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Leaching and Kinetic of Lithium Element from Waste Coal Fly Ash
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Sha WANG, Wei QIN, Xue HAN, Junwei WANG
Hydrometallurgy of China | 2024, 43(6) : 646 - 651
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Hydrometallurgy of China | 2024, 43(6): 646-651
Experiment Research
Leaching and Kinetic of Lithium Element from Waste Coal Fly Ash
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Sha WANG, Wei QIN, Xue HAN, Junwei WANG
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  • Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, China
Published: 2024-12-20 doi: 10.13355/j.cnki.sfyj.2024.06.008
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The extraction of lithium from fly ash by roasting activation with sodium carbonate and leaching with sulfuric acid was studied. The effects of mass ratio of fly ash to sodium carbonate, roasting temperature, roasting time, liquid-solid mass ratio, sulfuric acid concentration, acid leaching temperature and acid leaching time on the leaching rate of lithium were investigated. The dynamic analysis of the leaching process was carried out by using the core-shrinkage model. The results show that under the condition of 800 ℃, fly ash and sodium carbonate are mixed and roasted for 180 min according to the mass ratio of 1∶1, and then leaching with 2 mol/L sulfuric acid at 90 ℃ for 120 min, remarkable leaching effect can be obtained, and the leaching rate of lithium can reach 99.97%, the leaching process is mainly controlled by diffusion. The study has a certain guiding significance for the leaching and recovery of lithium from solid waste resources.

fly ash  /  lithium  /  extraction  /  roasting  /  activation  /  sulfuric acid  /  leaching  /  dynamics
Sha WANG, Wei QIN, Xue HAN, Junwei WANG. Leaching and Kinetic of Lithium Element from Waste Coal Fly Ash[J]. Hydrometallurgy of China, 2024 , 43 (6) : 646 -651 . DOI: 10.13355/j.cnki.sfyj.2024.06.008
Year 2024 volume 43 Issue 6
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doi: 10.13355/j.cnki.sfyj.2024.06.008
  • Receive Date:2024-04-22
  • Online Date:2025-09-10
  • Published:2024-12-20
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  • Received:2024-04-22
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    Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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