Latest ArticlesRobust signal transfer in the form of electromagnetic waves is of fundamental importance in modern technology, yet its operation is often challenged by unwanted modifications of the channel connecting transmitter and receiver. Parity-time- (PT-) symmetric systems, combining active and passive elements in a balanced form, provide an interesting route in this context. Here, we demonstrate a PT-symmetric microwave system operating in the extreme case in which the channel is shorted through a small reactance, which acts as a nearly impenetrable obstacle, and it is therefore expected to induce large reflections and poor transmission. After placing a gain element behind the obstacle, and a balanced lossy element in front of it, we observe full restoration of information and overall transparency to an external observer, despite the presence of the obstacle. Our theory, simulations, and experiments unambiguously demonstrate stable and robust wave tunneling and information transfer supported by PT symmetry, opening opportunities for efficient communication through channels with dynamic changes, active filtering, and active metamaterial technology.
Two-dimensional (2-D) materials of atomic thickness have attracted considerable interest due to their excellent electrical, optoelectronic, mechanical, and thermal properties, which make them attractive for electronic devices, sensors, and energy systems. Scavenging the otherwise wasted energy from the ambient environment into electrical power holds promise to address the emerging energy needs, in particular for the portable and wearable devices. The versatile properties of 2-D materials together with their atomically thin body create diverse possibilities for the conversion of ambient energy. The present review focuses on the recent key advances in emerging energy-harvesting devices based on monolayer 2-D materials through various mechanisms such as photovoltaic, thermoelectric, piezoelectric, triboelectric, and hydrovoltaic devices, as well as progress for harvesting the osmotic pressure and Wi-Fi wireless energy. The representative achievements regarding the monolayer heterostructures and hybrid devices are also discussed. Finally, we provide a discussion of the challenges and opportunities for 2-D monolayer material-based energy-harvesting devices in the development of self-powered electronics and wearable technologies.
Highly conductive and stable electrode materials are usually the focus of high-performance supercapacitors. In this work, a unique design of Ni2P@carbon self-supported composite nanowires directly grown on Ni foam was applied for a supercapacitor. The Co3O4 nanowire array was first synthesized on the Ni foam substrate, and the resulting Ni2P@carbon nanocomposite was obtained by hydrothermally coating Co3O4 with the Ni-ethylene glycol complex followed by gaseous phosphorization. We have discovered that the molecular weight of surfactant polyvinylpyrrolidone (PVP) used in the hydrothermal step, as well as the temperature for phosphorization, played very important roles in determining the electrochemical properties of the samples. Specifically, the sample synthesized using PVP with 10 k molecular weight and phosphorized at 300°C demonstrated the best supercapacitive performance among the different samples, with the highest capacitance and most stable cyclic retention. When an asymmetric supercapacitor (ASC) was assembled with this Ni2P@carbon sample as the cathode and activated carbon (AC) as the anode, the ASC device showed excellent capacitances of 3.7 and 1.6 F cm-2 at 2 and 50 mA cm-2, respectively, and it kept a high capacitance of 1.2 F cm-2 after 5000 cycles at a current rate of 25 mA cm-2. In addition, the ASC could reach a high energy density of about 122.8 Wh kg-1 at a power density of 0.15 kW kg-1 and 53.3 Wh kg-1 at the highest power density of 3.78 kW kg-1. Additionally, this device also had the ability to power up 16 red LEDs effortlessly, making it a strong candidate in electrochemical energy storage for practical usage.
Fast actuation with nanoprecision over a large range has been a challenge in advanced intelligent manufacturing like lithography mask aligner. Traditional stacked stage method works effectively only in a local, limited range, and vibration coupling is also challenging. Here, we design a dual mechanism multimodal linear actuator (DMMLA) consisted of piezoelectric and electromagnetic costator and coslider for producing macro-, micro-, and nanomotion, respectively. A DMMLA prototype is fabricated, and each working mode is validated separately, confirming its fast motion (0~50 mm/s) in macromotion mode, micromotion (0~135 μm/s) and nanomotion (minimum step: 0~2 nm) in piezoelectric step and servomotion modes. The proposed dual mechanism design and multimodal motion method pave the way for next generation high-precision actuator development.
The clay mineral assemblages and geochemical compositions of the Permian Talchir and Barakar mudstones of the Raniganj basin, India, have been used to interpret terrestrial paleoclimate. The Talchir Formation presents unequivocal evidences of the Permian global glacial climate, and the overlying Barakar Formation with braided fluvial deposits immediately follows the glacial amelioration stage to a humid warm climate. Sediments unaffected by burial diagenesis and originated from a similar source under contrasting climates are ideal for developing proxies for substantial climate shift. Illite (28.4-63.8%), illite/smectite (0-58.6%, 40-80% illite), chlorite (0-53.9%), and chlorite/smectite (5.6-29.8%) constitute the clay mineral assemblage in the Talchir Formation whereas illite (5.3-78.2%), illite/smectite (trace-34.1%, mostly 60-90% illite), and kaolinite (36.1-86.8%) dominate the clay mineral assemblage in the Barakar Formation. The Talchir mudrocks are enriched in mobile elements and depleted in alumina w.r.t. PAAS, have relatively higher K2O/Al2O3 ratios (~0.3), high ICV (1.12-1.28), and lower CIA values (52.6-65.1) compared to those of the younger Barakar mudstones. The Barakar mudstones are depleted in mobile elements w.r.t. PAAS, have relatively low ICV (0.33-0.62) and K2O/Al2O3 values (0.11-0.16), and higher CIA values (72.9-88.2). Textural, mineralogical immaturity, and rock fragments of different components of the basement seen in the Talchir sandstones show these sediments being a first-cycle sedimentary deposit. The distinctive clay mineral assemblage and major oxide composition of the Talchir mudrocks attest to a unique low intensity chemical weathering in cold arid climate. Significant presence of kaolinite as well as distinctive geochemical characters of the Barakar mudrocks marks a shift in the paleoclimate from cold arid to humid. This climatic shift is further supported by the proportion and composition of illite/smectite across the formations. The relative proportion of chlorite and kaolinite and composition of illite/smectite therefore closely corroborate the significant climate shift, and such proxies, therefore, are useful indicators of climate extremes in the geological record.
