Article(id=1321170197579419987, tenantId=1146029695717560320, journalId=1260987677001138203, issueId=1321170163563614210, articleNumber=null, orderNo=null, doi=10.13386/j.issn1002-0306.2024100152, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1729094400000, receivedDateStr=2024-10-17, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1792921121258, onlineDateStr=2026-10-25, pubDate=1769875200000, pubDateStr=2026-02-01, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792921121258, onlineIssueDateStr=2026-10-25, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792921121258, creator=13701087609, updateTime=1792921121258, updator=13701087609, issue=Issue{id=1321170163563614210, tenantId=1146029695717560320, journalId=1260987677001138203, year='2026', volume='47', issue='3', pageStart='1', pageEnd='497', issueExtLink='null', onlineDate='null', pubDate='1769875200000', pubDateStr='2026-02-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792921113148, creator='13701087609', updateTime=1792921113148, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=22, endPage=31, ext={EN=ArticleExt(id=1321170197776552276, articleId=1321170197579419987, tenantId=1146029695717560320, journalId=1260987677001138203, language=EN, title=Exploring the Potential Mechanism of Anti-aging Effects of Spray-dried Mulberry Leaf Phenolics Based on UPLC-Q-Exactive-MS/MS and Network Pharmacology, columnId=1261336277291548795, journalTitle=Science and Technology of Food Industry, columnName=Research and Investigation, runingTitle=null, highlight=null, articleAbstract=
Objective: Ultra-high performance liquid chromatography-quadrupole-electrostatic orbitrap mass spectrometry (UPLC-Q-Exactive-MS/MS) and network pharmacology methods were used to study the metabolic absorption and potential biological activity of spray-dried mulberry leaves. Methods: UPLC-Q-Exactive-MS/MS was used to detect the phenolic components of spray-dried mulberry leaves in simulated in vitro digestion, intestinal microbial fermentation and in vivo metabolic processes. Based on the detected phenolic components, the corresponding material targets were found through the database analysis platform Swiss Target and Pharmmapper, and the aging targets were obtained by searching the HAGR and Genecards databases. The PPI (Protein-Protein Interaction) network was constructed using String11.5 database and Cytoscape 3.9.1 software. DAVID 6.8 was used for gene ontology (GO) annotation and KEGG (Kyoto Encyclopedia of Genes and Genomes Analysis) pathway enrichment analysis to analyze core targets and action pathways, and then the "components-targets-pathway" network was constructed. Results: The phenolic compounds of spray-dried mulberry leaves mainly underwent hydrolysis or deglycosidation during the gastrointestinal digestion stage. After being absorbed, these substances mainly underwent phase Ⅰ and Ⅱ reactions such as reduction, hydroxylation, glucuronidation and sulfation in the body. The prototype compounds and metabolites of phenolic compounds in spray-dried mulberry leaves co-existed in the blood circulation. Through the network pharmacology method, 476 intersection targets of phenolic substances and aging were screened out. After constructing PPI, 47 core targets were screened out. The top ten targets were GAPDH (glyceraldehyde-3-phosphate dehydrogenase ), ALB (albumin), AKT1 (protein kinase B1), INS (insulin), ACTβ (β-actin), TP53 (tumor protein p53), TNF (tumor necrosis factor), IL6 (interleukin 6), EGFR (epidermal growth factor receptor), IL1β (interleukin 1β). KEGG results showed that phenolic compounds of spray-dried mulberry leaves might play an anti-aging role by regulating Wnt and TGF-β signaling pathways. Conclusion: The phenolic compounds of spray-dried mulberry leaves may play an anti-aging role through multi-component, multi-target and multi-pathway.
