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Catalytic ozonation of 2,3-dimethylpyrazine using CN-doped Mn3O4
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Yi CHEN1, Yin-ning HE1, Da WANG1, *, Shuang SONG1, Jun MA2
China Environmental Science | 2025, 45(3) : 1251 - 1259
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China Environmental Science | 2025, 45(3): 1251-1259
Water Pollution Control
Catalytic ozonation of 2,3-dimethylpyrazine using CN-doped Mn3O4
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Yi CHEN1, Yin-ning HE1, Da WANG1, *, Shuang SONG1, Jun MA2
Affiliations
  • 1.Key Laboratory of Microbial Technology for Industrial Pollution Control of Zhejiang Province, College of Environment, Zhejiang University of Technology, Hangzhou 310032, China
  • 2.State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150006, China
Published: 2025-03-20
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A CN-supported Mn3O4(Mn3O4-CN)composite was synthesized as a catalyst for the catalytic ozonation of 2,3-dimethylpyrazine degradation in wastewater. The catalytic efficiencies of 2, 3-dimethylpyrazine were investigated under various ozone dosages, catalyst dosages, pH and temperature conditions. The results showed that under the conditions of an ozone dosage of 3mg/L, a catalyst dosage of 0.02g/L, pH =7 and a temperature of 10℃, the degradation rate of pollutants reached 100% within 20 min. Scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction and other characterization methods were used to analyze the properties of the prepared Mn3O4-CN. It was confirmed that Mn3O4 and CN were successfully bonded, and the valence states of Mn were mostly +2 and +3. The reactive oxygen species analysis demonstrated that the surface hydroxyl groups and oxygen vacancies were identified as the main active sites, and ⋅OH was the main active oxygen species generated in the reaction system. The cyclic experiments showed that the Mn3O4-CN has good stability and reusability.

catalytic ozonation  /  pyrazines  /  water treatment  /  manganese oxide
Yi CHEN, Yin-ning HE, Da WANG, Shuang SONG, Jun MA. Catalytic ozonation of 2,3-dimethylpyrazine using CN-doped Mn3O4[J]. China Environmental Science, 2025 , 45 (3) : 1251 -1259 .
Year 2025 volume 45 Issue 3
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  • Receive Date:2024-08-09
  • Online Date:2026-03-18
  • Published:2025-03-20
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  • Received:2024-08-09
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Affiliations
    1.Key Laboratory of Microbial Technology for Industrial Pollution Control of Zhejiang Province, College of Environment, Zhejiang University of Technology, Hangzhou 310032, China
    2.State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150006, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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