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  • Gang WEN, Chu LI, Lin CHENG, Chuanbao XUN, Tongyun WANG, Guozhi ZHANG, Yiyang E
    Insulating Materials. 2023, 56(4): 77-84.

    Inter-turn short circuit is the main fault type of dry-type air-core reactors. At present, there is a lack of effective offline detection method to discover potential faults in time before dry-type reactors put into operation. Based on the theory of multiconductor transmission line, a distributed parameter model of dry-type air-core reactor winding was built to simulate the refraction and reflection processes after pulse signal injection, and the influence law of inter-turn short circuit on the response signal at the head and end of winding was discussed. On this basis, a characteristic waveform was constructed by the integral value of response signal absolute value, and a characteristic value was extracted to diagnose the inter-turn insulation state of winding. The results show that the test results of four-eigenvalue method proposed in this paper based on the wave process and multiconductor transmission line theory are consistent with the simulation results. Through the simulation calculation of different structural reactor models, it is found that the eigenvalue change trend of different structural reactor is also consistent when the inter-turn short circuit fault occurs. Therefore, the above method can be applied to diagnoze the inter-turn short circuit fault of reactors with different structures. The research results can provide guidance for the diagnosis of the severity and regional localization of inter-turn short circuit in dry-type air-core reactor.

  • Pengfei YANG, Yucai LIU, Jinxin ZHANG, Yufei CHEN, Xianqi FENG
    Insulating Materials. 2023, 56(4): 12-16.

    An epoxy resin-based sheet molding plastic (E-SMC) was prepared by using multi-function epoxy resin as the resin matrix, dicyandiamide as main curing agent, and mica as fillers. Then the epoxy molding composite was prepared by molding process, and its mechanical properties, thermodynamic properties, and electrical properties were systematically tested and studied. The results show that the epoxy molding composites have high mechanical strength, and the tensile strength, bending strength, vertical compression strength and parallel compression strength of typical samples can reach 64, 178, 440, and 332 MPa, respectively. At the same time, the epoxy molding composites have low density (1.69-1.76 g/cm3), high glass transition temperature (Tg up to 201℃), and excellent electrical strength properties, and the breakdown voltage of typical samples is up to 100 kV, the electric strength can reach 17.1 kV/mm, the comparative tracking index (CTI) is 600 V.

  • Hao YIN, Yunyun ZHAO, Xiuyun ZHANG, Huarui XU, Guisheng ZHU, Le WAN, Kun XU, Mingnan SHANGGUAN
    Insulating Materials. 2023, 56(4): 28-33.

    In order to improve the upper limit temperature and high temperature stability of BaTiO3 for MLCC insulating dielectric material, a Ba1-xCaxTiO3 nano-powder was prepared by using BaCl2·H2O, CaCl2, and H2TiO3 as raw materials and KOH as mineralizer under the condition of 210℃/22 h hydrothermal reaction. The phase structure, microstructure, and dielectric properties of the samples were characterized and analyzed by XRD, SEM, LCR detection methods. The results show that the obtained powders are uniformly dispersed and the particle size is (110±20) nm. The doping of Ca2+ increases the Curie temperature of BaTiO3, and a Ba0.91Ca0.09TiO3 ceramics with 136.2℃of Curie temperature, 1 882 of dielectric constant, and 0.02 of dielectric loss factor are obtained at 1 250℃/2 h. The preparation of MLCC insulating dielectric materials with small particle size, narrow distribution, low agglomeration, and high performance is realized.

  • Xin ZHANG
    Insulating Materials. 2023, 56(4): 7-11.

    In this paper, the performance and characteristics of low smoke halogen-free flame retardant cable material was reviewed. The advantage and disadvantage of ethylene-vinyl acetate copolymer (EVA) as the base material was introduced.The types and flame retardant mechanism of halogen-free flame retardant were reviewed. Finally, the development direction of low smoke halogen-free flame retardant cable material was prospected.

  • Yuanxiang ZHOU, Huijuan WANG, Xin HUANG, Xingjin ZHANG, Lei XUE
    Insulating Materials. 2023, 56(3): 1-8.

    In order to study the effect of organic and inorganic fillers on the performance of insulating paper, nano titanium dioxide (TiO2) treated with dopamine hydrochloride was coated with nano-fibrillated cellulose to get a multiple mixed filler (PDA-TiO2@NFC). Then the multiple mixed filler was filled into the cellulose insulating paper, and a sandwich structure insulating paper modified by different multiple mixed fillers was prepared. The optimal concentration of multiple mixed fillers was explored, and the tensile strength, DC volume resistivity, breakdown characteristics, and space charge of the modified insulating paper with different multiple mixed fillers were analyzed. The results show that when the multiple mixed fillers concentration is 0.5%, compared with the unmodified insulating paper, the tensile strength of the modified insulating paper increases by 17.90%, the AC and DC breakdown strentgh of oil-paper increase by more than 17%, and the injection of space charge can be effectively inhibited. The effect of multiple mixed fillers on the DC volume conductivity is not obvious. The mechanical properties and electric strength improvement of the sandwich structure insulating paper prepared using this method are significant, which provides reference for jointly improving the performance of insulating paper.

  • Haolin CHENG, Jianlin ZHOU, Rongjin ZENG
    Insulating Materials. 2023, 56(3): 9-13.

    The problem of nanoparticle agglomeration in wire enamel can be solved by modification and gradual dispersion of nanoparticles. Five modifiers, emulsifier OP-10, silane coupling agent AP1231, silane coupling agent A112, γ-propyl trimethoxysilane (KH560), and N-[3-(trimethoxysilyl) propyl] ethylenediamine (KH-792), were used to modify the surface of nano silica particles. The effects of modifier type, modifier dosage, modification temperature and time on the modification effect of nano-SiO2 particles were explored. The effects of nano-SiO2 particles before and after modification on the performance of corona resistant wire enamel were compared by corona resistance test, and the dispersion of nano-SiO2 particles before and after modification was observed by transmission electron microscopy (TEM). The results indicate that the nanoparticles modified by KH-560 have the best dispersion in wire enamel, and the best process conditions are as follows: the dosage of KH-560 is 1.5wt%, the modification temperature is 90℃, and the modification time is 4 h. The wire enamel with high stability and higher than 50 h of corona resistance time can be obtained by gradually dispersing modified nanoparticles into the wire enamel, and the appropriate addition amount of nanoparticles is 13.5wt%.

  • Guoxing WU, Chengwei ZHANG, Xiao CHEN, Shu XU, Lei JIA, Shuai HOU, Yunpeng ZHAN, Wenbo ZHU
    Insulating Materials. 2023, 56(3): 26-32.

    HVDC cross-linked polyethylene (XLPE) cables will be damaged by operation impulse voltage caused by switching and other operations in the power system under working condition, which will affect the insulation. However, at present, there is a lack of relevant research on the cable insulation deterioration generated by space charge accumulation caused by multiple impulse cumulative effect. Based on the PEA space charge measurement system under DC superimposed impulse voltage in the laboratory, the space charge characteristics of XLPE cable insulation under DC voltage, impulse voltage, and DC superimposed impulse voltage were measured in this paper. The results show that XLPE is dominated by heteropolar charges under positive DC voltage, and negative charges of the same polarity appear on the SC electrode under negative DC voltage. Continuous high-amplitude impulse voltage can cause large number of homopolar charges injection on the two electrodes, and the amount of injected charge is larger under negative impluse voltage. Under DC superimposed impulse voltage, the same polarity superimposition method can promote the injection of homopolar charge on the two electrodes more than the opposite polarity superimposition method. Moreover, the longer the impulse voltage is applied, the more charge accumulates in the XLPE sample.

  • Zehua PAN, Zhigang REN, Ping CHEN, Zhiyuan SUN, Zhimin YAN, Jian GAO, Jianying LI
    Insulating Materials. 2023, 56(3): 77-83.

    Effect of swelling effect of silicone rubber (SiR) caused by silicone grease coated on the interface between high voltage cable accessories and cable body on the electrical tree characteristics of SiR under monopolar impulse voltage (250/2 500 μs) was studied. The isothermal surface potential decay (ISPD) and equilibrium solvent swelling were carried out to characterize the influence of swelling effect on the trap characteristics and crosslinking structures of SiR. The results show that with the increase of swelling time, both the initiation probability and fractal dimension of electrical tree in SiR increase. After 340 h of swelling, the tree initiation voltage of 50% probability under positive and negative impulse voltage decrease from about 37 kV and about -41 kV to 32 kV and about -39 kV, respectively. In addition, the polarity effect can be observed in the electrical tree process of SiR under impulse voltage. The initiation and growth of electrical tree is easier under positive impulse voltage than negative impulse voltage. With the increase of swelling time, the shallow trap density increases, and the deep trap and physical crosslinking density decrease. The destruction of physical crosslinking structure leads to the expansion of free volume, which intensifies the collision ionization processes. Meanwhile, the decrease of deep trap density enhances the charge transport processes. Multiple physical processes intensify the fracture of molecular chains, which furtherly weakens the resistance to electrical tree of SiR. The polarity effect of electrical tree in SiR under impulse voltage is mainly caused by the different distribution of hole-type and electron-type traps.

  • Huanmin YAO, Haibao MU, Daning ZHANG, Kui MA, Yao LIU
    Insulating Materials. 2023, 56(3): 54-60.

    The equivalent extended Debye model of oil-paper insulation in the damp state no longer has linear characteristics, which makes the evaluation method of oil-paper insulation based on time-frequency conversion have errors. In this paper, the advantages of time domain and frequency domain dielectric spectroscopy were integrated, and the grey correlation algorithm was used to construct the evaluation model of oil-paper insulation damp condition on the basis of the time and frequency domain dielectric response parameters. Firstly, oil-paper insulation samples with different moisture content were prepared, and the influence of moisture and temperature on the polarization and depolarization current (PDC) and frequency domain spectroscopy (FDS) curves was analyzed. Furthermore, the characteristic parameters of PDC and FDS curves under different damp conditions were extracted. On this basis, the grey correlation algorithm was used to integrate the time and frequency domain dielectric characteristic parameters of oil-paper insulation to obtain its standardized reference vector. Finally, the accuracy of evaluation model was verified by laboratory sample data and field transformer data, which provides a new method for warning and diagnosis of transformer early fault.

  • Lihua ZHAO, Zhijie CHEN, Jianguo AN, Junwen REN
    Insulating Materials. 2023, 56(3): 19-25.

    A new type of insulating paper with aramid nanofiber as the basic structural unit was prepared, and its ageing characteristics in natural ester insulating oil and mineral insulating oil were systematically investigated and compared with the commercial Nomex T410 insulating paper. The results show that the aramid nanofiber-based insulating paper has better thermal stability and ageing resistance, and the mechanical and electrical properties of the aramid nanofiber-based insulating paper are better than those of Nomex T410 insulating paper after accelerated thermal ageing test under the same condition. In addition, the new oil-paper insulation system composed by natural ester insulating oil and aramid nanofiber-based insulating paper can effectively extend the life of the transformer, which provides a reference for the insulation design and development of green low-carbon electrical energy equipment.