, authors=Chaoli TAN
1, Xu ZHANG
2, Yuqing XIE
2, Jingjing SHENG
2, Yao PAN
2, Yanfang YU
3, Fang CHEN
2, *, authorsList=Chaoli TAN, Xu ZHANG, Yuqing XIE, Jingjing SHENG, Yao PAN, Yanfang YU, Fang CHEN, authorCompany=null, correspAuthors=Fang CHEN, authorNote=null, correspAuthorsNote=null, copyrightStatement=Copyright © 2026 Science and Technology of Food Industry. All rights reserved., copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1321170202725831009, articleId=1321170197579419987, tenantId=1146029695717560320, journalId=1260987677001138203, language=CN, title=基于UPLC-Q-Exactive-MS/MS及网络药理学探讨喷雾干燥桑叶酚类物质抗衰老潜在作用机制, columnId=1261336277849391232, journalTitle=食品工业科技, columnName=研究与探讨, runingTitle=null, highlight=null, articleAbstract=
目的：通过超高效液相色谱-四极杆-静电轨道阱质谱法（UPLC-Q-Exactive-MS/MS）及网络药理学方法研究喷雾干燥桑叶酚类物质的消化代谢情况以及潜在的抗衰老作用机制。方法：使用UPLC-Q-Exactive-MS/MS 分别检测喷雾干燥桑叶在模拟体外消化、肠道微生物发酵和体内代谢过程中的酚类物质成分。基于检测到的酚类物质成分，通过数据库分析平台Swiss Target和Pharmmapper查找相应的物质靶点，查找HAGR和Genecards数据库得到衰老靶点，二者取交集。采用String11.5 数据库和Cytoscape 3.9.1软件构建 PPI（Protein-Protein Interaction）网络。利用 DAVID 6.8 进行基因本体（Gene Ontology，GO）注释和 KEGG（Kyoto Encyclopedia of Genes and Genomes Analysis）核心作用通路分析，进而构建“活性成分-靶点-通路”网络。结果：喷雾干燥桑叶酚类物质在胃肠道消化阶段主要发生水解或脱去糖苷等反应。这些物质被吸收后在体内主要发生还原、羟基化、葡糖醛酸化和硫酸化等Ⅰ、Ⅱ相反应。喷雾干燥桑叶酚类物质的原型化合物和代谢产物共同存在于血液循环中。将检测到的16种化合物作为喷雾干燥桑叶发挥抗衰老作用的潜在活性成分。通过网络药理学方法筛选出476个酚类物质与衰老的交集靶点，构建PPI后筛选出47个核心靶点。排名前十的靶点有GAPDH（甘油醛-3-磷酸脱氢酶）、ALB（白蛋白）、AKT1（蛋白激酶B1）、INS（胰岛素）、ACTβ（β-肌动蛋白）、TP53（肿瘤蛋白p53）、TNF（肿瘤坏死因子）、IL6（白细胞介素6）、EGFR（表皮生长因子受体）、IL1β（白细胞介素1β）。KEGG通路富集结果表明，喷雾干燥桑叶酚类物质可能通过调控Wnt信号通路、TGF-β信号通路等发挥抗衰老作用。结论：喷雾干燥桑叶酚类物质可能通过多成分、多靶点、多通路发挥抗衰老的功能。
, authors=檀朝立
1, 章旭
2, 谢雨晴
2, 盛晶晶
2, 潘瑶
2, 俞燕芳
3, 陈芳
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1江西阳光乳业股份有限公司，江西南昌 330001, bio={"content":"
檀朝立（1990−），男，硕士研究生，研究方向：营养与食品卫生学，E-mail：1024894495@qq.com
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檀朝立（1990−），男，硕士研究生，研究方向：营养与食品卫生学，E-mail：1024894495@qq.com
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1江西阳光乳业股份有限公司，江西南昌 330001)]), AuthorCompany(id=1321170203107512677, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, xref=2, ext=[AuthorCompanyExt(id=1321170203115901286, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, companyId=1321170203107512677, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
2School of Public Health, Nanchang University, Nanchang 330000, China), AuthorCompanyExt(id=1321170203124289895, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, companyId=1321170203107512677, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
2南昌大学公共卫生学院，江西南昌 330000)]), AuthorCompany(id=1321170203199787368, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, xref=3, ext=[AuthorCompanyExt(id=1321170203203981673, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, companyId=1321170203199787368, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
