A composite photocatalyst of bismuth oxybromide with oxygen vacancies covered by biochar (BC/OV-BiOBr, BOVB)was developed by hydrothermal method. Its photocatalytic performance was investigated with tetracycline (TC) as the target pollutant, and the catalytic effect was verified by dye pollutants. The results showed that 99.8% of tetracycline (TC) and 100% Rhodamine B(RhB) could be decomposed within 60min or 40min under visible light, of which degradation rates were 8.92 times and 9.82 times that of pure BiOBr, respectively. The degradation process of pollutants had strong resistance to pH change and low concentration co-existing ions. The results of phase characterization and photoelectrochemical performance test showed that the morphology was changed from flake to flower and the concentration of oxygen vacancies was increased after adding biochar, which were beneficial to improve the photoresponse and accelerate the charge transfer. Due to the synergistic effect between biochar and oxygen vacancies in driving the free radical chain reaction, the concentration of superoxide free radical (·O2-) in the system was increased, which was further transformed it into hydroxyl free radical (·OH), providing abundant strong oxidizing active species for pollutant degradation. In addition, good cyclic stability was certified by 5consecutive degradation experiments.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |