Through several chromatographic methods, such as silica gel, Sephadex LH-20, medium-pressure liquid chromatography (MPLC), combined with modern spectroscopic techniques including nuclear magnetic resonance (1D and 2D NMR) and high resolution mass spectrometry (HRMS), two iridoids and six oleanane-type triterpenoids were isolated and identified from the roots and rhizomes of Patrinia scabiosaefolia. Among them, compound 1 was a new 3, 8-epoxy iridoid and named as patrinin C (1). Compounds 2-8 were isolated from this plant for the first time, and their structures were identified as alboside II (2), 11α, 12α-epoxy-3β, 23-dihydroxyolean-28, 13β-olide (3), 23-hydroxy-3-oxo-28-nor-12, 16-dien oleanane (4), 3′-O-acetyl-3-O-α-L-arabinosyl-23-hydroxyolean-12-en-28-oic acid (5), 2′, 3′-O-diacetyl-3-O-α-L-arabinopyranosyl-23-hydroxyolea-12-en-28-oic acid (6), hederagenin 3-O-(2-O-acetyl-β-D-xylopyranosyl)-(1→3)-α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranoside (7) and pictoside A (8), respectively.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |