A foreign copper sulfide concentrate from slag processing was treated by adopting heated sulfuric acid leaching with trivalent iron compound as an oxidant for recovering copper therein. The effects of oxidant dosage, leaching temperature, leaching time, initial concentration of sulfuric acid and liquid-solid ratio on the leaching rate of copper from copper sulfide concentrate were investigated. The results show that with the proper condition, including the oxidant of hematite at an amount of 0.2 g/g ore, leaching temperature of 85 ℃, leaching time of 6 h, liquid-solid ratio at 5∶1, and sulfuric acid with initial concentration of 200 g/L, the copper leaching rate can reach 97.96%. A verification test with different oxidants shows that hematite and magnetite present good oxidability in acid leaching system, leading to the copper in those copper sulfide concentrate leached out at a medium temperature. Also, the higher the purity of trivalent iron compounds, the better the oxidative leaching effect of copper.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |