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Quantitative acid addition nonlinear fitting method for rapid determination of neutral degreaser concentration
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Shao-Wen LI*, Yan-Bo ZHANG, Yi-Fan LIU
Laboratory Testing | 2024, 2(5) : 26 - 30
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Laboratory Testing | 2024, 2(5): 26-30
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Quantitative acid addition nonlinear fitting method for rapid determination of neutral degreaser concentration
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Shao-Wen LI*, Yan-Bo ZHANG, Yi-Fan LIU
Affiliations
  • Chinalco Luoyang Copper Co., Ltd. Luoyang 471039 China
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Objective To establish a rapid method for the determination of neutral degreaser concentration by quantitative acid addition and nonlinear fitting, and to solve the problem of titration method and weighing method lack of accuracy and detection efficiency. Methods Prepare the working curve solutions of different concentrations by using the degreaser original solution, and measure the $\mathrm{{pH}}$ value after adding a quantitative amount of acid.The relationship function between the $\mathrm{{pH}}$ value and the concentration of degreaser is obtained by non-linear fitting, and then the concentration in the production sites degreasing solution is calculated by the function.Explore the amount of acid added, curve fitting method, and fitting order, and determine the optimal experimental conditions. Results The method was applied to the rapid determination of neutral degreaser concentration, with a relative standard deviation (RSD) of 0.85% to 1.17% and a recovery rate between 98.52% to 103.34%. Conclusion The new method proposed in this study is accurate, reliable, simple and rapid.And overcomes the shortcomings of traditional titration and gravimetric methods, it can effectively guide the application of neutral degreaser and improve the surface quality of metal materials.

degreaser  /  neutral  /  concentration  /  nonlinear fitting  /  rapid determination
Shao-Wen LI, Yan-Bo ZHANG, Yi-Fan LIU. Quantitative acid addition nonlinear fitting method for rapid determination of neutral degreaser concentration[J]. Laboratory Testing, 2024 , 2 (5) : 26 -30 .
Year 2024 volume 2 Issue 5
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  • Online Date:2025-07-29
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Affiliations
    Chinalco Luoyang Copper Co., Ltd. Luoyang 471039 China

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*LI Shao-Wen, Engineer, Director of Chemical Analysis Laboratory, Chinalco Luoyang Copper Co., Ltd., Luoyang 471039, China. E-mail:
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
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Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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