3Economic Crops Research Institute of Jiangxi Province, Nanchang 330202, China), AuthorCompanyExt(id=1321170203212370282, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, companyId=1321170203199787368, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
3江西省经济作物研究所，江西南昌 330202)])], figs=[ArticleFig(id=1321170207519920536, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=EN, label=Fig.1, caption=
Simulation of the change pathway of phenolic compounds in spray drying mulberry leaves during in vitro digestion, figureFileSmall=kR2KIyhp6Mi9XKUD8FNhUQ==, figureFileBig=g6yfASIQvP4ChzeDqpaoUA==, tableContent=null), ArticleFig(id=1321170207603806617, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=CN, label=图1, caption=
模拟体外消化过程中喷雾干燥桑叶酚类物质的变化途径, figureFileSmall=kR2KIyhp6Mi9XKUD8FNhUQ==, figureFileBig=g6yfASIQvP4ChzeDqpaoUA==, tableContent=null), ArticleFig(id=1321170207796744602, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=EN, label=Fig.2, caption=
MS/MS spectra and fragmentation patterns of several phenolic compound metabolites in spray-dried mulberry leaves and the metabolic pathways of the main phenolic compounds in spray-dried mulberry leaves in mice, figureFileSmall=3DNbLQsHiKMR1yOMxuVpaQ==, figureFileBig=AuoDTciNyt43FTNGIFCaFA==, tableContent=null), ArticleFig(id=1321170209478660507, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=CN, label=图2, caption=
喷雾干燥桑叶中几种酚类化合物代谢物的MS/MS谱图及裂解模式及喷雾干燥桑叶中主要酚类化合物在小鼠体内的代谢途径注：A：咖啡酸硫酸结合物MS/MS质谱图以及裂解碎片信息；B：奎尼酸MS/MS质谱图以及裂解碎片信息；C：二氢咖啡酸MS/MS质谱图以及裂解碎片信息；D：喷雾干燥桑叶主要酚类物质在小鼠体内的代谢途径。
, figureFileSmall=3DNbLQsHiKMR1yOMxuVpaQ==, figureFileBig=AuoDTciNyt43FTNGIFCaFA==, tableContent=null), ArticleFig(id=1321170209554157980, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=EN, label=Fig.3, caption=
Venn diagram of compound targets and aginge targets, figureFileSmall=EaTBlWJVAWOEqXCuYOYxfA==, figureFileBig=rC5RuVF70yfgRZueuCWJUw==, tableContent=null), ArticleFig(id=1321170209638044061, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=CN, label=图3, caption=
物质靶点与衰老靶点韦恩图, figureFileSmall=EaTBlWJVAWOEqXCuYOYxfA==, figureFileBig=rC5RuVF70yfgRZueuCWJUw==, tableContent=null), ArticleFig(id=1321170209709347230, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=EN, label=Fig.4, caption=
PPI network of the intersection targets of active components in spray-dried mulberry leaf powder and aging targets, figureFileSmall=I66sqQZC7d2yNceZhzmDAQ==, figureFileBig=Nf6SZ4duC2WSLN/YuKVzgA==, tableContent=null), ArticleFig(id=1321170209789039007, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=CN, label=图4, caption=
喷雾干燥桑叶粉中活性成分物质与衰老靶点交集靶点的PPI网络注：节点的圆形面积越大，颜色越深，表明其degree值越高，其在网络中重要性越高。
