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Advances in persulfate activated by carbon-based materials for degradation of antibiotics
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Yan-fei GUO1, 2, Zhuang GUO2, Hui-feng WANG3, Jian WEI2, *, Dong-yao XU1
China Environmental Science | 2025, 45(2) : 704 - 717
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China Environmental Science | 2025, 45(2): 704-717
Water Pollution Control
Advances in persulfate activated by carbon-based materials for degradation of antibiotics
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Yan-fei GUO1, 2, Zhuang GUO2, Hui-feng WANG3, Jian WEI2, *, Dong-yao XU1
Affiliations
  • 1.College of Chemical and Environmental Engineering, China University of Mining and Technology-Beijing, Beijing 100083, China
  • 2.Institute of Water Eco-environment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
  • 3.Environmental Technology & Engineering Co.Ltd, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Published: 2025-02-20
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The persulfate-based advanced oxidation technology for antibiotic-containing wastewater treatment has become a current research hotspot in water treatment. Carbon-based materials have been used as green materials for activating persulfate due to their chemical stability and absence of secondary pollution. However, the catalytic activity of undoped or modified carbon materials is limited. This paper reviews strategies to enhance the catalytic performance of carbon materials, including non-metallic doping, metal doping, and carbon-based composites, and summarizes the new active sites formed by these strategies, as well as the connection between the types of active species produced by activated persulfate. In conjunction with the existing studies on the degradation of antibiotics by activated persulfate in carbon-based materials, the mechanisms of activation of persulfate by carbon-based materials (including free radicals, single-linear oxygen, electron transfer, and high-valent metal-oxygen species), and the methods to identify and determine the active species are concluded. Finally, the susceptible oxidation sites of tetracyclines, sulfonamides, and fluoroquinolones antibiotics, their linkages with active species, as well as the application of this technology in treating antibiotic-containing waters. These results can provide a reference for the development of carbon-based catalysts with high catalytic performance and stability, and their application to activated persulfate systems for efficient antibiotic degradation.

carbon-based materials  /  persulfate  /  mechanism of degradation  /  antibiotics  /  progress
Yan-fei GUO, Zhuang GUO, Hui-feng WANG, Jian WEI, Dong-yao XU. Advances in persulfate activated by carbon-based materials for degradation of antibiotics[J]. China Environmental Science, 2025 , 45 (2) : 704 -717 .
Year 2025 volume 45 Issue 2
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  • Receive Date:2024-07-16
  • Online Date:2026-03-17
  • Published:2025-02-20
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  • Received:2024-07-16
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Affiliations
    1.College of Chemical and Environmental Engineering, China University of Mining and Technology-Beijing, Beijing 100083, China
    2.Institute of Water Eco-environment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
    3.Environmental Technology & Engineering Co.Ltd, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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