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Effects of Different Stabilizers on the Properties of Natural Rubber Latex Films
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Liguang ZHAO1, 2, 3, Jianwei LI1, 3, Yazhong SONG1, 2, Li DING1, 3, Tuo DAI1, 3, Honghai HUANG1, 3, Yuekun WANG1, 2, Tao ZHAO1, 4, Hongxing GUI1, 2, *
Chinese Journal of Tropical Crops | 2023, 44(6) : 1237 - 1245
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Chinese Journal of Tropical Crops | 2023, 44(6): 1237-1245
Post-harvest Treatment & Quality Safety
Effects of Different Stabilizers on the Properties of Natural Rubber Latex Films
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Liguang ZHAO1, 2, 3, Jianwei LI1, 3, Yazhong SONG1, 2, Li DING1, 3, Tuo DAI1, 3, Honghai HUANG1, 3, Yuekun WANG1, 2, Tao ZHAO1, 4, Hongxing GUI1, 2, *
Affiliations
  • 1.Rubber Research Institute, Chinese Academy of Tropical Agricultural Sciences, Haikou, Hainan 571101, China
  • 2.Hainan Provincial Natural Rubber Cultivation and Processing Engineering Research Center, Haikou, Hainan 571101, China
  • 3.Hainan Provincial Key Laboratory of High-Performance Natural Rubber Materials Engineering, Haikou, Hainan 571101, China
  • 4.Qingdao University of Science and Technology, Qingdao, Shandong 266061, China
Published: 2023-06-25 doi: 10.3969/j.issn.1000-2561.2023.06.017
Outline
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In this study, four stabilizers including potassium hydroxide (KOH), ammonia, sodium dodecyl sulfate (SDS) and potassium laurate were added to concentrated natural rubber latex (CNRL). The performance of the CNRL film was most affected by the amount of KOH. With the increase of KOH content, the Mooney viscosity of the film increased and the shrinkage rate decreased. The tensile strength, tensile stress, elongation at break, tear strength and hardness all decreased rapidly. With the increase dosage of potassium laurate, the Mooney viscosity and the shrinkage rate of the raw rubber film decreased to a certain extent. The tensile strength had a tendency to increase first and then decrease. With the increase of ammonia consumption, there was also a trend of first rising and then falling. More dosage of sodium dodecyl sulfate (SDS) would lead to lower tear strength of the raw rubber film. The performance of the vulcanizate film was also most affected by the amount of KOH. With the increase of KOH dosage, the ML and MH of the vulcanizate film would increase. The t10, t50 and t90 would be shortened, and the film shrinkage was reduced. In addition, the tensile strength and elongation at break of the rubber film decreased. The tensile stress and tear strength had a trend of increasing first and then decreasing. As the amount of ammonia increased, the t90 of the vulcanizate film would increase. The shrinkage rate of the film increasesd, and the tensile stress first increased and then decreased. With the increase of the amount of SDS, the t90 of the vulcanizate film would be prolonged and the film shrinkage was reduced. With the increase of potassium laurate dosage, the ML and MH of the vulcanizate film would increase, the film shrinkage was reduced, and the tear strength showed a trend of increasing first and then decreasing. It could be seen from the hardness change that the film would become soft after adding KOH and the hardness would be greatly reduced. The Mooney viscosity of the film was greatly improved. After the addition of potassium laurate, the Mooney viscosity of the film decreased significantly, but the hardness of the film did not change much. From the perspective of vulcanization, after adding KOH, the vulcanization degree of the rubber film increased, and the vulcanization time decreased. KOH had a certain promotion and promotion effect on the vulcanization degree of the film. However, combined with the mechanical properties of the vulcanized film. The tensile stress of the film increased after adding KOH, but the tensile strength, tear strength and elongation were significantly reduced. However, the film strength changed little when the other three stabilizers were added.

natural rubber latex  /  stabilizer  /  vulcanization characteristics  /  film properties  /  mechanical properties
Liguang ZHAO, Jianwei LI, Yazhong SONG, Li DING, Tuo DAI, Honghai HUANG, Yuekun WANG, Tao ZHAO, Hongxing GUI. Effects of Different Stabilizers on the Properties of Natural Rubber Latex Films[J]. Chinese Journal of Tropical Crops, 2023 , 44 (6) : 1237 -1245 . DOI: 10.3969/j.issn.1000-2561.2023.06.017
Year 2023 volume 44 Issue 6
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Article Info
doi: 10.3969/j.issn.1000-2561.2023.06.017
  • Receive Date:2022-07-01
  • Online Date:2026-03-05
  • Published:2023-06-25
Article Data
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History
  • Received:2022-07-01
  • Revised:2022-10-17
Funding
Affiliations
    1.Rubber Research Institute, Chinese Academy of Tropical Agricultural Sciences, Haikou, Hainan 571101, China
    2.Hainan Provincial Natural Rubber Cultivation and Processing Engineering Research Center, Haikou, Hainan 571101, China
    3.Hainan Provincial Key Laboratory of High-Performance Natural Rubber Materials Engineering, Haikou, Hainan 571101, China
    4.Qingdao University of Science and Technology, Qingdao, Shandong 266061, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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