, figureFileSmall=I66sqQZC7d2yNceZhzmDAQ==, figureFileBig=Nf6SZ4duC2WSLN/YuKVzgA==, tableContent=null), ArticleFig(id=1321170209906479520, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=EN, label=Fig.5, caption=
Enrichment analysis of core targets, figureFileSmall=TJL+sg2xTiF37wGmoWNLaQ==, figureFileBig=JqhnCTWtghd5eGw/98eAcw==, tableContent=null), ArticleFig(id=1321170209977782689, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=CN, label=图5, caption=
核心靶点的富集分析注：A：GO富集分析结果；B：KEGG富集分析结果。
, figureFileSmall=TJL+sg2xTiF37wGmoWNLaQ==, figureFileBig=JqhnCTWtghd5eGw/98eAcw==, tableContent=null), ArticleFig(id=1321170210065863074, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=EN, label=Fig.6, caption=
Diagram of effective component-target-pathway network, figureFileSmall=b69cSlcyU26d1mEA6cn3XQ==, figureFileBig=TtwMhGRvf/kCV4IfNrcduw==, tableContent=null), ArticleFig(id=1321170210141360547, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=CN, label=图6, caption=
活性成分-靶点-通路网络示意图注：椭圆形代表喷雾干燥桑叶中的活性成分，菱形代表核心靶点，长方形代表信号通路。
, figureFileSmall=b69cSlcyU26d1mEA6cn3XQ==, figureFileBig=TtwMhGRvf/kCV4IfNrcduw==, tableContent=null), ArticleFig(id=1321170210191692196, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=EN, label=Table 1, caption=
Preparation of digestion working solution
, figureFileSmall=null, figureFileBig=null, tableContent=
| 成分 | 模拟口腔
消化液（mL） | 模拟胃
消化液（mL） | 模拟小肠
消化液（mL） |
|---|
| 氯化钾（0.5 mol/L） | 15 | 6.9 | 6.8 |
| 磷酸二氢钾（0.5 mol/L） | 3.7 | 0.9 | 0.8 |
| 碳酸氢钠（1 mol/L） | 6.8 | 12.5 | 42.5 |
| 氯化钠（2 mol/L） | − | 11.8 | 9.6 |
| 氯化镁（0.15 mol/L） | 0.5 | 0.4 | 1.1 |
| 碳酸铵（0.5 mol/L） | 0.06 | 0.5 | − |
), ArticleFig(id=1321170210258801061, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=CN, label=表1, caption=
消化工作液的配制
, figureFileSmall=null, figureFileBig=null, tableContent=
| 成分 | 模拟口腔
消化液（mL） | 模拟胃
消化液（mL） | 模拟小肠
消化液（mL） |
|---|
| 氯化钾（0.5 mol/L） | 15 | 6.9 | 6.8 |
| 磷酸二氢钾（0.5 mol/L） | 3.7 | 0.9 | 0.8 |
| 碳酸氢钠（1 mol/L） | 6.8 | 12.5 | 42.5 |
| 氯化钠（2 mol/L） | − | 11.8 | 9.6 |
| 氯化镁（0.15 mol/L） | 0.5 | 0.4 | 1.1 |
| 碳酸铵（0.5 mol/L） | 0.06 | 0.5 | − |
), ArticleFig(id=1321170210334298534, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=EN, label=Table 2, caption=
Identification of the major phenolic compounds in spray-dried mulberry leaves during the simulated gastrointestinal digestion and colonic fermentation
, figureFileSmall=null, figureFileBig=null, tableContent=
| 物质 | 保留时间
（min） | 质荷比
（m/z） | 质量偏差
（ppm） | 二级碎片 | 化合物 | 来源 |
|---|
| E | G | I | F0 | F1 | F3 | F6 | F12 | F24 |
|---|
| 1 | 0.863 | 191.0566 | 0.604 | 191.0563/111.0090/87.0090/85.0298 | 奎尼酸 | + | + | + | + | + | + | + | + | + |
| 2 | 1.932 | 353.0892 | 7.056 | 191.0558/135.0455/85.0294 | 3-咖啡酰奎宁酸 | + | + | + | + | + | − | − | − | − |