Piezoelectric materials are important for many physical and electronic devices. Although many piezoelectric ceramics exhibit good piezoelectricity, they often show poor compatibility with biological systems that limits their biomedical applications. Piezoelectric peptide and metabolite materials benefit from their intrinsic biocompatibility, degradability, and convenient biofunctionalization and are promising candidates for biological and medical applications. Herein, we provide an account of the recent progress of research works on piezoelectric peptide and metabolite materials. This review focuses on the growth mechanism of peptide and metabolite micro- and nanomaterials. The influence of self-assembly processes on their piezoelectricity is discussed. Peptide and metabolite materials demonstrate not only outstanding piezoelectric properties but also unique electronic, optical, and physical properties, enabling their applications in nanogenerators, sensors, and optical waveguiding devices.
Directional manipulation of underwater bubbles on a solid surface has attracted much attention due to its large-scale applications such as electrocatalytic gas evolution reactions, wastewater remediation, and solar energy harvesting. In this work, the patterned slippery surface (PSS) is fabricated via a facile method where the patterned pathways are fabricated by means of etching the pristine copper sheet. These patterned surfaces consisted of pristine copper and modified oxide copper which exhibit different wettability for bubble and water. The superhydrophobic and aerophilic surface can efficiently capture bubbles, and the infused oil layer is beneficial for reducing the resistance during transportation. Furthermore, the bubble can move upward, downward, and horizontally. Hence, it is easy to realize the bubble’s transportation and collection on the functional surfaces.
Thermoelectric materials, which directly convert heat into electricity based on the Seebeck effects, have long been investigated for use in semiconductor refrigeration or waste heat recovery. Among them, SnSe has attracted significant attention due to its promising performance in both p-type and n-type crystals; in particular, a higher out-of-plane ZT value could be achieved in n-type SnSe due to its 3D charge and 2D phonon transports. In this work, the thermoelectric transport properties of n-type polycrystalline SnSe were investigated with an emphasis on the out-of-plane transport through producing textural microstructure. The textures were fabricated using mechanical alloying and repeated spark plasma sintering (SPS), as a kind of hot pressing, aimed at producing strong anisotropic transports in n-type polycrystalline SnSe as that in crystalline SnSe. Results show that the lowest thermal conductivity of 0.36 Wm-1 K-1 was obtained at 783 K in perpendicular to texture direction. Interestingly, the electrical transport properties are less anisotropic and even nearly isotropic, and the power factors reach 681.3 μWm-1 K-2 at 783 K along both parallel and perpendicular directions. The combination of large isotropic power factor and low anisotropic thermal conductivity leads to a maximum ZT of 1.5 at 783 K. The high performance elucidates the outstanding electrical and thermal transport behaviors in n-type polycrystalline SnSe, and a higher thermoelectric performance can be expected with future optimizing texture in n-type polycrystalline SnSe.
The synthesis of perovskite oxynitrides, which are promising photoanode candidates for solar energy conversion, is normally accomplished by high-temperature ammonolysis of oxides and carbonate precursors, thus making the deposition of their planar films onto conductive substrates challenging. Here, we proposed a facile strategy to prepare a series of perovskite oxynitride films. Taking SrTaO2N as a prototype, we prepared SrTaO2N films on Ta foils under NH3 flow by utilizing the vaporized SrCl2/SrCO3 eutectic salt. The SrTaO2N films exhibit solar water-splitting photocurrents of 3.0 mA cm-2 at 1.23 V vs. RHE (reversible hydrogen electrode), which increases by 270% compared to the highest photocurrent (1.1 mA cm-2 at 1.23 V vs. RHE) of SrTaO2N reported in the literature. This strategy may also be applied to directly prepare a series of perovskite oxynitride films on conductive substrates such as ATaO2N () and ANbO2N ().
Electromagnetic waves carrying an orbital angular momentum (OAM) are of great interest. However, most OAM antennas present disadvantages such as a complicated structure, low efficiency, and large divergence angle, which prevents their practical applications. So far, there are few papers and research focuses on the problem of the divergence angle. Herein, a metasurface antenna is proposed to obtain the OAM beams with a small divergence angle. The circular arrangement and phase gradient were used to simplify the structure of the metasurface and obtain the small divergence angle, respectively. The proposed metasurface antenna presents a high transmission coefficient and effectively decreases the divergence angle of the OAM beam. All the theoretical analyses and derivation calculations were validated by both simulations and experiments. This compact structure paves the way to generate OAM beams with a small divergence angle.