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Synthesis of Graphite-Encapsulated Copper Nanoparticles Using the Sol-Gel Explosive Precursors
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Ning LUO1, 2, 3, Xiao-Jie LI4, Kai-Xin LIU2, Shi-Yu WU2, Shi-Yang CHEN2, Wen-Jie SONG2
Chinese Journal of High Pressure Physics | 2013, 27(6) : 847 - 855
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Chinese Journal of High Pressure Physics | 2013, 27(6): 847-855
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Synthesis of Graphite-Encapsulated Copper Nanoparticles Using the Sol-Gel Explosive Precursors
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Ning LUO1, 2, 3, Xiao-Jie LI4, Kai-Xin LIU2, Shi-Yu WU2, Shi-Yang CHEN2, Wen-Jie SONG2
Affiliations
  • 1.School of Mechanics And Civil Engineering, CUMT, Xuzhou 221116, China
  • 2.Department of Mechanics & Aerospace Engineering, College of Engineering, Peking University, Beijing 10087, China
  • 3.State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
  • 4.State Key Laboratory of Structural Analysis for Industrial Equipment, Department of Engineering Mechanics, Dalian University of Technology, Dalian 116023, China

    • LUO Ning (1980—), male, postdoctoral research fellow, associate professor, major in explosion mechanics and its effects. E-mail: ;

About Author:

LUO Ning (1980—), male, postdoctoral research fellow, associate professor, major in explosion mechanics and its effects. E-mail: ;

Published: 2013-12-15
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Graphite-encapsulated copper nanoparticles (GECNPs) were synthesized using the sol-gel explosive precursors by a detonation method. The sol-gel explosive precursors were prepared using copper nitrate, citric acid, ethylene glycol and trinitro-1-3-5-triazine. The morphology and nature properties of the composites were investigated by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), X-ray fluorescence (XRF) and Raman spectrometry (RS). As a result, the GECNPs were successfully synthesized by detonation decomposition of the sol-gel explosive precursors. Results show that the as-obtained composites were with a core-shell spherical structure and the diameters of these composites were in the ranging of 10-40 nm. The different sizes and composition of the composites and the thickness of the carbon coating can be prepared by adjusting the component materials of the sol-gel explosive precursors.

graphite-encapsulated copper nanoparticles  /  sol-gel explosive precursors  /  detonation method  /  microstructure
罗宁, 李晓杰, 刘凯欣, 吴士玉, 陈士洋, 宋文杰. 采用凝胶炸药前驱体制备石墨包覆铜纳米颗粒的研究. 高压物理学报, 2013 , 27 (6) : 847 -855 .
Ning LUO, Xiao-Jie LI, Kai-Xin LIU, Shi-Yu WU, Shi-Yang CHEN, Wen-Jie SONG. Synthesis of Graphite-Encapsulated Copper Nanoparticles Using the Sol-Gel Explosive Precursors[J]. Chinese Journal of High Pressure Physics, 2013 , 27 (6) : 847 -855 .
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Funding
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  • Natural Science Foundation of China(11272081)
  • CUMT Sail Project, Introduction of Talent Project
  • State Key Laboratory of Explosion Science and Technology Open Project(KFJJ13-5M)
References
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Appendix
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Year 2013 volume 27 Issue 6
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Article Info
  • Receive Date：2012-01-31
  • Online Date：2026-11-05
  • Published：2013-12-15
Article Data
Affiliations
History
  • Received：2012-01-31
  • Revised：2012-06-26
Funding
Natural Science Foundation of China(11272081)
CUMT Sail Project, Introduction of Talent Project
State Key Laboratory of Explosion Science and Technology Open Project(KFJJ13-5M)
Affiliations
    1.School of Mechanics And Civil Engineering, CUMT, Xuzhou 221116, China
    2.Department of Mechanics & Aerospace Engineering, College of Engineering, Peking University, Beijing 10087, China
    3.State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China
    4.State Key Laboratory of Structural Analysis for Industrial Equipment, Department of Engineering Mechanics, Dalian University of Technology, Dalian 116023, China
References
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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