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Liquid-Liquid Phase Transition of Water at High Pressure and Ambient Temperature
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Hui-Yuan WANG, Hai-Fei ZHENG
Chinese Journal of High Pressure Physics | 2013, 27(4) : 490 - 494
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Chinese Journal of High Pressure Physics | 2013, 27(4): 490-494
Liquid-Liquid Phase Transition of Water at High Pressure and Ambient Temperature
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Hui-Yuan WANG, Hai-Fei ZHENG
Affiliations
  • Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education, School of Earth and Space Science, Peking University, Beijng 100871, China
Published: 2013-08-15
Outline
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In-situ Raman measurement of water has been conducted at the temperature of 300 K and the pressure of 0.1-1 400 MPa using a SiC anvil cell. The experimental results show that the frequency of liquid water ν1 decreases with increase of pressure (p), and two discontinuities are observed at about 200 and 620 MPa. Therefore three states of water are recognized. From state Ⅰ to state Ⅱ then to state III, the value of |dν1/dp| reduces, indicating that the compressibility is related to the pressure, and it is becoming more difficult to compress as the pressure is increasing. The connection mode of a water molecule with its neighboring water molecules changes as the pressure increases. The discontinuous property of water suggests a possible liquid to liquid phase transition and structural change at 200 and 620 MPa.

high pressure  /  discontinuity  /  Raman spectra  /  mode of connection  /  liquid-liquid phase transition
王慧媛, 郑海飞. 常温高压下水的液-液相变. 高压物理学报, 2013 , 27 (4) : 490 -494 .
Hui-Yuan WANG, Hai-Fei ZHENG. Liquid-Liquid Phase Transition of Water at High Pressure and Ambient Temperature[J]. Chinese Journal of High Pressure Physics, 2013 , 27 (4) : 490 -494 .
Year 2013 volume 27 Issue 4
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Article Info
  • Receive Date:2012-02-05
  • Online Date:2026-11-05
  • Published:2013-08-15
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  • Received:2012-02-05
  • Revised:2012-03-05
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    Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education, School of Earth and Space Science, Peking University, Beijng 100871, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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