoelectrochemical nitrate reduction are clarified and the future directions of research are proposed, such as regulating the pathway of microbial absorption and utilization of photogenerated electrons through genetic engineering and other methods. The insights provided will serve as a reference for the development of new nitrate removal and reutilization technologies.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |