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Pressure-Induced Phase Transition of [Emim][PF6] and [Bmim][PF6] Studied by Raman Scattering
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Xiang ZHU, Yong-Qiang WANG, Zheng WANG, Xue-Rui CHENG, Chao-Sheng YUAN, Zhen-Ping CHEN, Lei SU
Chinese Journal of High Pressure Physics | 2013, 27(2) : 253 - 260
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Chinese Journal of High Pressure Physics | 2013, 27(2): 253-260
Pressure-Induced Phase Transition of [Emim][PF6] and [Bmim][PF6] Studied by Raman Scattering
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Xiang ZHU, Yong-Qiang WANG, Zheng WANG, Xue-Rui CHENG, Chao-Sheng YUAN, Zhen-Ping CHEN, Lei SU
Affiliations
  • The High Pressure Research Center of Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450002, China
Published: 2013-04-15
Outline
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In-situ pressure-induced phase transition of ionic liquids [Emim][PF6] and [Bmim][PF6] have been studied under high pressure and room temperature by using Raman spectroscopy and high-pressure diamond anvil cell (DAC) apparatus. With the increase of pressure, [Emim][PF6] experiences the solid-solid phase transition at about 0.86 GPa, and [Bmim][PF6] experiences the liquid-solid phase transition at about 0.62 GPa and the solid-solid phase transition at about 1.45 GPa. Furthermore, the decrease of pressure of [Bmim][PF6] has also been discussed in details. Pressure-released Raman spectra shows that the phase transition of [Bmim][PF6] is reversible under pressure up to 2 GPa.

room temperature ionic liquids  /  Raman spectra  /  phase transition  /  high pressure
朱祥, 王永强, 王征, 程学瑞, 袁朝圣, 陈镇平, 苏磊. 室温离子液体[Emim][PF6]和[Bmim][PF6]压致相变的拉曼散射研究. 高压物理学报, 2013 , 27 (2) : 253 -260 .
Xiang ZHU, Yong-Qiang WANG, Zheng WANG, Xue-Rui CHENG, Chao-Sheng YUAN, Zhen-Ping CHEN, Lei SU. Pressure-Induced Phase Transition of [Emim][PF6] and [Bmim][PF6] Studied by Raman Scattering[J]. Chinese Journal of High Pressure Physics, 2013 , 27 (2) : 253 -260 .
Year 2013 volume 27 Issue 2
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  • Receive Date:2011-10-21
  • Online Date:2026-11-05
  • Published:2013-04-15
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  • Received:2011-10-21
  • Revised:2012-03-03
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    The High Pressure Research Center of Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450002, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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