| 3 | 2.03 | 179.051 | 6.785 | 135.0442/134.0372/136.9236 | 咖啡酸 | + | + | + | + | + | + | + | + | + |
| 4 | 2.741 | 353.089 | 6.49 | 191.0574 | 5-咖啡酰奎宁酸 | + | + | + | + | + | − | − | − | − |
| 5 | 4.669 | 609.1465 | 0.363 | 447.0924/285.0401/283.0269 | 山奈酚-3,7-O糖苷 | + | + | + | + | − | − | − | − | − |
| 6 | 4.721 | 711.1411 | 4.340 | 667.1517/462.0804 | 槲皮素-丙二酰二己糖苷 | + | − | − | − | − | − | − | − | − |
| 7 | 6.935 | 625.1417 | 0.368 | 463.0866/300.0281 | 槲皮素3-槐糖苷 | + | + | + | + | − | − | − | − | − |
| 8 | 9.952 | 609.1479 | 0.365 | 300.0281 | 芦丁 | + | + | + | + | + | − | − | − | − |
| 9 | 10.671 | 463.0901 | 6.473 | 300.0283 | 异槲皮素 | + | + | + | + | + | − | − | − | − |
| 10 | 11.723 | 505.0993 | 3.233 | 300.0279/301.033 | 槲皮素3-O-（6-乙酰葡萄糖苷） | + | + | + | + | + | − | − | − | − |
| 11 | 11.793 | 549.0898 | 4.196 | 505.1000/300.0283 | 槲皮素3-O-丙二糖苷 | + | + | + | + | − | − | − | − | − |
| 12 | 11.88 | 593.1526 | 4.221 | 285.0405 | 山奈酚3-葡萄糖基-鼠李糖苷 | + | + | + | + | − | − | − | − | − |
| 13 | 12.355 | 447.0945 | 5.172 | 284.0331/285.0391/255.0302 | 紫云英苷 | + | + | + | + | + | − | − | − | − |
| 14 | 12.362 | 515.1189 | 0.966 | 353.0899/191.0557/179.0341 | 二咖啡酰奎宁酸 | + | + | + | + | − | − | − | − | − |
| 15 | 13.073 | 447.0953 | 6.961 | 284.0329/285.0377/151.0042 | 山奈酚7-O-葡萄糖苷 | − | − | + | + | + | − | − | − | − |
| 16 | 13.565 | 489.1053 | 5.209 | 284.0331/285.0391/255.0302 | 山奈酚3-（6-乙酰半乳糖苷） | + | + | + | + | + | − | − | − | − |
| 17 | 13.967 | 533.0934 | 1.535 | 489.1035/285.0406 | 山奈酚-丙二酰-葡萄糖苷 | + | + | + | + | − | − | − | − | − |
| 18 | 3.618 | 181.0508 | 6.985 | 136.9225/135.9150/109.04293/121.0295 | 二氢咖啡酸 | − | − | − | − | − | + | − | − | − |
| 19 | 3.811 | 177.0128 | -30.705 | 135.9156/89.0393/105.0350/136.9221 | 咖啡醌 | − | − | − | + | + | + | + | + | + |
| 20 | 4.741 | 121.0278 | -5.007 | 06.0285/93.0345 | 苯甲酸 | − | − | − | − | − | − | + | + | + |
| 21 | 7.767 | 165.0544 | -1.337 | 119.0501/135.9147/106.0420 | 对羟基苯丙酸 | − | − | − | + | + | + | + | + | + |
| 22 | 16.569 | 301.0364 | 7.045 | 151.0042/121.0300/107.0146 | 槲皮素 | − | − | − | + | + | + | − | − | − |
| 23 | 19.278 | 285.0416 | 7.843 | 93.0348 | 山奈酚 | − | − | − | + | + | − | − | − | − |
), ArticleFig(id=1321170210413990311, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=CN, label=表2, caption=
喷雾干燥桑叶经体外消化、肠道微生物发酵后主要酚类化合物的成分鉴定
, figureFileSmall=null, figureFileBig=null, tableContent=
| 物质 | 保留时间
（min） | 质荷比
（m/z） | 质量偏差
（ppm） | 二级碎片 | 化合物 | 来源 |
|---|
| E | G | I | F0 | F1 | F3 | F6 | F12 | F24 |
|---|
| 1 | 0.863 | 191.0566 | 0.604 | 191.0563/111.0090/87.0090/85.0298 | 奎尼酸 | + | + | + | + | + | + | + | + | + |
| 2 | 1.932 | 353.0892 | 7.056 | 191.0558/135.0455/85.0294 | 3-咖啡酰奎宁酸 | + | + | + | + | + | − | − | − | − |
