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Recovery and Purification of Zinc and Cadmium from Dust of Side Blowing-fuming Process for Treating Jarosites
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Jiahua ZHANG1, Yaru CUI1, Guohua WANG1, Zhengmin WANG2, Haiping GUI2, Deng LI1, Anxin LI1
Hydrometallurgy of China | 2024, 43(2) : 121 - 128
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Hydrometallurgy of China | 2024, 43(2): 121-128
Experiment Research
Recovery and Purification of Zinc and Cadmium from Dust of Side Blowing-fuming Process for Treating Jarosites
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Jiahua ZHANG1, Yaru CUI1, Guohua WANG1, Zhengmin WANG2, Haiping GUI2, Deng LI1, Anxin LI1
Affiliations
  • 1 School of Metallurgical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
  • 2 Hanzhong Zinc Industry Co., Ltd., Hanzhong 724204, China
Published: 2024-04-20 doi: 10.13355/j.cnki.sfyj.2024.02.002
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Zinc and cadmium were recovered by acid leaching—vulcanization impurity removal method from dust of slide blowing—fuming process for treating jarosites, and copper was selectively removed from the leaching solution by sulfide precipitation. Subsequently, the obtained purified solution will be used to prepare Cd-doped ZnS composites. Based on the thermodynamic analysis, the influencing factors and kinetics of zinc leaching rate in sulfuric acid system were investigated, and the influence of various parameters on sulfidation was elucidated through orthogonal tests. The results show that the zinc in dust mainly exists in the form of zinc oxide, the leaching reaction follows a mixed control model with a 73.70 kJ/mol activation energy. Zinc leaching rate can reach 98. 99% under the optimum conditions. The copper removal rate can reach 95.97% under 3.2 theoretical times of Na2S addition at pH of 2.0, with high retaining rate of Zn and Cd, achieving effectively selective separation of copper from zinc and cadmium.

dust  /  sulfuric acid  /  leaching  /  copper  /  zinc  /  cadmium  /  selective separation
Jiahua ZHANG, Yaru CUI, Guohua WANG, Zhengmin WANG, Haiping GUI, Deng LI, Anxin LI. Recovery and Purification of Zinc and Cadmium from Dust of Side Blowing-fuming Process for Treating Jarosites[J]. Hydrometallurgy of China, 2024 , 43 (2) : 121 -128 . DOI: 10.13355/j.cnki.sfyj.2024.02.002
Year 2024 volume 43 Issue 2
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doi: 10.13355/j.cnki.sfyj.2024.02.002
  • Receive Date:2023-11-27
  • Online Date:2025-09-10
  • Published:2024-04-20
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  • Received:2023-11-27
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    1 School of Metallurgical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
    2 Hanzhong Zinc Industry Co., Ltd., Hanzhong 724204, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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