| 3 | 2.03 | 179.051 | 6.785 | 135.0442/134.0372/136.9236 | 咖啡酸 | + | + | + | + | + | + | + | + | + |
| 4 | 2.741 | 353.089 | 6.49 | 191.0574 | 5-咖啡酰奎宁酸 | + | + | + | + | + | − | − | − | − |
| 5 | 4.669 | 609.1465 | 0.363 | 447.0924/285.0401/283.0269 | 山奈酚-3,7-O糖苷 | + | + | + | + | − | − | − | − | − |
| 6 | 4.721 | 711.1411 | 4.340 | 667.1517/462.0804 | 槲皮素-丙二酰二己糖苷 | + | − | − | − | − | − | − | − | − |
| 7 | 6.935 | 625.1417 | 0.368 | 463.0866/300.0281 | 槲皮素3-槐糖苷 | + | + | + | + | − | − | − | − | − |
| 8 | 9.952 | 609.1479 | 0.365 | 300.0281 | 芦丁 | + | + | + | + | + | − | − | − | − |
| 9 | 10.671 | 463.0901 | 6.473 | 300.0283 | 异槲皮素 | + | + | + | + | + | − | − | − | − |
| 10 | 11.723 | 505.0993 | 3.233 | 300.0279/301.033 | 槲皮素3-O-（6-乙酰葡萄糖苷） | + | + | + | + | + | − | − | − | − |
| 11 | 11.793 | 549.0898 | 4.196 | 505.1000/300.0283 | 槲皮素3-O-丙二糖苷 | + | + | + | + | − | − | − | − | − |
| 12 | 11.88 | 593.1526 | 4.221 | 285.0405 | 山奈酚3-葡萄糖基-鼠李糖苷 | + | + | + | + | − | − | − | − | − |
| 13 | 12.355 | 447.0945 | 5.172 | 284.0331/285.0391/255.0302 | 紫云英苷 | + | + | + | + | + | − | − | − | − |
| 14 | 12.362 | 515.1189 | 0.966 | 353.0899/191.0557/179.0341 | 二咖啡酰奎宁酸 | + | + | + | + | − | − | − | − | − |
| 15 | 13.073 | 447.0953 | 6.961 | 284.0329/285.0377/151.0042 | 山奈酚7-O-葡萄糖苷 | − | − | + | + | + | − | − | − | − |
| 16 | 13.565 | 489.1053 | 5.209 | 284.0331/285.0391/255.0302 | 山奈酚3-（6-乙酰半乳糖苷） | + | + | + | + | + | − | − | − | − |
| 17 | 13.967 | 533.0934 | 1.535 | 489.1035/285.0406 | 山奈酚-丙二酰-葡萄糖苷 | + | + | + | + | − | − | − | − | − |
| 18 | 3.618 | 181.0508 | 6.985 | 136.9225/135.9150/109.04293/121.0295 | 二氢咖啡酸 | − | − | − | − | − | + | − | − | − |
| 19 | 3.811 | 177.0128 | -30.705 | 135.9156/89.0393/105.0350/136.9221 | 咖啡醌 | − | − | − | + | + | + | + | + | + |
| 20 | 4.741 | 121.0278 | -5.007 | 06.0285/93.0345 | 苯甲酸 | − | − | − | − | − | − | + | + | + |
| 21 | 7.767 | 165.0544 | -1.337 | 119.0501/135.9147/106.0420 | 对羟基苯丙酸 | − | − | − | + | + | + | + | + | + |
| 22 | 16.569 | 301.0364 | 7.045 | 151.0042/121.0300/107.0146 | 槲皮素 | − | − | − | + | + | + | − | − | − |
| 23 | 19.278 | 285.0416 | 7.843 | 93.0348 | 山奈酚 | − | − | − | + | + | − | − | − | − |
), ArticleFig(id=1321170210489487784, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=EN, label=Table 3, caption=
Identification of metabolites of major phenolic compounds in spray-dried mulberry leaves after metabolism in mice
, figureFileSmall=null, figureFileBig=null, tableContent=
| 物质 | 保留时间
（min） | 分子式 | 质荷比
（m/z） | 质量偏差
（ppm） | 二级碎片 | 原型物质 | 鉴定反应 | 心 | 肝 | 肾 | 肺 | 血 |
|---|
| 1 | 0.863 | C9H8O4 | 179.1067 | 0.000 | 134.9866/161.0960/107.0850 | 绿原酸 | 咖啡酸（绿原酸分解产物） | − | − | − | − | + |
| 2 | 1.932 | C7H12O6 | 191.0554 | 2.018 | 191.0563/111.0090/127.0381/85.0298 | 绿原酸 | 奎尼酸（原型/绿原酸分解产物） | − | − | − | − | + |
| 3 | 2.03 | C15H12O7 | 303.0583 | 27.621 | 267.0732/135.0299 | 槲皮素糖苷 | 还原 | + | − | − | − | − |
| 4 | 2.741 | C16H16O8 | 336.0845 | 1.580 | 303.0529/243.0314/187.0413 | 槲皮素糖苷 | 还原、水和、甲基化 | − | + | + | − | − |
| 5 | 4.669 | C17H20O9 | 367.1054 | 8.285 | 127.0196/187.0410 | 绿原酸 | 甲基化 | − | + | − | − | − |
| 6 | 4.721 | C17H14O7 | 329.0393 | -7.986 | 301.0349/241.0589 | 槲皮素糖苷 | 双甲基化 | + | + | − | − | + |
| 7 | 6.935 | C9H8O3 | 163.0392 | 1.407 | 119.0490/121.7563 | 绿原酸 | 香豆酸（绿原酸分解产物） | + | + | − | − | − |
| 8 | 9.952 | C9H10O4 | 181.0498 | 1.462 | 163.0391/135.0440/119.04903/134.0361 | 咖啡酸糖苷 | 氢化 | − | − | + | + | + |
| 9 | 10.671 | C9H8O7S | 258.9912 | 1.932 | 179.0339/135.0438/134.0361 | 咖啡酸糖苷 | 咖啡酸硫酸化 | − | − | − | − | + |
| 10 | 11.723 | C7H10O5 | 173.0808 | 0.000 | 111.0802/129.0906/155.0701 | 绿原酸 | 莽草酸（绿原酸分解产物） | − | − | − | − | + |
| 11 | 11.793 | C15H10O9S | 365.0727 | 0.000 | 116.9272/180.8893/285.1159/297.1528 | 山奈酚糖苷 | 山奈酚硫酸化 | − | − | − | − | + |
| 12 | 11.88 | C16H12O9 | 347.1708 | 2.177 | 301.1661 | 槲皮素糖苷 | 甲基化，双羟基化 | − | − | − | − | + |
), ArticleFig(id=1321170210577568169, tenantId=1146029695717560320, journalId=1260987677001138203, articleId=1321170197579419987, language=CN, label=表3, caption=
喷雾干燥桑叶经小鼠体内代谢后主要酚类化合物代谢产物鉴定结果
, figureFileSmall=null, figureFileBig=null, tableContent=
| 物质 | 保留时间
（min） | 分子式 | 质荷比
（m/z） | 质量偏差
（ppm） | 二级碎片 | 原型物质 | 鉴定反应 | 心 | 肝 | 肾 | 肺 | 血 |
|---|
| 1 | 0.863 | C9H8O4 | 179.1067 | 0.000 | 134.9866/161.0960/107.0850 | 绿原酸 | 咖啡酸（绿原酸分解产物） | − | − | − | − | + |
| 2 | 1.932 | C7H12O6 | 191.0554 | 2.018 | 191.0563/111.0090/127.0381/85.0298 | 绿原酸 | 奎尼酸（原型/绿原酸分解产物） | − | − | − | − | + |
| 3 | 2.03 | C15H12O7 | 303.0583 | 27.621 | 267.0732/135.0299 | 槲皮素糖苷 | 还原 | + | − | − | − | − |
| 4 | 2.741 | C16H16O8 | 336.0845 | 1.580 | 303.0529/243.0314/187.0413 | 槲皮素糖苷 | 还原、水和、甲基化 | − | + | + | − | − |
| 5 | 4.669 | C17H20O9 | 367.1054 | 8.285 | 127.0196/187.0410 | 绿原酸 | 甲基化 | − | + | − | − | − |
| 6 | 4.721 | C17H14O7 | 329.0393 | -7.986 | 301.0349/241.0589 | 槲皮素糖苷 | 双甲基化 | + | + | − | − | + |
| 7 | 6.935 | C9H8O3 | 163.0392 | 1.407 | 119.0490/121.7563 | 绿原酸 | 香豆酸（绿原酸分解产物） | + | + | − | − | − |
| 8 | 9.952 | C9H10O4 | 181.0498 | 1.462 | 163.0391/135.0440/119.04903/134.0361 | 咖啡酸糖苷 | 氢化 | − | − | + | + | + |
| 9 | 10.671 | C9H8O7S | 258.9912 | 1.932 | 179.0339/135.0438/134.0361 | 咖啡酸糖苷 | 咖啡酸硫酸化 | − | − | − | − | + |
| 10 | 11.723 | C7H10O5 | 173.0808 | 0.000 | 111.0802/129.0906/155.0701 | 绿原酸 | 莽草酸（绿原酸分解产物） | − | − | − | − | + |
| 11 | 11.793 | C15H10O9S | 365.0727 | 0.000 | 116.9272/180.8893/285.1159/297.1528 | 山奈酚糖苷 | 山奈酚硫酸化 | − | − | − | − | + |
| 12 | 11.88 | C16H12O9 | 347.1708 | 2.177 | 301.1661 | 槲皮素糖苷 | 甲基化，双羟基化 | − | − | − | − | + |
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